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991.
Edmund K. Burke Timothy Curtois Gerhard Post Rong Qu Bart Veltman 《European Journal of Operational Research》2008
This paper is concerned with the development of intelligent decision support methodologies for nurse rostering problems in large modern hospital environments. We present an approach which hybridises heuristic ordering with variable neighbourhood search. We show that the search can be extended and the solution quality can be significantly improved by the careful combination and repeated use of heuristic ordering, variable neighbourhood search and back-tracking. The amount of computational time that is allowed plays a significant role and we analyse and discuss this. The algorithms are evaluated against a commercial Genetic Algorithm on commercial data. We demonstrate that this methodology can significantly outperform the commercial algorithm. This paper is one of the few in the scientific nurse rostering literature which deal with commercial data and which compare against a commercially implemented algorithm. 相似文献
992.
原子荧光法测定甘草中汞 总被引:8,自引:0,他引:8
利用还原气化的非色散型装置,以湿法消解的方式,对中药甘草中的痕量汞进行了原子荧光测定。研究了影响测定结果的条件,比较了两种玻璃仪器的洗涤方式,并以工作曲线法和加入作图法对照,试验回收率在86.9%-110.8%,误差<13.1%,得出了满意的分析结果。 相似文献
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994.
Banach空间值白噪声广义泛函是一类重要的向量值白噪声广义泛函. 该文建立了Banach空间值白噪声广义泛函的一个解析刻画定理, 并给出了此结果的若干应用. 相似文献
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998.
Zapolotsky Eugeny N. Qu Yanyang Babailov Sergey P. 《Journal of inclusion phenomena and macrocyclic chemistry》2022,102(1-2):1-33
Journal of Inclusion Phenomena and Macrocyclic Chemistry - The paramagnetic lanthanide complexes with polyaminopolycarboxylate (PAPC) ligands attract considerable attention from the standpoint of... 相似文献
999.
Dr. Zhaohua Li Dr. Rui Hu Dr. Shuai Ye Prof. Jun Song Prof. Liwei Liu Prof. Junle Qu Prof. Weiguo Song Dr. Changyan Cao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(27):e202104588
Catalyst wettability regulation has emerged as an attractive approach for high catalytic performance for the past few years. By introducing appropriate wettability, the molecule diffusion of reactants and products can be enhanced, leading to high activity. Besides this, undesired molecules are isolated for high selectivity of target products and long-term stability of catalyst. Herein, we summarize wettability-induced high-performance heterogeneous thermocatalysis in recent years, including hydrophilicity, hydrophobicity, hybrid hydrophilicity-hydrophobicity, amphiphilicity, and superaerophilicity. Relevant reactions are further classified and described according to the reason for the performance improvement. It should be pointed out that studies of utilizing superaerophilicity to improve heterogeneous thermocatalytic performance have been included for the first time, so this is a comparatively comprehensive review in this field as yet. 相似文献
1000.
Jun-Bo Chen Dr. Cen Zhou Ru-Qiang Lu Dr. Xin-Chang Wang Hang Qu Dr. Mithu Saha Hao-Liang Liu Prof. Hui Zhang Prof. Xiao-Yu Cao 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(5):1293-1299
Triindolo-truxene, a C3-symmetric molecule with a large π-conjugated plane, has six methylene carbon atoms and three aromatic carbon atoms that can be facilely functionalized. Herein, butyl, carbonyl, cyano, and/or malononitrile groups were introduced at six methylene carbon atoms (6-, 14-, 22- or 8-, 16-, 24-positions) and/or three aromatic carbon atoms (2-, 10-, and 18-positions) of triindolo-truxene to produce eight derivatives. Their photophysical properties, electrochemical properties, and molecular assembly can be effectively modulated by substituents and substitution patterns. Incorporation of electron-deficient groups led to redshifts in both the absorption and emission of these derivatives and also lowered their HOMO and LUMO levels. Different substitution patterns resulted in the different intramolecular donor–acceptor interactions. Electron-deficient substituents at the methylene carbon atoms in the 6-, 14-, and 22-positions led to intramolecular charge transfer from the fluorene arms to the truxene core, whereas the corresponding substitutions at the methylene carbon atoms in the 8-, 16-, and 24-positions resulted in intramolecular charge transfer from the truxene core to the fluorene arms. The molecular packing in single crystals and molecular aggregation in solution are also influenced by the substituents and substitution patterns. This work provides a straightforward strategy to alter the properties of triindolo-truxene. 相似文献