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951.
952.
微分简易示波伏安法测定分子筛中微量钴的研究 总被引:1,自引:0,他引:1
微分简易示波伏安法是一种新的示波分析方法.与经典示波计时电位法相比,具有灵敏度高、去极剂峰高易于测定等优点.本文研究了CO-4(2一毗院偶氮)间苯二酚钠(PAR)体系的示波特性并探讨了应用微分简易示波伏安法测定微量钻的可能性.试验发现,在O.2mol/LHAc-0·2mol/LNaAc-2·5X10-’mol/LPAR底液中,钻离子在iFE曲线的阴极支上电位为一1.68V处产生一尖锐峰,其峰高与钻离子浓度在1.5X10’~1·2X10-‘mol/L范围内呈线性关系,检测灵敏度为5.OXIO-’mol/L‘以此拟定了测定微量钻的新方法.与光度法相比,该… 相似文献
953.
Zusammenfassung Die Modifizierung hochvernetzter Styrol—Divinylbenzolcopolymerisate durch Zusatz von Verdünnungsmitteln bei der Polymerisation führt zur Bildung proliferationsfähiger Polymerer. Es besteht ein enger optimaler Zusammensetzungsbereich. Der Zusammenhang der Proliferationsfähigkeit mit Gleichgewichtsquellung, permanenter Porosität und Gehalt an anhängenden Doppelbindungen wird untersucht; die Morphologie des Proliferationsprozesses wird in mikrokinematographischen Zeitrafferaufnahmen festgehalten.
Mit 10 Abbildungen 相似文献
The modification of highly crosslinked styrene—divinylbenzene copolymers by adding diluents to the polymerizing system yields polymers showing proliferous polymerization. There exists an optimum concentration range of diluent. The correlation of proliferous polymerization to equilibrium swelling, permanent porosity, and content of pendent double bonds is investigated. The morphology of the proliferation process is observed in micro time lapse motion pictures.
Mit 10 Abbildungen 相似文献
954.
Upper bounds for the maximum shear stress in the St. Venant torsion problem are derived with the aid of the theory of subharmonic functions. The main result is a bound that is determined in a simple manner by the magnitude of the applied twisting moment and two parameters peculiar to the cross section: the radius of the largest circle contained in it and the minimum curvature of the curve that bounds it.
Zusammenfassung Mit Hilfe subharmonischer Funktionen werden obere Grenzen in dem Torsionsproblem von St. Venant erhalten. Das Hauptergebnis ist eine Grenze, die auf einfache Weise vom Drehmoment und zwei nur vom Querschnitt abhängigen Parametern bestimmt ist, und zwar von dem Radius des grössten eingeschriebenen Kreises und von der Minimalkrümmung der Begrenzungskurve des Querschnitts.相似文献
955.
We have implemented a kinetic Monte Carlo (KMC) simulation to study the effects of wafer miscut and wafer defects on the morphologies of Si (111) surfaces etched in NH4F. Although a conventional KMC simulation reproduced previously published results, it failed to produce the morphologies observed in our experiments. By introducing both dopant sites and lattice defect sites into the model, we are able to simulate samples having different dopant elements and densities as well as different defect concentrations. Using the modified KMC simulation, the simulated surface morphologies agree well with the morphologies observed in our experiments. The enhanced model also gives insights to the formation mechanism for multiple level stacking pits, a notable morphology on the etched surfaces of samples with very small miscut angles. 相似文献
956.
Diversifying vancomycin via chemoenzymatic strategies 总被引:4,自引:0,他引:4
[reaction: see text] The rapid diversification of glycopeptides via glycorandomization reveals that significantly diverse substitutions are tolerated and suggests there may be a synergistic benefit to the construction of mechanistically related natural product core scaffold fusions. This work also further highlights the utility of chemoenzymatic approaches to diversify complex natural product architectures. 相似文献
957.
Austin RH Xie A van der Meer L Redlich B Lindgård PA Frauenfelder H Fu D 《Physical review letters》2005,94(12):128101
The amide I and II bands in myoglobin show a heterogeneous temperature dependence, with bands at 6.17 and 6.43 microm which are more intense at low temperatures. The amide I band temperature dependence is on the long wavelength edge of the band, while the short wavelength side has almost no temperature dependence. We compare concepts of anharmonic solid-state crystal physics and chemical physics for the origins of these bands. We suggest that the long wavelength side is composed of those amino acids which hydrogen bond to the hydration shell of the protein, and that temperature dependent bands can be used to determine the time it takes vibrational energy to flow into the hydration shell. We determine that vibrational energy flow to the hydration shell from the amide I takes approximately 20 ps to occur. 相似文献
958.
Electronic Moirè patterns found on lead (Pb) quantum islands can serve as a template to grow self-organized cluster (nanopucks) arrays of various materials. These patterns can be divided into fcc- and hcp-stacked areas, which exhibit different binding strengths to the deposited adatoms. For Ag adatoms, the binding energy can differ substantially and the confined nucleation thus occurs in the fcc sites. Both the size distribution and spatial arrangement of the Ag nanopucks are analyzed and found to be commensurate with the characteristics of the template island, which exhibits a bilayer oscillatory behavior. 相似文献
959.
Formation of spontaneous polarization in one-dimensional (1D) structures is a key phenomenon that reveals collective behaviors in systems of reduced dimensions, but has remained unsolved for decades. Here we report ab initio studies on finite-temperature structural properties of infinite-length nanowires of Pb(Zr0.5Ti0.5)O3 solid solution. Whereas existing studies have ruled out the possibility of phase transition in 1D chains, our atomistic simulations demonstrate a different conclusion, characterized by the occurrence of a ferroelectric polarization and critical behaviors of dielectric and piezoelectric responses. The difference is accounted for by the use of depolarizing effects associated with finite thickness of wires. Our results suggest no fundamental constraint that limits the use of ferroelectric nanowires and nanotubes arising from the absence of spontaneous ordering. 相似文献
960.
A novel optical edge-projection method is proposed for surface contouring of an object with low reflectivity. A structured light edge is projected onto a dark surface, and the image is captured by a CCD camera. The object contour is evaluated with an active triangular projection algorithm, and one obtains a whole-field three-dimensional contour of the object by scanning the optical edge over the entire object surface. The proposed method is applied to a black nonreflective object made from woven carbon fiber and is also applied to measure the profile of a small object (a coin). The results show that an accurate profile of the specimen can be obtained. 相似文献