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排序方式: 共有1115条查询结果,搜索用时 109 毫秒
31.
Wen-Xing Yang Ai-Xi Chen Ting-Ting Zha Yanfeng Bai Ray-Kuang Lee 《Central European Journal of Physics》2014,12(10):737-743
We demonstrate the generation of two-mode continuous-variable (CV) entanglement in a V-type three-level atom trapped in a doubly resonant cavity using a microwave field driving a hyperfine transition between two upper excited states. By numerically simulating the dynamics of this system, our results show that the CV entanglement with large mean number of photons can be generated even in presence of the atomic relaxation and cavity losses. More interestingly, it is found that the intensity and period of entanglement can be enhanced significantly with the increasing of the atomic relaxation due to the existence of the perfect spontaneously generated interference between two atomic decay channels. Moreover, we also show that the entanglement can be controlled efficiently by tuning the intensity of spontaneously generated interference and the detuning of the cavity field. 相似文献
32.
We studied the electron heat transport across a non‐local stochastic magnetic field and a non‐local non‐stochastic magnetic field in tokamak plasmas. Analytical results and numerical simulation results were compared with conditions of a stochastic and a non‐stochastic magnetic field respectively in this article. Parameter of stochasticity in perturbed magnetic field was found not tobe a key factor in influencing effective radial heat conductivity in radial direction of tokomak when Chirikov parameter is close to one (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
33.
Nanoscale poly(alkyl methacrylate)s including poly(methyl methacrylate), poly(ethyl methacrylate), poly(cyclohexyl methacrylate), poly(iso‐butyl methacrylate) and poly(benzyl methacrylate) were prepared by a modified microemulsion polymerization procedure. NMR analysis suggested that these poly(methacrylate)s samples were higher in syndiotactic content, lower in isotactic content and the glass transition temperatures (Tgs) of them were also higher than those reported in the literature. The tacticities of the poly(methacrylate)s, beside the restricted volume effect of nanoparticles during the modified microemulsion polymerization, were mainly influenced by the reaction temperature, the lower the reaction temperature, the higher the syndiotacticity of the products. The syndiotacticity of the product decreased obviously when the polymerization was carried out at a temperature far above the Tg of the resulting polymer. It was also shown that the tacticity of the polymer was affected by the monomer structure, a monomer with the bulkier alkyl side group would liable to result in a polymer with richer syndiotacticity. Possible mechanism of rich‐syndiotacticity was also discussed. 相似文献
34.
Shaoming Yang Hong Li Wenling Zha Qing Sun Longzhen Zheng Aixi Chen 《Journal of Solid State Electrochemistry》2013,17(10):2603-2610
A highly sensitive label-free electrochemical aptasensor has been constructed for the electrochemical detection of thrombin (TB), where two layers of cobalt hexacyanoferrate (CoHCF) redox probes sandwiched with carbon nanotubes–Nafion were directly immobilized on the electrode surface by electrodeposition. Through the strong interaction between CN? (CoHCF) and gold nanoparticles (GNPs), GNPs were assembled on the CoHCF-modified electrode for the immobilization of thiolated thrombin aptamers (TBA). In the presence of target TB, TBA on the electrode surface could catch TB to form TBA–TB complex, which made a barrier for the electron transfer, resulting in a greater decrease in CoHCF redox probe signals. Thus, the proposed aptasensor showed a high sensitivity and a much wider linearity to TB in the range of 1.0 pg/mL?~?1.0 μg/mL with a detection limit of 0.28 pg/mL. 相似文献
35.
The reaction of halogenated 9H-carbazoles or carbazole with bromoesters in DMF under microwave irradiation readily affords a series of 9H-carbazoles-9-hydroxylic acids. 相似文献
36.
