全文获取类型
收费全文 | 28486篇 |
免费 | 3709篇 |
国内免费 | 3157篇 |
专业分类
化学 | 20747篇 |
晶体学 | 375篇 |
力学 | 1403篇 |
综合类 | 241篇 |
数学 | 3548篇 |
物理学 | 9038篇 |
出版年
2024年 | 47篇 |
2023年 | 440篇 |
2022年 | 497篇 |
2021年 | 763篇 |
2020年 | 915篇 |
2019年 | 932篇 |
2018年 | 797篇 |
2017年 | 763篇 |
2016年 | 1126篇 |
2015年 | 1147篇 |
2014年 | 1361篇 |
2013年 | 1914篇 |
2012年 | 2279篇 |
2011年 | 2517篇 |
2010年 | 1764篇 |
2009年 | 1738篇 |
2008年 | 1938篇 |
2007年 | 1763篇 |
2006年 | 1580篇 |
2005年 | 1393篇 |
2004年 | 1109篇 |
2003年 | 902篇 |
2002年 | 882篇 |
2001年 | 740篇 |
2000年 | 622篇 |
1999年 | 580篇 |
1998年 | 504篇 |
1997年 | 443篇 |
1996年 | 474篇 |
1995年 | 386篇 |
1994年 | 367篇 |
1993年 | 341篇 |
1992年 | 319篇 |
1991年 | 276篇 |
1990年 | 232篇 |
1989年 | 191篇 |
1988年 | 167篇 |
1987年 | 128篇 |
1986年 | 141篇 |
1985年 | 154篇 |
1984年 | 101篇 |
1983年 | 64篇 |
1982年 | 71篇 |
1981年 | 53篇 |
1980年 | 52篇 |
1979年 | 58篇 |
1978年 | 40篇 |
1976年 | 37篇 |
1974年 | 40篇 |
1973年 | 45篇 |
排序方式: 共有10000条查询结果,搜索用时 78 毫秒
941.
A sensitive and specific method using high-performance liquid chromatography (LC)-tandem mass spectrometry (MS) for the analysis of total ribavirin in human red blood cells (RBC) is developed and validated. The method involves the addition of an internal standard and perchloric acid, the conversion of ribavirin phosphorylated metabolites to ribavirin, purification with a solid-phase exchange cartridge, and LC-MS-MS analysis. The MS-MS is selected to monitor m/z 245-113 for ribavirin and m/z 250-113 for [13C]ribavirin using positive electrospray ionization. The calibration curve is linear over a concentration of 100-10,000 ng/mL with a limit of quantitation of 100 ng/mL. Mean interassay accuracy for quality control (QC) at 100, 1000, and 10,000 ng/mL are 101.8%, 99.4%, and 98.8%, respectively. Mean interassay precision (%CV) for QC at 100, 1000, and 10,000 ng/mL are 5.0%, 5.0%, and 2.5%, respectively. Extractibility of total ribavirin from RBC is confirmed with RBC obtained from a [(14)C]ribavirin-dosed monkey. The method is used to determine the free and total ribavirin concentration in human RBC obtained from hepatitis C patients treated with ribavirin. 相似文献
942.
Thermolysis of [Ru3(CO)9(mu3-NOMe)(mu3-eta2-PhC2Ph)] (1) with two equivalents of [Cp*Co(CO)2] in THF afforded four new clusters, brown [Ru5(CO)8(mu-CO)3(eta5-C5Me5)(mu5-N)(mu4-eta2-PhC2Ph)] (2), green [Ru3Co2(CO)7(mu3-CO)(eta5-C5Me5)2(mu3-NH)[mu4-eta8-C6H4-C(H)C(Ph)]] (3), orange [Ru3(CO)7(mu-eta6-C5Me4CH2)[mu-eta3-PhC2(Ph)C(O)N(OMe)]] (4) and pale yellow [Ru2(CO)6[mu-eta3-PhC2(Ph)C(O)N(OMe)]] (5). Cluster 2 is a pentaruthenium mu5-nitrido complex, in which the five metal atoms are arranged in a novel "spiked" square-planar metal skeleton with a quadruply bridging alkyne ligand. The mu5-nitrido N atom exhibits an unusually low frequency chemical shift in its 15N NMR spectrum. Cluster 3 contains a triangular Ru2Co-imido moiety linked to a ruthenium-cobaltocene through the mu4-eta8-C6H4C(H)C(Ph) ligand. Clusters 4 and 5 are both metallapyrrolidone complexes, in which interaction of diphenylacetylene with CO and the NOMe nitrene moiety were observed. In 4, one methyl group of the Cp* ring is activated and interacts with a ruthenium atom. The "distorted" Ru3Co butterfly nitrido complex [Ru3Co(CO)5(eta5-C5Me5)(mu4-N)(mu3-eta2-PhC2Ph)(mu-I)2I] (6) was isolated from the reaction of 1 with [Cp*Co(CO)I2] heated under reflux in THF, in which a Ru-Ru wing edge is missing. Two bridging and one terminal iodides were found to be placed along the two Ru-Ru wing edges and at a hinge Ru atom, respectively. The redox properties of the selected compounds in this study were investigated by using cyclic voltammetry and controlled potential coulometry. 15N magnetic resonance spectroscopy studies were also performed on these clusters. 相似文献
943.
