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101.
Yablokov M. Yu. Shchegolikhin A. N. Lebedev O. V. Goncharuk G. P. Ozerin A. N. 《Russian Chemical Bulletin》2021,70(9):1816-1821
Russian Chemical Bulletin - Gradient polymer composites were prepared by melt-mixing of carbon black and polypropylene in a compounder and subsequent hot pressing of pellets. The thermally treated... 相似文献
102.
Optics and Spectroscopy - The influence of symmetry breaking caused by charge transfer in excited quadrupole molecules of the D-π-A-π-D or A-π-D-π-A type, where A and D are the... 相似文献
103.
Journal of Structural Chemistry - Thermodynamic characteristics are calculated for aqueous alkanolamine solutions that are obtained by substituting alkyl radicals for the protons in the amino group... 相似文献
104.
Kuntsevich A. Yu. Rybal’chenko G. V. Martovitskii V. P. Bannikov M. I. Selivanov Yu. G. Gavrilkin S. Yu. Tsvetkov A. Yu. Chizhevskii E. G. 《JETP Letters》2020,111(3):151-156
JETP Letters - A structural reason for superconductivity in a Cu-, Sr-, or Nb-atom-doped Bi2Se3 topological insulator is still unclear. To understand this reason, a codoping approach has been... 相似文献
105.
Turyanskiy A. G. Vorob’ev N. S. Gizha S. S. Makushina V. A. Mikhal’kov Yu. M. Smirnov A. V. Pirshin I. V. Senkov V. M. Shashkov E. V. Fishman R. I. Ziyatdinova M. Z. Komel’kov A. S. 《JETP Letters》2020,112(11):734-738
JETP Letters - The possibility of stable generation of intense characteristic Cs radiation upon electronic excitation of a Mo anode target heat treated in Cs and O2 vapors is demonstrated. The... 相似文献
106.
Experimental Mechanics - There have been relatively few studies on mechanical properties of nanomaterials under high strain rates, mainly due to the lack of capable nanomechanical testing devices.... 相似文献
107.
108.
Immobilized Catalysts for Iridium‐Catalyzed Allylic Amination: Rate Enhancement by Immobilization 下载免费PDF全文
Dr. Chandi C. Malakar Prof. Dr. Günter Helmchen 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(19):7127-7134
The first immobilized catalyst for Ir‐catalyzed asymmetric allylic aminations is described. The catalyst is a cationic (π‐allyl)Ir complex bound by cation exchange to an anionic silica gel support. Preparation of the catalyst is facile, and the supported catalyst displayed considerably enhanced activity compared with the parent homogeneous catalyst. Up to 43 consecutive amination runs were possible in recycling experiments. 相似文献
109.
Gelikonov G. V. Ksenofontov S. Yu. Shilyagin P. A. Gelikonov V. M. 《Radiophysics and Quantum Electronics》2019,62(3):228-236
Radiophysics and Quantum Electronics - We propose and experimentally test a numerical method for correction of the influence of fluctuations in the distance to objects during noncontact probing in... 相似文献
110.
Roberto Morales-Cerrada Dr. Christophe Fliedel Dr. Jean-Claude Daran Dr. Florence Gayet Dr. Vincent Ladmiral Dr. Bruno Améduri Prof. Rinaldo Poli 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(1):296-308
Thermal decarbonylation of the acyl compounds [Mn(CO)5(CORF)] (RF=CF3, CHF2, CH2CF3, CF2CH3) yielded the corresponding alkyl derivatives [Mn(CO)5(RF)], some of which have not been previously reported. The compounds were fully characterized by analytical and spectroscopic methods and by several single-crystal X-ray diffraction studies. The solution-phase IR characterization in the CO stretching region, with the assistance of DFT calculations, has allowed the assignment of several weak bands to vibrations of the [Mn(12CO)4(eq-13CO)(RF)] and [Mn(12CO)4(ax-13CO)(RF)] isotopomers and a ranking of the RF donor power in the order CF3<CHF2<CH2CF3≈CF2CH3. The homolytic Mn−RF bond cleavage in [Mn(CO)5(RF)] at various temperatures under saturation conditions with trapping of the generated RF radicals by excess tris(trimethylsilyl)silane yielded activation parameters ΔH≠ and ΔS≠ that are believed to represent close estimates of the homolytic bond dissociation thermodynamic parameters. These values are in close agreement with those calculated in a recent DFT study (J. Organomet. Chem. 2018 , 864, 12–18). The ability of these complexes to undergo homolytic Mn−RF bond cleavage was further demonstrated by the observation that [Mn(CO)5(CF3)] (the compound with the strongest Mn−RF bond) initiated the radical polymerization of vinylidene fluoride (CH2=CF2) to produce poly(vinylidene fluoride) in good yields by either thermal (100 °C) or photochemical (UV or visible light) activation. 相似文献