弹塑性梁在轴向应力波下的动态屈曲

本文考虑轴向应力波效应，利用分叉理论研究各种支承半无限长弹塑性梁的动态屈曲问题。在轴向阶梯载荷和脉冲载荷冲击下得到了梁的临界屈曲载荷及初始屈曲模态。其结果与实验现象相一致。同时也为研究结构动态屈曲问题提供了有效途径。     

水坝在水流作用下动力响应的一种分析方法

以广东某水坝为研究对象,给出一种基于Fluent平台和Ansys平台进行结构动力响应分析的方法。首先采用基于YOUNGS界面重构技术的VOF模型,对流动进行数值模拟,成功捕捉了闸门开启过程中自由面的变化,比较了在三种落差情况下水坝的受力差异。计算表明,即使在上游平稳的入流条件下,水坝所受到的湍流水压力也会出现波动现象,水压力对坝体的冲击为低频作用,下游水位的升高会减缓水压力的波动,这些特点都与现场观察的相符。然后将水动力作为激励条件导入结构动力分析平台Ansys后,进一步对坝体结构进行动力分析。结构的模态分析结果与实测结果一致。因此,方法可以应用于实际。     

激光准直检测仪的研制及其应用开发

检测仪的研制，是从工程中数量甚大的桥式起重机的安全性检测中，国家规范要求甚高而实际检测手段简陋的矛盾提出的。装置充分利用激光束的直线性和传输过程中光斑中心不变、光强较高的特性；通过集光、机、电为一体的测尺直接读出数据。应用这套装置，已进行１１台双梁桥式起重机箱形主梁的变形测定，结果表明：这套装置在现场使用方便，精度与检测要求匹配，装置价格不高，对工程单位比较实用。１９９５年获国家实用新型专利     

一种改进混合迎风格式在翼型流场激波捕捉中的应用

波阻是飞行器超音速飞行的关键设计因素,精确捕捉激波在流场中的位置,是数值模拟含激波流场和精确计算波阻的一个重要研究内容.本文基于网格节点有限体积空间离散方法,采用AUSM格式与FVS格式的混合格式(MAUSM方法)计算对流通量,从而抑制在数值模拟流场出现的激波处振荡和过冲现象,确保AUSM准确捕获接触间断的特性和FVS格式捕捉激波的能力.本文使用MAUSM方法分别计算了在跨声速和超声速条件下的NACA0012翼型流场,并与中心差分格式的计算结果进行比较.结果表明,对于存在激波的翼型流场,MAUSM方法是有效的.     

有压管道双孔板水流流场的数值模拟

利用数值计算的方法对多级孔板消能器内湍流流场进行模拟，并将所得的结果与实验进行了比较。这些比较表明，数值计算的方法是可靠的。     

Copper‐Catalyzed Formation of α‐Alkoxycycloalkenones from N‐Tosylhydrazones

The combination of 20 mol % of copper iodide and lithium tert‐butoxide triggers the formation of a broad range of substituted, functionalized α‐alkoxy 2H‐naphthalenones from readily available N‐tosylhydrazones. The data suggests that this transformation occurs through cycloaddition of a copper carbenoid with an ester, followed by a Lewis acid‐catalyzed [1,2] alkyl shift of the in situ generated alkoxyepoxide intermediate.     

Localization and Dynamics of Long‐Lived Excitations in Colloidal Semiconductor Nanocrystals with Dual Quantum Confinement

Semiconductor nanocrystals consisting of a quantum dot (QD) core and a quantum well (QW) shell, where the QD and QW are separated by a tunneling barrier, offer a unique opportunity to engineer the photophysical properties of individual nanostructures. Using the thicknesses of the corresponding layers, the excitons of the first and second excited states can be separated spatially, localizing one state to the QD and the other to the QW. Thus the wave function overlap of the two states can be minimized, suppressing non‐radiative thermalization between the two wells, which in turn leads to radiative relaxation from both states. The molecular analogy to such dual emission would be the inhibition of internal conversion, a special case that violates Kasha′s rule. Using nanosecond time‐resolved spectroscopy of QDQW CdSe/ZnS onion‐like nanocrystals, an intermediate regime of exciton separation and suppressed thermalization is identified where the non‐radiative relaxation of the higher‐energy state is slowed, but not completely inhibited. In this intermediate thermalization regime, the temporal evolution of the delayed emission spectra resulting from trapped carriers mimic the dynamics of such states in nanocrystals that consist of only a QD core. In stark contrast, when a higher‐energy metastable state exists in the QW shell due to strongly suppressed interwell thermalization, the spectral dynamics of the long‐lived excitations in the QD and QW, which are spectrally distinct, are amplified and differ from each other as well as from those in the core‐only nanocrystals. This difference in spectral dynamics demonstrates the utility of exploiting well‐defined exciton localization to study the nature and spatial dependence of the intriguing photophysics of colloidal semiconductor nanocrystals, and illustrates the power of nanosecond gated luminescence spectroscopy in illuminating complex relaxation dynamics which are entirely masked in steady‐state or ultrafast spectroscopy.     

Conductivity‐Dependent Completion of Oxygen Reduction on Oxide Catalysts

The electric conductivity‐dependence of the number of electrons transferred during the oxygen reduction reaction is presented. Intensive properties, such as the number of electrons transferred, are difficult to be considered conductivity‐dependent. Four different perovskite oxide catalysts of different conductivities were investigated with varying carbon contents. More conductive environments surrounding active sites, achieved by more conductive catalysts (providing internal electric pathways) or higher carbon content (providing external electric pathways), resulted in higher number of electrons transferred toward more complete 4e reduction of oxygen, and also changed the rate‐determining steps from two‐step 2e process to a single‐step 1e process. Experimental evidence of the conductivity dependency was described by a microscopic ohmic polarization model based on effective potential localized nearby the active sites.     

Electrochemical Sensors Using Two‐Dimensional Layered Nanomaterials

Two‐dimensional (2D) layered nanomaterials, e.g. graphene and molybdenum disulfide (MoS₂), have rapidly emerged in material sciences due to their unique physical, chemical and mechanical properties. In the meanwhile, there is a growing interest in constructing electrochemical sensors for a wide range of chemical and biological molecules by using these 2D nanomaterials. In this review, we summarize recent advances on using graphene and MoS₂ for the development of electrochemical sensors for small molecules, proteins, nucleic acids and cells detection. We also provide our perspectives in this rapidly developing field.