全文获取类型
收费全文 | 511篇 |
免费 | 19篇 |
国内免费 | 4篇 |
专业分类
化学 | 290篇 |
晶体学 | 1篇 |
力学 | 20篇 |
数学 | 29篇 |
物理学 | 194篇 |
出版年
2023年 | 2篇 |
2021年 | 8篇 |
2020年 | 8篇 |
2019年 | 6篇 |
2018年 | 9篇 |
2017年 | 4篇 |
2016年 | 12篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 25篇 |
2012年 | 31篇 |
2011年 | 30篇 |
2010年 | 16篇 |
2009年 | 17篇 |
2008年 | 25篇 |
2007年 | 29篇 |
2006年 | 26篇 |
2005年 | 22篇 |
2004年 | 24篇 |
2003年 | 30篇 |
2002年 | 15篇 |
2001年 | 6篇 |
2000年 | 11篇 |
1999年 | 5篇 |
1998年 | 4篇 |
1997年 | 3篇 |
1996年 | 8篇 |
1995年 | 10篇 |
1994年 | 6篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 3篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 5篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 12篇 |
1977年 | 4篇 |
1976年 | 13篇 |
1975年 | 3篇 |
1974年 | 2篇 |
1973年 | 6篇 |
1970年 | 3篇 |
排序方式: 共有534条查询结果,搜索用时 928 毫秒
101.
Four cubane-like Cu4I4 units are assembled around an iodine atom to form the giant, mixed-valent Cu(II)Cu(I)15I17 cluster. The Cu(II)Cu(I)15I17 cluster and a bipyrazole linker form a 3D open framework with paramagnetic and thermochromic properties. This paper also touches on the resemblance of this cluster to the self-similar object of a Sierpinski tetrahedron. 相似文献
102.
Constructing Interfacial Energy Transfer for Photon Up‐ and Down‐Conversion from Lanthanides in a Core–Shell Nanostructure 下载免费PDF全文
Dr. Bo Zhou Dr. Lili Tao Dr. Yang Chai Prof. Shu Ping Lau Prof. Qinyuan Zhang Dr. Yuen Hong Tsang 《Angewandte Chemie (International ed. in English)》2016,55(40):12356-12360
We report a new mechanistic strategy for controlling and modifying the photon emission of lanthanides in a core–shell nanostructure by using interfacial energy transfer. By taking advantage of this mechanism with Gd3+ as the energy donor, we have realized efficient up‐ and down‐converted emissions from a series of lanthanide emitters (Eu3+, Tb3+, Dy3+, and Sm3+) in these core–shell nanoparticles, which do not need a migratory host sublattice. Moreover, we have demonstrated that the Gd3+‐mediated interfacial energy transfer, in contrast to energy migration, is the leading process contributing to the photon emission of lanthanide dopants for the NaGdF4@NaGdF4 core–shell system. Our finding suggests a new direction for research into better control of energy transfer at the nanometer length scale, which would help to stimulate new concepts for designing and improving photon emission of the lanthanide‐based luminescent materials. 相似文献
103.
104.
Xiu Min REN Kai Man TSANG 《数学学报(英文版)》2007,23(2):265-280
In this paper, it is proved that with at most O(N65/66) exceptions, all even positive integers up to N are expressible in the form p^2 2+p^3 3+p^4 4+p^5 5. This improves a recent result O(N19193/19200+ε) due to C. Bauer. 相似文献
105.
R. S. Chen D. G. Fang K. F. Tsang Edward K. N. Yung 《International Journal of Infrared and Millimeter Waves》2000,21(9):1541-1560
An effective wavelet based multigrid preconditioned conjugate gradient method is developed to solve electromagnetic large matrix problem for millimeter wave scattering application. By using wavelet transformation we restrict the large matrix equation to a relative smaller matrix and which can be solved rapidly. The solution is prolonged as the new improvement for the conjugate gradient (CG) method. Numerical results show that our developed wavelet based multigrid preconditioned CG method can reach large improvement of computational complexity. Due to the automaticity of wavelet transformation, this method is potential to be a block box solver without physical background. 相似文献
106.
Synthesis of Unsymmetric Bipyridine–PtII–Alkynyl Complexes through Post‐Click Reaction with Emission Enhancement Characteristics and Their Applications as Phosphorescent Organic Light‐Emitting Diodes 下载免费PDF全文
Dr. Yongguang Li Dr. Daniel Ping‐Kuen Tsang Dr. Carmen Ka‐Man Chan Dr. Keith Man‐Chung Wong Dr. Mei‐Yee Chan Prof. Dr. Vivian Wing‐Wah Yam 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(42):13710-13715
Two unsymmetric bipyridine–platinum(II)–alkynyl complexes have been synthesised by a post‐click reaction. These metal complexes are found to exhibit emission enhancement properties. The photoluminescence quantum yield can be significantly increased from 0.03 in solution to 0.72 in solid‐state thin films. Efficient solution‐processable organic light‐emitting diodes have been fabricated by utilizing these complexes as phosphorescent dopants. A high external quantum efficiency of up to 5.8 % has been achieved. 相似文献
107.
