化学概念教学中学生归纳与演绎思维的培养*——基于对“电解质”概念教学的分析

归纳与演绎思维在化学概念的形成、巩固和应用过程中发挥着重要作用,化学概念教学中归纳与演绎思维的培养要遵循生为主体师为主导、概念教学与思维培养相统一、思维培养和概念教学循序渐进、归纳演绎与分析综合相结合的原则。以“电解质”概念的教学为例,分别从化学概念教学中归纳思维的培养和演绎思维的培养等2个维度对具体培养路径进行了阐释。     

An Optimal Nonlinear Feedback Control Strategy for Randomly Excited Structural Systems

A strategy for optimal nonlinear feedback control of randomlyexcited structural systems is proposed based on the stochastic averagingmethod for quasi-Hamiltonian systems and the stochastic dynamicprogramming principle. A randomly excited structural system isformulated as a quasi-Hamiltonian system and the control forces aredivided into conservative and dissipative parts. The conservative partsare designed to change the integrability and resonance of the associatedHamiltonian system and the energy distribution among the controlledsystem. After the conservative parts are determined, the system responseis reduced to a controlled diffusion process by using the stochasticaveraging method. The dissipative parts of control forces are thenobtained from solving the stochastic dynamic programming equation. Boththe responses of uncontrolled and controlled structural systems can bepredicted analytically. Numerical results for a controlled andstochastically excited Duffing oscillator and a two-degree-of-freedomsystem with linear springs and linear and nonlinear dampings, show thatthe proposed control strategy is very effective and efficient.     

AN IMPROVED ARC-LENGTH METHOD AND APPLICATION IN THE POST-BUCKLING ANALYSIS FOR COMPOSITE STRUCTURES

Based on the conventional arc- length method, an improved arc- length method with high-efficiency is proposed. The weighted modifications with respect to the variation of structural stiffness and extra-interpolation modification by using the information of known equilibrium points are introduced to improve the incremental arc- length . An approximate expansion method for the accumulated and expected arc-length is used to ensure the convergence at given load levels in large range of applications. Numerical results show that the improved arc-length method has well adaptability and higher efficiency in the post-buckling analysis of plates and sheik structures for tracing whole load-deflection path and obtaining the convergence values at any specified load levels.     

固定接触界面切向静弹性刚度问题研究

根据两球体单峰同时受法向、切向载荷时微滑切向应力的分布以及MB模型,给出了界面的总切向接触静弹性条件刚度、总条件法向载荷的解析解。将切向接触静弹性条件刚度的解析解嵌入到有限元软件中,获得了整机的理论模态。以一款八四七厂华中工学院XHK5140型自动换刀计算机数控立式镗铣床上的结合部为研究对象,通过实验对解析解进行了定量验证。研究结果表明：在理论振型与实验振型一致的条件下,界面模型的相对误差在-19．2％～16．8％之间。     

DPD Simulation on the Transformation and Stability of O/W and W/O Microemulsions

The dissipative particle dynamics simulation method is adopted to investigate the microemulsion systems prepared with surfactant (H1T1), oil (O) and water (W), which are expressed by coarse-grained models. Two topologies of O/W and W/O microemulsions are simulated with various oil and water ratios. Inverse W/O microemulsion transform to O/W microemulsion by decreasing the ratio of oil-water from 3:1 to 1:3. The stability of O/W and W/O microemulsion is controlled by shear rate, inorganic salt and the temperature, and the corresponding results are analyzed by the translucent three-dimensional structure, the mean interfacial tension and end-to-end distance of H1T1. The results show that W/O microemulsion is more stable than O/W microemulsion to resist higher inorganic salt concentration, shear rate and temperature. This investigation provides a powerful tool to predict the structure and the stability of various microemulsion systems, which is of great importance to developing new multifunctional microemulsions for multiple applications.     