A phosphate-based epoxy resin for flame retardance: synthesis, characterization, and cure properties 总被引:2,自引:0,他引:2
A phosphorus-containing oligomer, bis(3-hydroxyphenyl) phenyl phosphate (BHPP), was synthesized through the reaction of phenyl dichlorophosphate and 1,3-dihydroxybenzene, and characterized by elemental analysis, Fourier transform IR spectroscopy, and 1H NMR and 31P NMR spectroscopy. Consequently, the phosphate-based epoxy resins with a phosphorus content of 1 and 2 wt % were prepared via the reaction of diglycidyl ether of bisphenol-A with BHPP and bisphenol-A, and were confirmed with Fourier transform IR spectroscopy and gel permeation chromatography. Phenolic melamine, Novolak, and dicyanodiamide were used as curing agents to prepare the thermoset resins with the control and the phosphate-based epoxy resins. Thermal properties and thermal degradation behavior of these thermoset resins were investigated by using differential scanning calorimetry and thermogravimetric analysis. The thermoset resins cured with phenolic melamine exhibited higher glass-transition temperatures than the other cured resins owing to the high rigidity of their molecular chain. Thermogravimetric analysis studies demonstrated that the decomposition temperatures of the thermoset resins cured with Novolak were higher than those of the others. A synergistic effect from the combination of the phosphate-based epoxy resin and the nitrogen-containing curing agent can result in a great improvement of the flame retardance for their thermoset resins. 相似文献
944.
945.
We report herein an unprecedented protocol for radical carbotrifluoromethylation of unactivated alkenes. With Cu(OTf)2 as the catalyst, the reaction of unactivated alkenes, TMSCF3 and activated alkyl chlorides at room temperature provides the corresponding carbotrifluoromethylation products in satisfactory yields. Directed by trifluoromethylation of alkyl radicals, the method exhibits an excellent regioselectivity that is opposite to those driven by CF3 radical addition. 相似文献
946.
947.
纤维素基磁性聚偕氨肟树脂吸附Mn(Ⅶ) 总被引:2,自引:0,他引:2
用酸处理的纤维素基磁性聚偕氨肟树脂(AMAO)在溶液中吸附KMnO4,发生氧化还原反应的几率在2%以下;用碱处理的树脂(BMAO)作吸附剂,KMnO4还原为Mn(OH)4的比例剧增,达到或超过10%,并且与溶液的pH有关。但是,Mn(Ⅶ)被还原为Mn(Ⅳ)的量基本上不受KMnO4起始浓度、吸附剂添加量和吸附时间变化的影响。BMAO树脂吸附KMnO4的量是树脂偕氨肟基含量的5倍以上。超当量吸附现象反映了物理吸附的本质。 相似文献
948.
双波长吸光光度法同时测定饮用水中钙和镁 总被引:1,自引:0,他引:1
研究了以偶氮胂Ⅲ作显色剂 ,用双波长吸光光度法同时测定水中钙和镁的最佳条件。测定钙和镁的最佳波长对分别为 6 5 0~ 5 93nm和 6 15~ 6 6 5 .5nm ,服从比耳定律的线性范围分别为0~ 12 μg/ 2 5ml和 0~ 18μg/ 2 5ml,检出限分别为 0 .0 1和 0 .0 18μg·ml- 1,加标回收率分别在 97 2 %~ 10 4 .5 %和 89.8%~ 92 .8%之间。将此法应用于饮用水中钙和镁的测定 ,结果满意。 相似文献
949.
The adsorption of a rake-type polymeric siloxane surfactant (polydimethylsiloxane-graft-polyether copolymer) on carbon black (CB) particles dispersed in mixtures of water with polar organic solvents (ethanol, formamide, or glycerol) has been investigated. The adsorption obeys the Langmuir isotherm at low surfactant concentrations (below the critical micelle concentration, CMC). At these conditions, the average surface area occupied by one siloxane surfactant follows the sequence water+glycerol mixture >plain water >water+ethanol mixture. At higher surfactant concentrations in the solution in contact with the particles, a sharp increase in the adsorbed amount is observed. The adsorbed layer thickness has been determined by dynamic light scattering. Below the CMC the adsorbed layer thickness is less than 10 nm. Above the CMC, the adsorbed layer thickness increases to 20-30 nm, a length scale comparable to the diameter of the siloxane surfactant micelles in aqueous solution. This fact, together with SANS data that we have obtained in the absence of added polar organic solvent, indicates that the structure of the adsorbed layer is similar to that of micelles. The findings presented here are relevant to waterborne coatings and ink formulations, where polymeric surfactants are used in conjunction with polar organic solvents. 相似文献
950.
The oligopeptides of alanine (penta-, deca-, and pentadeca-) were synthesized by solid phase method and new peptide-resin cleaving reagent TFA-BBr3 was used to cleave the peptides from resin-support. Penta-alanine was also synthesized by liquid phase for the comparision and FAB-Mass method was used to determine the molecular weight of penta-alanine. HPLC separation of these new oligopeptides were described. 相似文献