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91.
92.
Long-term, high resolution holographic storage has been achieved in side-chain liquid crystalline polyesters with high diffraction efficiency. The information can be completely erased by heating the film to about 80°C. The modular architecture of the polyesters permits a varition in the length of the main- and side-chains and the substituents of the azo chromophore. Each of these has a profound influence on the storage properties of the polyesters. In this article, we examine the influence of the length of the side-chains, the probe-beam-polarization dependence of the observed signal on the interface and the crystalline vs. amorphous nature of the films for optical storage. 相似文献
93.
94.
An environmentally stable mode-locked fiber laser based on nonlinear polarization rotation is experimentally demonstrated. The laser is based on a novel laser configuration that has negligible low-power steady-state reflectivity from one side and, consequently, no CW gain. The laser is self starting and the configuration is implementable as an all-fiber laser with standard polarization-maintaining fiber-pigtailed components. A pulse duration of 5.6 ps is obtained at a repetition rate of 5.96 MHz and at an average power of 8 mW. As an application of the proposed laser configuration, 213 mW of supercontinuum (600-1750 nm) was demonstrated from a fiber laser system with no sections of free-space optics. 相似文献
95.
96.
Mechanistic Insights into the Post‐Cyclization Isomerization in Gold‐Catalyzed 7‐exo‐dig‐Hydroarylations 下载免费PDF全文
M. Sc. Daniel Pflästerer Sören Schumacher Dr. Matthias Rudolph Prof. Dr. A. Stephen K. Hashmi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(32):11585-11589
The subsequent double‐bond isomerization in the synthesis of dibenzocycloheptenes and their heteroaromatic analogues was investigated. In the case of biphenyls, a basic additive completely prevented an isomerization to the thermodynamic product. With electron‐rich intramolecular heteroaromatic nucleophiles, the isomerization was still observed, but the kinetic product can be obtained by careful control of the reaction times in most cases. Mechanistic studies demonstrated that a slow isomerization is also possible with the gold catalyst at elevated temperatures, but much faster isomerization rates were observed with acidic additives. An observed initiation period for the gold‐catalyzed isomerization indicates that not the homogenous catalyst, but a decomposition product of it may be the catalytically active species. 相似文献
97.
以简化推力轴承为对象 ,理论上证明了推力轴承运行时存在热不稳定性 ,采用小扰动分析法得到了油膜温度的扰动方程 ,应用简正模态分析法推导了无量纲热不稳定性准则数以及推力轴承运行的热不稳定性准则 . 相似文献
98.
99.
G. G. Pereira W. V. Pinczewski D. Y. C. Chan L. Paterson P. E. Øren 《Transport in Porous Media》1996,24(2):167-201
Drainage displacements in three-phase flow under strongly wetting conditions are completely described by a simple generalisation of well understood two-phase drainage mechanisms. As in two-phase flow, the sequence of throat invasions in three-phase flow is determined by fluid connectivity and threshold capillary pressure for the invading interface. Flow through wetting and intermediate spreading films is important in determining fluid recoveries and the progress of the displacement in three-phase flow. Viscous pressure drops associated with flow through films give rise to multiple filling and emptying of pores. A three-phase, two-dimensional network model based on the pore-scale fluid distributions and displacement mechanisms reported by Øren et al. and which accounts for flow through both wetting and intermediate fluid films is shown to correctly predict all the important characteristics of three-phase flow observed in glass micromodel experiments. 相似文献
100.
Synthesis and Characterization of Geminally Dialkylsubstituted Tetraindanotetraoxa[8]circulenes 下载免费PDF全文
A synthetic methodology for the synthesis of 2,2‐dialkyl‐4,7‐dimethoxy‐2,3‐dihydro‐1H‐inden‐1‐ones from 4,7‐dimethoxy‐2,3‐dihydro‐1H‐inden‐1‐one has been developed, and some of these compounds were converted into the corresponding geminally dialkylsubstituted tetraindanotetraoxa[8]circulenes with the expectation of obtaining discotic liquid crystalline materials. 相似文献