TLP-CCC: Temporal Link Prediction Based on Collective Community and Centrality Feature Fusion

In the domain of network science, the future link between nodes is a significant problem in social network analysis. Recently, temporal network link prediction has attracted many researchers due to its valuable real-world applications. However, the methods based on network structure similarity are generally limited to static networks, and the methods based on deep neural networks often have high computational costs. This paper fully mines the network structure information and time-domain attenuation information, and proposes a novel temporal link prediction method. Firstly, the network collective influence (CI) method is used to calculate the weights of nodes and edges. Then, the graph is divided into several community subgraphs by removing the weak link. Moreover, the biased random walk method is proposed, and the embedded representation vector is obtained by the modified Skip-gram model. Finally, this paper proposes a novel temporal link prediction method named TLP-CCC, which integrates collective influence, the community walk features, and the centrality features. Experimental results on nine real dynamic network data sets show that the proposed method performs better for area under curve (AUC) evaluation compared with the classical link prediction methods.     

Free-Space QKD with Modulating Retroreflectors Based on the B92 Protocol

Free-space quantum key distribution (QKD) has attracted considerable attention due to its lower channel loss and link flexibility. It allows two participants share theoretical unconditional secure keys, and can potentially be applied to air-to-ground quantum communication to establish a global quantum network. Free-space QKD using modulating retro-reflectors (MRR-QKD) significantly reduces the pointing requirement and simplifies the structure of the mobile terminal, therefore making it suitable for lightweight aircraft such as unmanned aerial vehicle and Cubesat, etc. Based on intensity modulation of two non-orthogonal states and the B92 protocol, we proposed a scheme to improve the previous work (Optics Express 2018, 26, 11331). Our scheme simplifies the optical structure and shows more robustness in equipment imperfection. The analysis and simulation show that the number of multiple quantum well modulators needed in our scheme decreases from eight to three with similar performance. Additionally, while the previous scheme cannot work due to low modulator extinction ratio or high optical misalignment, our scheme can still operate.     

Sensitive electrochemical determination of α-fetoprotein using a glassy carbon electrode modified with in-situ grown gold nanoparticles,graphene oxide and MWCNTs acting as signal amplifiers

The authors describe an electrochemical immunoassay for α-fetoprotein (α-FP) using a glassy carbon electrode (GCE) modified with a nanocomposite made from gold nanoparticles, graphene oxide and multi-walled carbon nanotubes (AuNPs/GO-MWCNTs) and acting as a signal amplification matrix. The nanocomposite was synthesized in a one-pot redox reaction between GO and HAuCl₄ without using an additional reductant. The stepwise assembly of the immunoelectrode was characterized by means of cyclic voltammetry and electrochemical impedance spectroscopy. The interaction of antigen and antibody on the surface of the electrode creates a barrier for electrons and causes retarded electron transfer, this resulting in decreased signals in differential pulse voltammetry of hexacyanoferrate which is added as an electrochemical probe. Using this strategy and by working at a potential of 0.2 V (vs. SCE), a wide analytical range (0.01 - 100 ng∙mL‾¹) is covered. The correlation coefficient is 0.9929, and the limit of detection is as low as 3 pg∙mL‾¹ at a signal-to-noise ratio of 3. This electrochemical immunoassay combines the specificity of an immunological detection scheme with the sensitivity of an electrode modified with AuNPs and GO-MWCNTs.

Schematic illustration of the fabrication procedure of the immunosensor

     

无8-,9-和10-圈的平面图的3-可选择性

寻找平面图是3-或者4-可选择的充分条件是图的染色理论中一个重要研究课题,本文研究了围长至少是4的特殊平面图的选择数,通过权转移的方法证明了每个围长至少是4且不合8-圈,9-圈和10-圈的平面图是3-可选择的．     

A filter method for nonlinear semidefinite programming with global convergence

In this study, a new filter algorithm is presented for solving the nonlinear semidefinite programming. This algorithm is inspired by the classical sequential quadratic programming method. Unlike the traditional filter methods, the sufficient descent is ensured by changing the step size instead of the trust region radius. Under some suitable conditions, the global convergence is obtained. In the end, some numerical experiments are given to show that the algorithm is effective.