Optimized synthesis and purification of erlotinib hydrochloride (N-(3-ethynylphenyl)-6,7-bis(2-methoxyethoxy)quinazoline-4-amine hydrochloride) were studied. Highly polar piperazine was used in a nucleophilic substitution reaction with the chlorinated intermediate byproduct N-(3-ethynylphenyl)-6(2-chloroethoxy)-7-(2-methoxyethoxy)quinazolin-4-amine hydrochloride. As a result, N-(3-ethynylphenyl)-6(2-chloroethoxy)-7-(2-methoxyethoxy)quinazolin-4-amine hydrochloride was completely transformed to N-(3-ethynylphenyl)-6(2-piperzinoethoxy)-7-(2-methoxyethoxy)quinazolin-4-amine hydrochloride. The polarity of N-(3-ethynylphenyl)-6(2-piperzinoethoxy)-7-(2-methoxyethoxy)quinazolin-4-amine hydrochloride was changed, and its molecule was enlarged. It was easy to remove this larger, more polar, compound by recrystallization. Highly pure erlotinib hydrochloride was obtained with low impurity content (<1 %). The purity of erlotinib hydrochloride was >99.9 %. 相似文献
37.
38.
LUO Zha LIU Hao SHEN Wei SHI Kun CHEN Ankang SHENG Libo SUI Yongming ZOU Bo 《高等学校化学研究》2022,38(3):843-846
We used a diamond anvil cell(DAC) to control the deformation of synthesized copper nanorods and silver nanoparticles. And we measured the surface plasmon resonance of copper nanorods and silver nanoparticles, which exhibit redshifts or blueshifts. The surface plasmon resonance shows an abnormal blue shift for both copper nanorods and silver nanoparticles. The solvents of copper nanorods and silver nanoparticles are n-hexane and water, where the pressure loads include quasi-hydrostatic and non-hydrostatic. 相似文献
39.
Yantao Liu Yating Shi Lanen Wei Ke Zhao Dr. Jingjing Zhao Prof. Puyu Zhang Prof. Xuejun Xu Prof. Pan Li 《化学:亚洲杂志》2021,16(17):2417-2420
A gold-catalyzed synthesis of polyfluoroalkylated oxazoles from N-propargylamides under visible-light irradiation has been developed. These reactions display excellent compatibility of radicals and gold catalysts under visible-light irradiation. Mechanistic experiments indicate that polyfluoroalkyl iodides play a dual role in enhanced compatibility of radicals and gold catalysts through assisted protodeauration of vinyl gold and reactivated the gold catalyst. In addition, PPh3AuNTf2 not only activates N-propargylamide to generate vinyl gold intermediate, but also greatly promotes homolysis of polyfluoroalkyl iodides under blue light irradiation. 相似文献
40.
Jienan Li Lin Lin Bowei Jiang Chudong Wang Moutanou Modeste Judes Zeye Dan Wen Wei He Weifeng Qu Ying Liu Lagabaiyila Zha 《Electrophoresis》2021,42(9-10):1143-1152
DNA genotyping from trace and highly degraded biological samples is one of the most significant challenges of forensic DNA identification. There is a lack of simple and effective methods for genotyping highly degraded samples. In this study, a multiple loci insertion/deletion polymorphisms (Multi-InDels) panel was designed for detecting 18 autosomal Multi-InDels through capillary electrophoresis (CE) with amplicon sizes no longer than 125 bp. Studies of sensitivity, degradation, and species specificity were performed and a population study was carried out using 192 samples from Han populations in Hunan province in the south of China. The combined random match probability (CMP) of these 18 Multi-InDels was 3.23 × 10–12 and the cumulative probability of exclusion (CPE) was 0.9989, suggesting this panel could be used independently for human identification and could provide efficient supporting information for parentage testing. Complete profiles were obtained from as low as 62.5 pg of total input DNA after increasing the number of PCR cycles. Moreover, all alleles were detected from artificially highly degraded DNA after 80 min of boiling water bath treatment. This 18 Multi-InDels panel is simple, fast, and effective for the forensic analysis of highly degraded DNA. 相似文献