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41.
Anik Goswami Gunjan Verma P. A. Hassan Vinod K. Aswal 《Journal of Dispersion Science and Technology》2014,35(12):1717-1726
The adsorption behavior of binary mixtures comprising nonionic surfactants at the air–water interface has been studied by bubble pressure tensiometry at concentrations above and below their critical micelle concentrations. Surfactants with the same hydrocarbon chains but different degree of ethoxylations were chosen as the components to understand their mixing behavior at equilibrium and dynamic conditions. At short times, the adsorption is found to be diffusion limited for individual components as well as for the mixtures, as predicted by the Ward and Tordai model. The effective diffusion coefficient of the monomers in the mixed state displays a dynamic synergism, consistent with the molecular thermodynamic model for dynamic surface tension. However, the equilibrium surface tension and micellar diffusion coefficient of the mixtures exhibit ideal behavior. 相似文献
42.
J. S. Samantray Sunil Goswami V. K. Sharma Jayashree Biswal H. J. Pant 《Journal of Radioanalytical and Nuclear Chemistry》2014,302(2):979-982
A radiotracer investigation was carried out in a diesel hydrotreater (DHDT) unit in a refinery for leak detection in a breech-lock heat exchanger system. The main objectives of the study were to identify the leaking heat exchanger in a system with six heat exchangers and estimate the leak rate. Bromine-82 as dibromobiphenyl was selected and used as radiotracer for the investigation. The radiotracer was instantaneously injected into the suction end of the feed pump line to the heat exchanger of the DHDT unit. The movement of the tracer was measured at strategically selected locations using NaI(Tl) scintillation detectors. Based upon the results of the radiotracer investigation, it was found that out of six heat exchangers, exchanger E-1F was leaking. 相似文献
43.
Haladhara Naik Ashok Goswami Guinyun Kim Kwangsoo Kim Sung-Chul Yang Muhammad Sahid Muhammad Zaman Manwoo Lee Sung-Gyun Shin Moo-Hyun Cho 《Journal of Radioanalytical and Nuclear Chemistry》2014,299(3):1335-1343
The independent isomeric-yield ratios of 89m,gNb for the 93Nb(γ, 4n) 89m,gNb reaction with bremsstrahlung energies of 45-, 50-, 55-, 60-, and 70-MeV were measured by the activation and the off-line γ-ray spectrometric technique at 100 MeV electron linac of the Pohang accelerator laboratory. The isomeric-yield ratios of 89m,gNb for the natZr(p, xn) 89m,gNb and the 89Y(α, 4n) 89m,gNb reactions were measured by using a stacked-foil activation technique with the proton energies of 19–45 MeV and alpha energies of 38.9-, 40.5-, and 42.5-MeV at the MC-50 cyclotron of Korea Institute of Radiological and Medical Sciences. The measured isomeric-yield ratio of 89m,gNb from the 93Nb(γ, 4n), natZr(p, xn), and 89Y(α, 4n) reactions were compared with the similar literature data in the 89Y(3He, 3n) reaction. It was found that the isomeric yield ratio of 89m,gNb increases with projectile energy, which indicate the effect of excitation energy. However, for the similar compound nucleus with the same excitation energy, the isomeric-yield ratios of 89m,gNb in the 89Y(α, 4n) and 89Y(3He, 3n) reactions are higher than those in the 93Nb(γ, 4n) and natZr(p, xn) reactions, which indicates the role of input angular momentum. The isomeric-yield ratios of 89m,gNb in the 93Nb(γ, 4n), natZr(p, xn), 89Y(α, 4n), and 89Y(3He, 3n) reactions were also calculated theoretically using computer code TALYS 1.4. The theoretical isomeric-yield ratios of 89m,gNb from four reactions increase with excitation energy. However, the theoretical value are significantly higher than the experimental data in the 93Nb(γ, 4n) and natZr(p, xn) reactions but slightly lower or comparable in the 89Y(α, 4n) rand 89Y(3He, 3n) reactions. 相似文献
44.
Dr. Bhupendra Goswami Dr. Thomas J. Feuerstein Dr. Ravi Yadav Dr. Ralf Köppe Dr. Sergei Lebedkin Prof. Dr. Manfred M. Kappes Prof. Dr. Peter W. Roesky 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(13):4401-4411
The synthesis of calcium complexes ligated by three different chiral iminophosphonamide ligands, L- H ( L =[Ph2P{N(R)CH(CH3)Ph}2]), L′ -H ( L′ =[Ph2P{NDipp}{N(R)CH(CH3)Ph}]), (Dipp=2,6-iPr2C6H3), and L′′ -H ( L′′ =[Ph2P{N(R)CH(CH3)naph}2]), (naph=naphthyl) is presented. The resulting structures [ L 2Ca], [ L′ 2Ca], and [ L′′ 2Ca] represent the first examples of enantiopure homoleptic calcium complexes based on this type of ligands. The calcium complexes show blue–green photoluminescence (PL) in the solid state, which is especially bright at low temperatures. Whereas the emission of [ L′′ 2Ca] is assigned to the fluorescence of naphthyl groups, the PL of [ L 2Ca] and [ L′ 2Ca] is contributed by long-lived phosphorescence and thermally activated delayed fluorescence (TADF), with a strong variation of the PL lifetimes over the temperature range of 5–295 K. Furthermore, an excellent catalytic activity was found for these complexes in hydroboration of ketones at room temperature, although no enantioselectivity was achieved. 相似文献
45.
