全文获取类型
收费全文 | 267篇 |
免费 | 6篇 |
国内免费 | 6篇 |
专业分类
化学 | 191篇 |
力学 | 2篇 |
数学 | 34篇 |
物理学 | 52篇 |
出版年
2022年 | 4篇 |
2021年 | 3篇 |
2020年 | 6篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 6篇 |
2016年 | 12篇 |
2015年 | 11篇 |
2014年 | 7篇 |
2013年 | 11篇 |
2012年 | 17篇 |
2011年 | 13篇 |
2010年 | 16篇 |
2009年 | 15篇 |
2008年 | 11篇 |
2007年 | 20篇 |
2006年 | 20篇 |
2005年 | 12篇 |
2004年 | 11篇 |
2003年 | 8篇 |
2002年 | 13篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 7篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1991年 | 2篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1986年 | 1篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1966年 | 1篇 |
1932年 | 2篇 |
1931年 | 2篇 |
1906年 | 1篇 |
排序方式: 共有279条查询结果,搜索用时 46 毫秒
271.
The fragment shape variation index approach is applied to intramolecular interactions involving C6 aromatic molecular fragments
in the special case where the shape-modifying interactions are also caused primarily by other C6 aromatic fragments of the
same molecule. This report is a part of a series of studies aimed at the detailed modeling of various components of intramolecular
interactions among molecular fragments, including aromatic ring interactions, aromatic ring and non-aromatic conjugated and
non-conjugated system interactions, and more general through-space and through-bond interactions. The ultimate purpose of
these studies is a better understanding of the electron density shape modifying effects of intramolecular interactions. 相似文献
272.
Franziska Debatin Karsten Behrens Dr. Jens Weber Dr. Igor A. Baburin Prof. Dr. Arne Thomas Dr. Johannes Schmidt Dr. Irena Senkovska Prof. Dr. Stefan Kaskel Alexandra Kelling Dr. Niklas Hedin Dr. Zoltan Bacsik Dr. Stefano Leoni Prof. Dr. Gotthard Seifert Prof. Dr. Christian Jäger Dr. Christina Günter Prof. Dr. Uwe Schilde Dr. Alwin Friedrich Prof. Dr. Hans‐Jürgen Holdt 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(37):11630-11640
We report on a new series of isoreticular frameworks based on zinc and 2‐substituted imidazolate‐4‐amide‐5‐imidate (IFP‐1–4, IFP=imidazolate framework Potsdam) that form one‐dimensional, microporous hexagonal channels. Varying R in the 2‐substitued linker (R=Me (IFP‐1), Cl (IFP‐2), Br (IFP‐3), Et (IFP‐4)) allowed the channel diameter (4.0–1.7 Å), the polarisability and functionality of the channel walls to be tuned. Frameworks IFP‐2, IFP‐3 and IFP‐4 are isostructural to previously reported IFP‐1. The structures of IFP‐2 and IFP‐3 were solved by X‐ray crystallographic analyses. The structure of IFP‐4 was determined by a combination of PXRD and structure modelling and was confirmed by IR spectroscopy and 1H MAS and 13C CP‐MAS NMR spectroscopy. All IFPs showed high thermal stability (345–400 °C); IFP‐1 and IFP‐4 were stable in boiling water for 7 d. A detailed porosity analysis was performed on the basis of adsorption measurements by using various gases. The potential of the materials to undergo specific interactions with CO2 was investigated by measuring the isosteric heats of adsorption. The capacity to adsorb CH4 (at 298 K), CO2 (at 298 K) and H2 (at 77 K) at high pressure were also investigated. In situ IR spectroscopy showed that CO2 is physisorbed on IFP‐1–4 under dry conditions and that both CO2 and H2O are physisorbed on IFP‐1 under moist conditions. 相似文献
273.
