Sodium silver tricobalt bis(diphosphate) and sodium silver copper(II) diphosphate

The crystal structures of two new diphosphates, sodium silver tricobalt bis(diphosphate), (Na_1.42Ag_0.58)Co₃(P₂O₇)₂, and sodium silver copper(II) diphosphate, (Na_1.12Ag_0.88)CuP₂O₇, provide examples of the effect of mixing Na and Ag in the same site of known host phosphate compounds. The small differences in ionic radii of the two monocations do not lead to significant differences in the structural details. In the latter compound, the Cu atom lies on an inversion center.     

The first report on the catalytic oxidation of urazoles to their corresponding triazolinediones via in situ catalytic generation of Br using periodic acid or oxone/KBr system

A combination of periodic acid or oxone^® and a catalytic amount of KBr in the presence of few drops of water, were used for the catalytic oxidation of urazoles and bis-urazoles to their corresponding triazolinediones under mild and heterogeneous conditions with moderate to excellent yields.     

Batching deteriorating items with applications in computer communication and reverse logistics

We study two deterministic scheduling problems that combine batching and deterioration features. In both problems, there is a certain demand for identical good quality items to be produced in batches. In the first problem, each batch is assigned an individual machine that requires a cost and a time to be activated. All the machines are identical, work in parallel, and always produce good quality items. All the items are available at time zero and they deteriorate while waiting for production. Deterioration results in a linear increase of time and cost of production. In the second problem, there is a single machine that produces good quality as well as defective items in batches. Each batch is preceded by a setup time and requires a setup cost. Defective items have to be reworked on the same machine. They deteriorate while waiting for rework. At a time to be decided, the machine switches from production to rework defective items of the current batch. After rework, every defective item has the required good quality. In both problems, the objective is to find batch partitioning such that a linear combination of the production cost and production completion time is minimized. The two problems are observed at computer service providers and also reverse logistics. In computer service providers, machines and items correspond to communication service channels and information transfer tasks, respectively. We reduce both problems to minimizing a function of one variable representing the number of batches. In an optimal solution of either problem, there are at most two different batch sizes. Linear time algorithms are proposed for both problems.     

Monotonicity of input-output mappings in inverse coefficient and source problems for parabolic equations

This article presents a mathematical analysis of input-output mappings in inverse coefficient and source problems for the linear parabolic equation ut=(kx(x)ux)+F(x,t), (x,t)∈ΩT:=(0,1)×(0,T]. The most experimentally feasible boundary measured data, the Neumann output (flux) data f(t):=−k(0)ux(0,t), is used at the boundary x=0. For each inverse problems structure of the input-output mappings is analyzed based on maximum principle and corresponding adjoint problems. Derived integral identities between the solutions of forward problems and corresponding adjoint problems, permit one to prove the monotonicity and invertibility of the input-output mappings. Some numerical applications are presented.     

Hall effect on unsteady MHD Couette flow and heat transfer of a Bingham fluid with suction and injection

The unsteady magnetohydrodynamic flow of an electrically conducting viscous incompressible non-Newtonian Bingham fluid bounded by two parallel non-conducting porous plates is studied with heat transfer considering the Hall effect. An external uniform magnetic field is applied perpendicular to the plates and the fluid motion is subjected to a uniform suction and injection. The lower plate is stationary and the upper plate moves with a constant velocity and the two plates are kept at different but constant temperatures. Numerical solutions are obtained for the governing momentum and energy equations taking the Joule and viscous dissipations into consideration. The effect of the Hall term, the parameter describing the non-Newtonian behavior, and the velocity of suction and injection on both the velocity and temperature distributions are studied.     

Preconcentration and Determination of Copper（Ⅱ） Using Octadecyl Silica Membrane Disks Modified by 1,5-Diphenylcarhazide and Flame Atomic Absorption Spectrometry

A simple and reproducible method for the rapid extraction and determination of trace amounts of copper（Ⅱ） ions using octadecyl-bonded silica membrane disks modified by 1,5-diphenylcarbazide （DPC） and atomic absorption spectrometry was presented, which was based on complex formation on the surface of the ENVI-18 DISK^TM disks followed by stripping of the retained species by minimum amounts of appropriate organic solvents. The elution was efficient and quantitative. The effect of potential interfering ions, pH, ligand amount, stripping solvent, and sample flow rate were also investigated. Under the optimal experimental conditions, the break-through volume was found to be about 1000 mL providing a preconcentration factor of 400. The maximum capacity of the disks was found to be （255±5） lag for Cu^2＋, and the limit of detection of the proposed method was 5 ng per 1000 mL. The method was applied to the extraction and recovery of copper in different water samples.     

Regularization of Nonmonotone Variational Inequalities

In this paper we extend the Tikhonov-Browder regularization scheme from monotone to rather a general class of nonmonotone multivalued variational inequalities. We show that their convergence conditions hold for some classes of perfectly and nonperfectly competitive economic equilibrium problems.     

The characterization of charcoal and high-density carbon pellets produced from Douglas-fir bark

High-density carbon pellets (HDCP) produced from Douglas-fir bark could provide an alternate source of carbon for industry. The production of HDCP in vertical retorts is discussed. Scanning electron microscopy (SEM), atomic absorption spectroscopy (AAS), carbon elemental analysis, and other analytical methods were used to characterize HDCP. HDCP produced from Douglas-fir bark in this work have 90% fixed carbon, an average density of 1.3 g/mL, and 1.18% average ash content with negligible metal impurities. These pellets should be particularly suited for use in the production of adsorbents, high-grade carbons, reductants, carbon black, carbon electrodes, and activated carbons.

     

Liquid-liquid extraction of palladium(II) from hydrobromic acid media by hexadecylpyridinium bromide.

A simple and rapid liquid-liquid extraction of palladium has been studied involving ion-pairing of bromocomplexes of palladium(II) with hexadecylpyridinium bromide (HDPB) dissolved in chloroform. The stoichiometry and distribution of (HDP)2PdBr4 between the aqueous and organic phase was investigated by spectrophotometric mole ratio method. The extraction efficiency of palladium(II) by HDPB was studied as a function of several variables: acid, salt, surfactant concentration and equilibrium time. The results showed that PdBr4(2-) extraction could be explained by assuming the formation of (HDP)2PdBr4 complexes in the aqueous solution and transfer to organic phase. The extraction was fast and the shaking time was only a few min. The average recovery of palladium(II) from an aqueous solution containing 10 microg/ml of analyte was 99% with an RSD% of 0.95. The percentage recovery of 0.2 microg/ml palladium(II) was 96%.     

Chelates and corrosion inhibition of newly synthesized Schiff bases derived from <Emphasis Type="Italic">o</Emphasis>-tolidine

New copper(II), nickel(II), iron(III) and palladium(II) Schiff base complexes derived from o-tolidine and selected aldehydes, namely salicyaldehyde and 2-hydroxynaphthaldehyde have been synthesized and characterized by a combination of elemental analyses, magnetic moments, spectral (u.v.–vis., i.r.) and thermal (tg, dtg) mesurements. The corrosion inhibition of aluminium and copper in 1 M HCl and chromium–nickel steel in crude oil using N,N′bis(salicyledene)-o-tolidine have been studied by weight loss method.