全文获取类型
收费全文 | 7312篇 |
免费 | 1367篇 |
国内免费 | 706篇 |
专业分类
化学 | 5103篇 |
晶体学 | 41篇 |
力学 | 432篇 |
综合类 | 44篇 |
数学 | 916篇 |
物理学 | 2849篇 |
出版年
2024年 | 22篇 |
2023年 | 145篇 |
2022年 | 247篇 |
2021年 | 282篇 |
2020年 | 346篇 |
2019年 | 260篇 |
2018年 | 246篇 |
2017年 | 233篇 |
2016年 | 350篇 |
2015年 | 384篇 |
2014年 | 419篇 |
2013年 | 524篇 |
2012年 | 674篇 |
2011年 | 709篇 |
2010年 | 460篇 |
2009年 | 414篇 |
2008年 | 461篇 |
2007年 | 431篇 |
2006年 | 409篇 |
2005年 | 290篇 |
2004年 | 259篇 |
2003年 | 166篇 |
2002年 | 191篇 |
2001年 | 120篇 |
2000年 | 137篇 |
1999年 | 148篇 |
1998年 | 127篇 |
1997年 | 142篇 |
1996年 | 126篇 |
1995年 | 117篇 |
1994年 | 101篇 |
1993年 | 99篇 |
1992年 | 68篇 |
1991年 | 59篇 |
1990年 | 58篇 |
1989年 | 33篇 |
1988年 | 32篇 |
1987年 | 32篇 |
1986年 | 11篇 |
1985年 | 24篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1916年 | 1篇 |
排序方式: 共有9385条查询结果,搜索用时 15 毫秒
101.
示差脉冲伏安法测定黄酒中的酪氨酸 总被引:3,自引:0,他引:3
本文研究了硼砂介质中镍与酪氨酸络合物的示差脉冲吸附伏安特性,实验了仪器参数对示差脉冲阴极吸附伏安法的影响,在最佳条件下络合物峰电流与酪氨酸浓度在2.0×10^-7~4.0×10^-5mol.L^-1范围内有线性关系,并以此法测定了黄酒中酪氨酸的含量。 相似文献
102.
本文报道以青蒿酸(2)为原料合成了一些含羟基的青蒿倍半萜内酯差向异构体9与10、11与12、13与14。其中9已从青蒿中分离到。 相似文献
103.
THz spectroscopic investigation of 2,4-dinitrotoluene 总被引:5,自引:0,他引:5
Yunqing Chen Haibo Liu Yanqing Deng Dunja Schauki Michael J. Fitch Robert Osiander Caroline Dodson James B. Spicer Michael Shur X.-C. Zhang 《Chemical physics letters》2004,400(4-6):357-361
We have investigated the terahertz (THz) spectrum of 2,4-DNT by using Fourier transform infrared spectroscopy in the 0.2–19.5 THz region. We also examined low-frequency intermolecular or phonon modes between 0.2 and 1.8 THz via THz time-domain spectroscopy. The extracted absorption coefficient and refractive index of an intermolecular band at 1.08 THz are 110 cm−1 and 1.67, respectively. Density functional theory (DFT) was applied to obtain structure and vibrational frequencies of 2,4-DNT. The calculated results are in agreement with the experimental data. Observed vibrational frequencies have been interpreted using DFT. Two intermolecular or phonon modes were identified at 1.08 and 2.52 THz. 相似文献
104.
A capillary electrophoresis--inductively coupled plasma atomic-emission spectrometry (CE-ICP-AES) system using a polytetrafluoroethylene (PTFE) capillary has been developed. The CE-ICP interface was a modified concentric nebulizer. The PTFE capillary (50 microm internal diameter) was used as the central capillary of the nebulizer. Using the PTFE capillaries, the solution flow rate induced by the carrier gas flow was smaller than that of glass capillary. Solution flow was mainly induced by the CE electric field. Baseline separation of Ba2+/Mg2+ ion pair using simple buffer solution of 0.014 M sodium acetate was reported. Separation and correlation of metal species in metallothioneins (MT-1 and MT-2 in MT) of rabbit liver using the CE-ICP system were also discussed. 相似文献
105.
106.
Lin Jiacheng Li Qianqian Zeng Xiaodong Chen Ziyang Ding Qihang Li Yang Zhou Hui Meng Xianli Chen Deliang Deng Zixin Hong Xuechuan Xiao Yuling 《中国科学:化学(英文版)》2020,63(6):766-770
Osteosarcoma is the most common primary malignant tumor of bone, particularly among children and adolescents. Advances in imaging, surgical techniques, and implants have dramatically reduced the need for amputation in the past three decades.Recently, in vivo fluorescence imaging in the second near-infrared window(NIR-II, 1,000–1,700 nm) shows impressive advantages of deeper tissue penetration and higher spatial resolution, which makes it a promising tool for the early diagnosis and post-operative observation of Osteosarcoma. To the best of our knowledge, this paper is the first time to develop a novel NIR-II fluorescence probe conjugated with an osteosarcoma targeted oligopeptide for molecular tumor imaging in a xenograft orthotopic osteosarcoma mouse model. 相似文献
107.
108.
Yi Ming Liu Sui Ping Deng Hui Zheng Jian Ming Ouyang 《中国化学快报》2007,18(3):345-348
The ring patterns of calcium oxalate crystals were induced by domains in Langmuir-Blodgett (LB) films of dipalmitoylpho- sphatidylcboline (DPPC). The result was explained by the defects at the ring boundaries of liquid condensed (LC) and liquid expanded (LE) phases of LB film. These boundaries could provide less free energy and much more nucleating sites for COM crystals. 相似文献
109.
2-(Chloromethyl)furan as an electrophile reacted with lithium trialkylalkyllylbo-rates,followcl by the oxidation with H_2O_2 under basic condition to afford 2-furfurylketonesin good yields.This provides a new method for the preparation of 2-furfurylkctoncs. 相似文献
110.
Panaxynol is a bioactive component in traditional Chinese medicines (TCMs), such as Saposhnikovia divaricata and Panax ginseng. In the work, two solvent-free sample techniques of pressurized hot water extraction (PHWE) and headspace liquid-phase microextraction (HS-LPME) were combined and developed for the determination of panaxynol in a TCM of S. divaricata. Panaxynol in the TCM samples from different growing areas was extracted by PHWE in dynamic mode, followed by extraction and concentration with HS-LPME and analysis with gas chromatography-mass spectrometry (GC-MS). The PHWE and HS-LPME parameters were optimized and the method validations were studied. Panaxynol in S. divaricata from four different growing areas was quantitatively analyzed by internal standard method. These results have shown that PHWE-LPME-GC-MS is a simple, rapid, efficient and low-cost method for the determination of panaxynol in TCMs and is a potential tool for TCM quality assessment. 相似文献