全文获取类型
收费全文 | 84496篇 |
免费 | 1652篇 |
国内免费 | 1087篇 |
专业分类
化学 | 28918篇 |
晶体学 | 827篇 |
力学 | 7107篇 |
综合类 | 50篇 |
数学 | 32782篇 |
物理学 | 17551篇 |
出版年
2023年 | 139篇 |
2022年 | 158篇 |
2021年 | 248篇 |
2020年 | 344篇 |
2019年 | 257篇 |
2018年 | 10603篇 |
2017年 | 10421篇 |
2016年 | 6352篇 |
2015年 | 1188篇 |
2014年 | 675篇 |
2013年 | 797篇 |
2012年 | 4392篇 |
2011年 | 11147篇 |
2010年 | 6071篇 |
2009年 | 6426篇 |
2008年 | 7007篇 |
2007年 | 9129篇 |
2006年 | 618篇 |
2005年 | 1587篇 |
2004年 | 1772篇 |
2003年 | 2125篇 |
2002年 | 1191篇 |
2001年 | 366篇 |
2000年 | 421篇 |
1999年 | 302篇 |
1998年 | 323篇 |
1997年 | 286篇 |
1996年 | 324篇 |
1995年 | 237篇 |
1994年 | 177篇 |
1993年 | 191篇 |
1992年 | 120篇 |
1991年 | 122篇 |
1990年 | 106篇 |
1989年 | 91篇 |
1988年 | 90篇 |
1987年 | 88篇 |
1986年 | 68篇 |
1985年 | 70篇 |
1984年 | 52篇 |
1983年 | 42篇 |
1982年 | 45篇 |
1981年 | 44篇 |
1980年 | 47篇 |
1979年 | 45篇 |
1914年 | 45篇 |
1913年 | 40篇 |
1912年 | 40篇 |
1909年 | 41篇 |
1908年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
Understanding and control of the surface properties such as molecular orientations are of great importance in numerous applications of ionic liquids. However, there remain discrepancies among the previous experimental and theoretical studies on the surface orientation and structures of room temperature ionic liquids(RTIL) systems. In this article, the orientation of 1-butyl-3-methylimidazolium([bmin]) cation at the air/liquid interface of a characteristic RTIL, 1-butyl-3-methylimidazolium hexafluorophosphate([bmim][PF6]), was investigated by the sum frequency generation vibrational spectroscopy(SFG-VS). Detailed polarization and experimental configuration analyses of the SFG-VS spectra showed the possibility of a small spectral splitting in the CH3 symmetric stretching region, which can be further attributed to the probable existence of multiple orientations for the interfacial [bmim] cations. In addition, the(N)–CH3 vibrations were absent, ruling out the prediction by several recent molecular dynamics simulations which state that portions of the [bmim] cations orient with a standing-up(N)–CH3 group at the ionic liquid surface. Hence, new realistic theoretical models have to be developed to reflect the complex nature of the ionic liquid surface. 相似文献
22.
23.
24.
25.
26.
The structure, chemical composition, and magnetic properties of electrochemically deposited nanocrystalline Co-Ni-Fe films
were investigated using a number of techniques. A high saturation magnetic induction up to B
s
= 21 kG was attained. An enhancement of the saturation magnetization compared to the ideal anticipated one was revealed,
which correlated with the nonlinear behavior of the structural phase composition and lattice parameters with the change of
the composition.
The text was submitted by the authors in English. 相似文献
27.
A forecasting model is developed for the number of daily applications for loans at a financial services telephone call centre. The purpose of the forecasts and the associated prediction intervals is to provide effective staffing policies within the call centre. The model building process is constrained by the availability of only 2 years and 7 months of data. The distinctive feature of the data is that demand is driven in the main by advertising. The analysis given focuses on applications stimulated by press advertising. Unlike previous analyses of broadly similar data, where ARIMA models were used, a model with a dynamic level, multiplicative calendar effects and a multiplicative advertising response is developed and shown to be effective. 相似文献
28.
杂多酸催化合成乙酸乙酯 总被引:14,自引:0,他引:14
回流吸附法制备的负载型12-钨磷酸(HPW/C)是合成乙酸乙酯的高效催化剂。最佳反应条件下乙醇转化率达96%,酯化选择性100%。催化剂的高活性是由于HPW在活性炭上高度分散,使活性位增多,有效酸量增大。HPW/C还具有热稳定性高和不易流失等优点。 相似文献
29.
Chee Sing Yap 《The Journal of the Operational Research Society》1989,40(7):649-658
This paper describes three case studies which investigated issues relating to the implementation and management of advanced information technology. The benefits derived from information technology were found to vary from one organization to another. These studies provide further evidence to support earlier research findings that senior management has an important role to play in the effective exploitation of information technology, and that the investment approach taken by an organization has a significant effect on the development of computer-based information systems. The effectiveness of a system depends not only on applying the appropriate technology, but also on how successfully technical and behavioural issues are resolved. 相似文献
30.
采用密度泛涵理论(density functional theory,DFT)中的广义梯度近似(generally gradient approximation,GGA)对富勒烯C72和内掺金属La富勒烯La2@C72三种同分异构体的几何结构和电子结构进行研究.发现在C72的三种同分异构体中,满足独立五边形规则(isolated-pentagon-rule,IPR)的C72(D6d)结构最为稳定;在La2@C72三种同分异构体中,有着两对两两相邻五元环(twofused-pentagon)的La2@C72(#10611)结构最为稳定,而满足IPR的La2@C72(D6d)的结构变成了最不稳定结构.从能级图和态密度图分析得知,笼子稳定性的变化与La原子的原子轨道与C72原子轨道之间的杂化有关.Mulliken电荷分析得知,La2@C72(#10611)的两个La原子共转移了约3个电子给C72,并且,它们几乎分布在整个C笼上,形成的电子结构为La23+@C3-72.净自旋分析得知,La2@C72(#10611)中La原子磁性完全淬灭. 相似文献