Dr. Yong Zhang Dr. Devrishi Goswami Dr. Danling Wang Dr. Tsung‐Shing Andrew Wang Shiladitya Sen Dr. Thomas J. Magliery Dr. Patrick R. Griffin Dr. Feng Wang Dr. Peter G. Schultz 《Angewandte Chemie (International ed. in English)》2014,53(1):132-135
The X‐ray crystal structure of a bovine antibody (BLV1H12) revealed a unique structure in its ultralong heavy chain complementarity determining region 3 (CDR3H) that folds into a solvent‐exposed β‐strand “stalk” fused to a disulfide crosslinked “knob” domain. We have substituted an antiparallel heterodimeric coiled‐coil motif for the β‐strand stalk in this antibody. The resulting antibody (Ab‐coil) expresses in mammalian cells and has a stability similar to that of the parent bovine antibody. MS analysis of H–D exchange supports the coiled‐coil structure of the substituted peptides. Substitution of the knob‐domain of Ab‐coil with bovine granulocyte colony‐stimulating factor (bGCSF) results in a stably expressed chimeric antibody, which proliferates mouse NFS‐60 cells with a potency comparable to that of bGCSF. This work demonstrates the utility of this novel coiled‐coil CDR3 motif as a means for generating stable, potent antibody fusion proteins with useful pharmacological properties. 相似文献
46.
Cobalt‐Embedded Nitrogen‐Rich Carbon Nanotubes Efficiently Catalyze Hydrogen Evolution Reaction at All pH Values 下载免费PDF全文
Dr. Xiaoxin Zou Xiaoxi Huang Dr. Anandarup Goswami Dr. Rafael Silva Dr. Bhaskar R. Sathe Eliška Mikmeková Prof. Tewodros Asefa 《Angewandte Chemie (International ed. in English)》2014,53(17):4372-4376
Despite being technically possible, splitting water to generate hydrogen is still practically unfeasible due mainly to the lack of sustainable and efficient catalysts for the half reactions involved. Herein we report the synthesis of cobalt‐embedded nitrogen‐rich carbon nanotubes (NRCNTs) that 1) can efficiently electrocatalyze the hydrogen evolution reaction (HER) with activities close to that of Pt and 2) function well under acidic, neutral or basic media alike, allowing them to be coupled with the best available oxygen‐evolving catalysts—which also play crucial roles in the overall water‐splitting reaction. The materials are synthesized by a simple, easily scalable synthetic route involving thermal treatment of Co2+‐embedded graphitic carbon nitride derived from inexpensive starting materials (dicyandiamide and CoCl2). The materials’ efficient catalytic activity is mainly attributed to their nitrogen dopants and concomitant structural defects. 相似文献
47.
Cover Picture: Double CaromH Activation Associated with Etheral Oxygen Insertion to Phenazine Architecture in Oxidisable Ruthenium(III) Complexes: A Mechanistic Insight (Chem. Eur. J. 10/2014) 下载免费PDF全文
48.
Tamal Goswami Dr. Anirban Misra 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(43):13951-13956
The effect of an external electric field on the magnetic anisotropy of a single‐molecule magnet has been investigated, for the first time, with the help of DFT. The application of an electric field can alter the magnetic anisotropy from “easy‐plane” to “easy‐axis” type. Excitation analysis performed through time‐dependent DFT predicts that the external electric field facilitates metal to π‐acceptor ligand charge transfer, leading to uniaxial magnetic anisotropy and concomitant spin Hall effect in a single molecule. 相似文献
49.
Y. C. Goswami Vijay Kumar P. Rajaram V. Ganesan Mohammad Azad Malik Paul O’Brien 《Journal of Sol-Gel Science and Technology》2014,69(3):617-624
Fluorine doped SnO2 nanostructures were grown using ultrasonic assisted sol–gel method. The gel was obtained by dissolving stannous chloride in methanol with ammonium fluoride as dopant followed by irradiation with ultrasonic vibrations. Obtained samples were characterized by structural, morphological and optical studies. All the peaks in the X-ray diffractograms are identified and indexed as tetragonal cassiterite structure. Negative slope of Williamson–Hall plots indicates compressive strain. Particle size of SnO2 nanostructures is decreases with increases in concentration of fluorine doping. Atomic force microscopy, scanning electron microscopy and transmission electron microscopy studies confirm the formation of ring like porous structures and then hollow tube like growth with increase in the fluorine concentration. Peaks in Raman spectra also indicate strong confinement in SnO2 particles. Distinct peaks in the PL spectra make the structure suitable for photovoltaic applications. 相似文献
50.