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21.
A theoretical interpretation of the reduction in E2 strengths in 126Ba prior to backbending is presented. A shell model basis is built from normal parity orbilals organized into multiplets of a pseudo SU(3) symmetry coupled to configurations restricted to states of seniority zero and two. Within the framework of the model the scattering of a pair of protons from normal parity to the orbital produces band crossing and a corresponding reduction in E2 transition strengths prior to pair alignment which is the principal mechanism of the backbending. 相似文献
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Silica samples (type III, Corning 7940) were implanted with N using multiple energies to produce a layer ∼600 nm thick in which the concentration of N was constant to within ±5%. The optical absorption spectra of the samples were measured from 1.8 to 6.5 eV. Electron paramagnetic resonance (EPR) measurements were made at ∼20.3 and 33 GHz for sample temperatures ranging from 77 K to 100 K for most measurements. The components identified in the EPR spectra, based on comparison with reported parameters, were due to E′ centers and peroxy radicals. By comparing the changes in the optical absorption at 5.85 eV with the changes in the concentrations of the various EPR components and with the reports in the literature, we conclude that there is an additional band at 5.7-5.9 eV other than the E′ center band. We conclude that the bands between 2 and 6.5 eV and the EPR spectral components produced by implantation of N are due to radiation damage processes; neither optical bands nor EPR components related to N are detected. 相似文献
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Robin B. Bedford Michael Betham Jonathan P.H. Charmant Amanda L. Weeks 《Tetrahedron》2008,64(26):6038-6050
The amination of 2-chloroanilines with aryl bromides and subsequent intramolecular direct arylation can be exploited in the synthesis of a range of fluorinated carbazoles, where the fluorine substituent can be introduced via the aniline, the aryl bromide or both substrates. Depending on substitution patterns, the two steps can either be performed in tandem in one-pot under microwave heating conditions or else require a two pot approach. 相似文献
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We propose a simplified version of local molecular field (LMF) theory to treat Coulomb interactions in simulations of ionic fluids. LMF theory relies on splitting the Coulomb potential into a short-ranged part that combines with other short-ranged core interactions and is simulated explicitly. The averaged effects of the remaining long-ranged part are taken into account through a self-consistently determined effective external field. The theory contains an adjustable length parameter sigma that specifies the cutoff distance for the short-ranged interaction. This can be chosen to minimize the errors resulting from the mean-field treatment of the complementary long-ranged part. Here we suggest that in many cases an accurate approximation to the effective field can be obtained directly from the equilibrium charge density given by the Debye theory of screening, thus eliminating the need for a self-consistent treatment. In the limit sigma-->0, this assumption reduces to the classical Debye approximation. We examine the numerical performance of this approximation for a simple model of a symmetric ionic mixture. Our results for thermodynamic and structural properties of uniform ionic mixtures agree well with similar results of Ewald simulations of the full ionic system. In addition, we have used the simplified theory in a grand-canonical simulation of a nonuniform ionic mixture where an ion has been fixed at the origin. Simulations using short-ranged truncations of the Coulomb interactions alone do not satisfy the exact condition of complete screening of the fixed ion, but this condition is recovered when the effective field is taken into account. We argue that this simplified approach can also be used in the simulations of more complex nonuniform systems. 相似文献
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Atomic force microscopy (AFM) has been successfully used to study the activation energy for evaporation of pentaerythritol tetranitrate (PETN) nanoislands formed by spin coating. These islands are annealed isothermally in the temperature range of 30-70 degrees C for a given time and are scanned with AFM in contact mode at room temperature. The volume of these islands does not change significantly up to about 35-40 degrees C indicating that sublimation is not significant below 40 degrees C. Above 40 degrees C, the islands start shrinking, and the rate of weight loss is analyzed as a function of temperature. The activation energy of evaporation using AFM was found to be similar to that for bulk PETN crystals using thermogravimetric analysis (TGA) at higher temperatures (110-135 degrees C). These results demonstrate that AFM is a useful tool to measure thermodynamic properties with a nanoscale probe. 相似文献
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