Gál ZA Rutt OJ Smura CF Overton TP Barrier N Clarke SJ Hadermann J 《Journal of the American Chemical Society》2006,128(26):8530-8540
An homologous series of layered oxysulfides Sr2MnO2Cu(2m-delta)S(m+1) with metamagnetic properties is described. Sr2MnO2Cu(2-delta)S2 (m = 1), Sr2MnO2Cu(4-delta)S3 (m = 2) and Sr2MnO2Cu(6-delta)S4 (m = 3), consist of MnO2 sheets separated from antifluorite-type copper sulfide layers of variable thickness by Sr(2+) ions. All three compounds show substantial and similar copper deficiencies (delta approximately equal to 0.5) in the copper sulfide layers, and single-crystal X-ray and powder neutron diffraction measurements show that the copper ions in the m = 2 and m = 3 compounds are crystallographically disordered, consistent with the possibility of high two-dimensional copper ion mobility. Magnetic susceptibility measurements show high-temperature Curie-Weiss behavior with magnetic moments consistent with high spin manganese ions which have been oxidized to the (2+delta)+ state in order to maintain a full Cu-3d/S-3p valence band, and the compounds are correspondingly p-type semiconductors with resistivities around 25 Omega cm at 295 K. Positive Weiss temperatures indicate net ferromagnetic interactions between moments. Accordingly, magnetic susceptibility measurements and low-temperature powder neutron diffraction measurements show that the moments within a MnO(2) sheet couple ferromagnetically and that weaker antiferromagnetic coupling between sheets leads to A-type antiferromagnets in zero applied magnetic field. Sr2MnO2Cu(5.5)S4 and Sr2MnO2Cu(3.5)S3 are metamagnets which may be driven into the fully ordered ferromagnetic state below 25 K by the application of fields of 0.06 and 1.3 T respectively. The relationships between the compositions, structures, and physical properties of these compounds, and the prospects for chemical control of the properties, are discussed. 相似文献
274.
Chromatographic determination of glutathione disulfide (GSSG) without any preliminary reduction has been presented using GSSG derivatization by p-hydroxymercuribenzoate (pHMB) in strong alkaline medium followed by the determination of GS-pHMB complex by reversed phase chromatography coupled to chemical vapour generation and atomic fluorescence detector (RPC-CVGAFS). A detection limit of 35 nM for GSSG (corresponding to 1.8 pmol) detected as GS-pHMB species was achieved based on a signal-to-noise ratio of 3 in buffer and in blood. The proposed method was applied to the determination of GSSG in whole blood and validated by the classical determination of GSSG by derivatization after reduction with dithiothreitol (DTT). 相似文献
275.
Zoltan Szucs Danie Moolman Sabine Verryn Jan Rijn Zeevaart 《Journal of Radioanalytical and Nuclear Chemistry》2010,284(1):239-243
The synthesis of the three 18F-labeled 2-nitroimidazoyl oximes is described to be used as possible hypoxia tumor imaging agents. The title oximes were
successfully synthesized in a four step sequence, characterized, and finally radiolabeled. Under optimized labeling conditions,
the radiochemical yields of the three markers were in the range of 69–80%. 相似文献
276.
Laszlo Szarvas Zoltan Bajko Stefan Fusz Sebastian Burck Jrg Daniels Martin Nieger Dietrich Gudat 《无机化学与普通化学杂志》2002,628(11):2303-2310
The bis‐phosphonio‐1, 2, 4‐diazaphospholide salt ( 1 [Cl]) reacts with complex boron hydrides under selective extrusion of one PPh3 moiety to give borane adducts of a novel zwitterionic phosphonio‐1, 2, 4‐diazaphospholide. Both the Et3B adduct 2b and the free zwitterionic heterocycle 3 , which was liberated by further reaction of 2b with NEt3, were characterized by spectroscopic data and 2b , as well, by a single crystal X‐ray diffraction study. The comparison of the structural data with those of a neutral 1, 2, 4‐diazaphosphole and a lithium‐1, 2, 4‐diazaphospholide which was formed by deprotonation of the parent 1, 2, 4‐diazaphosphole 4a discloses trends in endocyclic bonding distances which can be rationalized in terms of a charge dependent shift in the π‐electron distribution. First studies of the co‐ordination properties reveal for both 2b and 4a a marked preference to bind two M(CO)5‐fragments (M = Cr, W) via the lone‐pairs of the phosphorus and one nitrogen atom; mononuclear complexes with P‐co‐ordinated heterocycles are formed as intermediates. A single crystal X‐ray diffraction study of the dinuclear complex [Cr2(CO)10(μ2‐C2H3N2P‐κP, κN)] ( 10a ) together with spectroscopic studies (including 183W NMR studies of tungsten complexes) suggests that M→L back donation is more efficient for P‐ than for N‐bound metal fragments. No evidence for π‐co‐ordination of the 1, 2, 4‐diazaphosphole ring to a Cr(CO)3 fragment was obtained. 相似文献
277.
DFT and coupled‐cluster calculations show that the B2N2O4 molecule has a triplet ground state and therefore is paramagnetic. 相似文献
278.
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
279.