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31.
32.
Williamson RC 《Optics letters》2001,26(17):1362-1363
For lumped-element electro-optic modulators, the sensitivity ( partial differentialphi/ partial differentialV) of the phase, phi , in response to an applied voltage V is related to the optical group delay, T(g) , and the bandwidth, Domega . This relationship imposes a fundamental trade-off between the sensitivity and the bandwidth of electro-optic modulators: ( partial differentialphi/ partial differentialV)Domega= (dn/dV)(omega /n) , where n is the optical index. A similar relationship for traveling-wave modulators sets an upper limit on ( partial differentialphi/ partial differentialV) that is proportional to T(g) . 相似文献
33.
Abhayapala TD Kennedy RA Williamson RC 《The Journal of the Acoustical Society of America》2000,107(1):392-403
This paper introduces an efficient parameterization for the nearfield broadband beamforming problem with a single parameter to focus the beamformer to a desired operating radius and another set of parameters to control the actual broadband beampattern shape. The parameterization is based on an orthogonal basis set of elementary beampatterns by which an arbitrary beampattern can be constructed. A set of elementary beamformers are then designed for each elementary beampattern and the desired beamformer is constructed by summing the elementary beamformers with frequency and source-array distance dependent weights. An important consequence of our result is that the beamformer can be factored into three levels of filtering: (i) beampattern independent elementary beamformers; (ii) beampattern shape dependent filters; and (iii) radial focusing filters where a single parameter can be adjusted to focus the array to a desired radial distance from the array origin. As an illustration the method is applied to the problem of producing a practical array design that achieves a frequency invariant beampattern over the frequency range of 1:10 (which is suitable for speech acquisition using a microphone array), and with the array focused either to farfield or nearfield where at the lowest frequency the radial distance to the source is only three wavelengths. 相似文献
34.
J.B. Simeonsson L.J. Williamson 《Spectrochimica Acta Part B: Atomic Spectroscopy》2011,66(9-10):754-760
Studies have been performed to characterize laser induced breakdown spectroscopy (LIBS) plasmas formed in Ar/H2 gas mixtures that are used for hydride generation (HG) LIBS measurements of arsenic (As), antimony (Sb) and selenium (Se) hydrides. The plasma electron density and plasma excitation temperature have been determined through hydrogen, argon and arsenic emission measurements. The electron density ranges from 4.5 × 1017 to 8.3 × 1015 cm?3 over time delays of 0.2 to 15 μs. The plasma temperatures range from 8800 to 7700 K for Ar and from 8800 to 6500 K for As in the HG LIBS plasmas. Evaluation of the plasma properties leads to the conclusion that partial local thermodynamic equilibrium conditions are present in the HG LIBS plasmas. Comparison measurements in LIBS plasmas formed in Ar gas only indicate that the temperatures are similar in both plasmas. However it is also observed that the electron density is higher in the Ar only plasmas and that the emission intensities of Ar are higher and decay more slowly in the Ar only plasmas. These differences are attributed to the presence of H2 which has a higher thermal conductivity and provides additional dissociation, excitation and ionization processes in the HG LIBS plasma environment. Based on the observed results, it is anticipated that changes to the HG conditions that change the amount of H2 in the plasma will have a significant effect on analyte emission in the HG LIBS plasmas that is independent of changes in the HG efficiency. The HG LIBS plasmas have been evaluated for measurements of elements hydrides using a constant set of HG LIBS plasma conditions. Linear responses are observed and limits of detection of 0.7, 0.2 and 0.6 mg/L are reported for As, Sb and Se, respectively. 相似文献
35.
36.
T M Haygood B Eisenberg M B Hays J F García M R Williamson 《Magnetic resonance imaging》1989,7(5):571-573
We report the first case of avascular necrosis of a carpal bone to be imaged on a 0.064 Tesla magnet, one of the lowest field strength magnetic resonance imaging systems currently available. 相似文献
37.
38.
L. Landois R. v. Jaksch J. B. Haycraft R. J. Williamson und F. Kraus 《Fresenius' Journal of Analytical Chemistry》1890,29(1):241-244
Ohne Zusammenfassung 相似文献
39.
Prof. Michael North Marta Omedes‐Pujol Courtney Williamson 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(37):11367-11375
The asymmetric addition of trimethylsilyl cyanide to aldehydes can be catalysed by Lewis acids and/or Lewis bases, which activate the aldehyde and trimethylsilyl cyanide, respectively. It is not always apparent from the structure of the catalyst whether Lewis acid or Lewis base catalysis predominates. To investigate this in the context of using salen complexes of titanium, vanadium and aluminium as catalysts, a Hammett analysis of asymmetric cyanohydrin synthesis was undertaken. When Lewis acid catalysis is dominant, a significantly positive reaction constant is observed, whereas reactions dominated by Lewis base catalysis give much smaller reaction constants. [{Ti(salen)O}2] was found to show the highest degree of Lewis acid catalysis, whereas two [VO(salen)X] (X=EtOSO3 or NCS) complexes both displayed lower degrees of Lewis acid catalysis. In the case of reactions catalysed by [{Al(salen)}2O] and triphenylphosphine oxide, a non‐linear Hammett plot was observed, which is indicative of a change in mechanism with increasing Lewis base catalysis as the carbonyl compound becomes more electron‐deficient. These results suggested that the aluminium complex/triphenylphosphine oxide catalyst system should also catalyse the asymmetric addition of trimethylsilyl cyanide to ketones and this was found to be the case. 相似文献
40.
A kinetic analysis of the asymmetric addition of trimethylsilyl cyanide to benzaldehyde using three aluminium based catalysts has been carried out. All three catalysts displayed rate equations, which were first order in trimethylsilyl cyanide concentration and zero order in benzaldehyde concentration. The results are consistent with a common mechanism for effective asymmetric catalysis of cyanohydrin synthesis, involving combined activation of the aldehyde by a Lewis acid and activation of the trimethylsilyl cyanide by a Lewis base. The mechanistic analysis was also applied to a magnesium-based catalyst system to demonstrate its general applicability. 相似文献