Wu Zhou Zunyue Zhang Hao Chen Hon Ki Tsang Yeyu Tong 《Laser \u0026amp; Photonics Reviews》2024,18(4):2300460
Space-division multiplexing (SDM) is one of the key enabling technologies to increase the capacity of fiber communication systems. However, implementing SDM-based systems using multimode fiber has been challenging with the need for compact, low-cost, and scalable mode de/multiplexer (DE/MUX). Here a novel integrated mode MUX for few-mode fibers (FMFs) is presented which can launch up to eight spatial and polarization channels. The new design is composed of a 2D multimode grating coupler (MMGC), highly compact spot size converters (SSCs), and adiabatic directional couplers (ADCs). Eight data lanes in FMFs can be selectively launched with integrated optical phase shifters. Experimental results reveal efficient chip-to-fiber coupling with peak efficiencies of −3.8, −5.5, −3.6, and −4.1 dB for LP01, LP11a, LP11b, and LP21b modes, respectively. Thanks to the use of an integrated subwavelength Mikaelian lens for mode-independent field size conversion with loss ≤−0.25 dB, the total footprint of the MMGC and SSCs is only 35×35 µm2. The proposed design shows great potential for densely integrated photonic circuits in future SDM applications. 相似文献
108.
Swarna A. Gamage Julie A. Spicer Kit Y. Tsang Patrick D. O'Connor Jack U. Flanagan Woo‐Jeong Lee James M. J. Dickson Peter R. Shepherd William A. Denny Gordon W. Rewcastle 《化学:亚洲杂志》2019,14(8):1249-1261
Using a scaffold‐hopping approach, imidazo[1,2‐a]pyridine analogues of the ZSTK474 (benzimidazole) class of phosphatidylinositol 3‐kinase (PI3K) inhibitors have been synthesized for biological evaluation. Compounds were prepared using a heteroaryl Heck reaction procedure, involving the palladium‐catalysed coupling of 2‐(difluoromethyl)imidazo[1,2‐a]pyridines with chloro, iodo or trifluoromethanesulfonyloxy (trifloxy) substituted 1,3,5‐triazines or pyrimidines, with the iodo intermediates being preferred in terms of higher yields and milder reaction conditions. The new compounds maintain the PI3K isoform selectivity of their benzimidazole analogues, but in general show less potency. 相似文献
109.
We report the synthesis and characterization of luminescent rhenium(I) amidodipyridoquinoxaline biotin complexes [Re(CO)3(dpqa)(L)](PF6) (dpqa = 2-(n-butylamido)dipyrido[3,2-f:2',3'-h]quinoxaline; L = 4-(biotinamidomethyl)pyridine (py-4-CH2-NH-biotin) (1), 3-(N-((2-biotinamido)ethyl)amido)pyridine (py-3-CO-NH-en-NH-biotin) (2), 4-(N-((6-biotinamido)hexanoyl)aminomethyl)pyridine (py-4-CH2-NH-cap-NH-biotin) (3)), and their biotin-free counterpart [Re(CO)3(dpqa)(py)](PF6) (py = pyridine (4)). Upon irradiation, these complexes exhibited intense triplet metal-to-ligand charge-transfer (3MLCT) (dpi(Re) --> pi(dpqa)) emission in fluid solutions at 298 K and in alcohol glass at 77 K. However, the emission became much weaker in aqueous buffer, probably due to the interactions of water molecules with the amide substituent of the dpqa ligand. These properties render the complexes good candidates as luminescent probes for hydrophobic media, such as the substrate-binding sites of proteins. The avidin-binding properties of the new biotin complexes have been studied by 4'-hydroxyazobenzene-2-carboxylic acid (HABA) assays, emission titrations, and competitive association and dissociation assays. Most importantly, the complexes showed a profound increase in emission intensities upon binding to avidin. Additionally, we found that the fluorescence of anthracene was quenched by these rhenium(I) complexes, and the 3MLCT emission of the complexes was also quenched by anthracene. On the basis of these findings, new homogeneous assays for biotin using these complexes, avidin, and anthracene-labeled avidin have been designed. 相似文献
110.
Neverov AA Lu ZL Maxwell CI Mohamed MF White CJ Tsang JS Brown RS 《Journal of the American Chemical Society》2006,128(50):16398-16405
The catalytic ability of a dinuclear Zn2+ complex of 1,3-bis-N1-(1,5,9-triazacyclododecyl)propane (3) in promoting the cleavage of an RNA model, 2-hydroxypropyl-p-nitrophenyl phosphate (HPNPP, 1), and a DNA model, methyl p-nitrophenyl phosphate (MNPP, 4), was studied in methanol solution in the presence of added CH3O- at 25 degrees C. The di-Zn2+ complex (Zn2 :3), in the presence of 1 equiv of added methoxide, exhibits a second-order rate constant of (2.75 +/- 0.10) x 10(5) M(-1) s(-1) for the reaction with 1 at s(s)pH 9.5, this being 10(8)-fold larger than the k2 value for the CH3O- promoted reaction (kOCH3 = (2.56 +/- 0.16) x 10(-3) M(-1) s(-1)). The complex is also active toward the DNA model 4, exhibiting Michaelis-Menten kinetics with a KM and kmax of 0.37 +/- 0.07 mM and (4.1 +/- 0.3) x 10(-2) s(-1), respectively. Relative to the background reactions at s(s)pH 9.5, Zn2 :3 accelerates cleavage of each phosphate diester by a remarkable factor of 1012-fold. A kinetic scheme common to both substrates is discussed. The study shows that a simple model system comprising a dinuclear Zn2+ complex and a medium effect of the alcohol solvent achieves a catalytic reactivity that approaches enzymatic rates and is well beyond anything seen to date in water for the cleavage of these phosphate diesters. 相似文献