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排序方式: 共有428条查询结果,搜索用时 31 毫秒
91.
Saptarshi Chakraborty Dr. Shinto Varghese Prof. Dr. Suhrit Ghosh 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16725-16731
Oligothiophene derivatives have been extensively studied as p-type semiconducting materials in organic electronics applications. This work reports the synthesis, self-assembly and photophysical properties of acceptor–donor–acceptor (A–D–A)-type oligothiophene derivatives by end-group engineering of quaterthiophene (QT) with naphthalene monoimide (NMI) chromophores that are further connected to a trialkoxy benzamide wedge. Conjugation to the NMI units reduces the HOMO–LUMO gap significantly, and consequently the absorption spectrum exhibits a bathochromic shift of about 50 nm compared with QT. Furthermore, extended H-bonding interactions among the amido groups of the peripheral wedges produce entangled fibrillar nanostructures and gelation in hydrocarbon solvents such as methylcyclohexane, wherein the A–D–A chromophore exhibits typical H-aggregation. On the contrary, the fact that the same chromophore, lacking only the amido units, does not produce gels or H-aggregates indicates strong impact of H-bonding on the self-assembly. Computational studies revealed the electronic properties of the chromophore and predicted the geometry of a dimer in the H-aggregate that reasonably matches with the experimental results. Bulk electrical conductivity measurements determined an excellent conductivity of 2.3×10−2 S cm−1 for the H-aggregated system (OT-1), which is two orders of magnitude higher than that of the same chromophore lacking the amido groups (OT-2). 相似文献
92.
The influence of iodine on the electrical properties of sandwich structures of magnesium phthalocyanine (Mg Pc) thin films
with gold and aluminium electrodes has been investigated. The various electrical properties and different electrical parameters
of the iodine-doped Mg Pc thin film devices have been estimated and compared with the values of normal Mg Pc devices from
the analysis of the current-voltage characteristics. Generally samples showed an asymmetric conductivity both under forward
and reverse bias. From our study we found that iodine doped Mg Pc films showed an enhanced electrical conductivity of nearly
ten times that of typical Mg Pc. At low voltages the films showed an ohmic conduction with a hole concentration of P0 = 6.34 × 1018 m−3 and hole mobility μ = 9.16 × 10−5 m 2 V−1 s−1, whereas at higher voltage levels the conduction is dominated by space charged limited conduction (SCLC) with a discrete
trapping level of 1.33 × 1022 m−3 at 0.63 eV above the valance band edge. The ratio of the free charges to trapped charges (trapping factor) for the doped
samples was found to be 1.07 × 10−7. Furthermore the reverse conduction mechanisms have also been investigated. From the current limitations in the reverse condition
a strong rectifying behaviour was evident which was attributed to Poole-Frankel emission with a field-lowering coefficient
of value 2.24 × 10−5 eV m1/2 V−1/2. 相似文献
93.
Samuel Varghese Muhammed Iqbal Suresh Nair V. P. N. Nampoori C. P. G. Vallabhan 《Fiber and Integrated Optics》2007,26(5):245-254
A new method for the fabrication of a monolithic 1 × 4 single-mode fused coupler is described together with details of its performance in terms of coupling ratio, spectral response and polarization sensitivity. The fabricated device exhibits ultra-broadband performance with low polarization dependent loss. The coupling pattern exhibits identical coupling to all interacting fibers, enabling an easy control on fabrication parameters of the device. 相似文献
94.
95.
N C Soni Ram Prasad Ashok Mohan M D Vora S Banerjee C V Tomy S K Malik H S Yadav K R K Rao 《Pramana》1989,32(6):801-809
Superconducting oxide-copper monoliths have been fabricated by shock-wave loading using cylindrical and plane geometries.
Bulk densities up to 96% T.D. have been obtained by varying detonation parameters. The superconducting properties, interface
bonding and microstructure of the compacts have been evaluated. 相似文献
96.
The reaction of H2S gas with an aqueous solution of ammonium heptamolybdate in the presence of 1,4-diazabicyclo-2,2,2-octane (DABCO) led to the formation of a red colored complex. The complex was recrystallized in hot water and characterized by elemental analysis and UV-Visible, FT-IR, and 1H NMR spectroscopy. The single sharp peak in the 1H NMR spectrum has revealed that all the methylene protons are equivalent due to the hydrogen resonating between the two nitrogens in the DABCO cation. The complex crystallizes in a cubic system with space group P213, a = 10.9482(9) Å, α = 90°, V = 1325.3(7) Å3, R
3 = 0.0154, wR
2 = 0.038, Z = 4. The structure consists of the tetrahedral tetrathiomolybdate anions, which form an extended three-dimensional network in the solid state involving Mo-S...H-N hydrogen bonding interactions with DABCO and the ammonium cation.Original Russian Text Copyright © 2004 by S. Pokhrel, K. S. Nagaraja, B. Varghese__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 945–949, September–October, 2004. 相似文献
97.
98.
A method utilizing solvent extraction and analysis by gas chromatography-positive chemical ionization mass spectrometry (SE-GC-PCIMS) was developed for the analysis of three neutral hydrophobic perfluorooctanesulfonamide compounds [perfluorooctanesulfonamide (PFOSA), N-ethyl perfluorooctanesulfonamide (N-EtPFOSA), and N,N-diethyl perfluorooctanesulfonamide (N,N-Et2PFOSA)]. These compounds are suspected metabolic precursors of perfluorooctane sulfonate. The SE-GC-PCI-MS method was used to analyze all three perfluorooctanesulfonamides in fast food, fish, and Arctic marine mammal liver samples. The SE-GC-PCI-MS method produced relatively higher recoveries of the analytes (averaging 83 +/- 6%, 84 +/- 9%, and 89 +/- 19% for N,N-Et2PFOSA, N-EtPFOSA, and PFOSA, respectively) with lower coefficients of variation, and less susceptibility to matrix effects, than ion pair extraction-liquid chromatography-tandem mass spectrometric methods. Method detection limits (MDLs) were 100, 120, and 250 pg/g for N,N-Et2PFOSA, N-EtPFOSA, and PFOSA, respectively. The three compounds were found at concentrations ranging from below the MDL to 22 ng/g wet weight in fast food, fish, and Arctic marine mammal liver samples. 相似文献
99.
100.
[reaction: see text] Polysubstituted propadienes are obtained in good to excellent yields by the consecutive carbocupration-homologation-beta-elimination reactions on the easily accessible alkynyl sulfoxides or sulfones. This one-pot reaction also allows the preparation of functionalized allenes. 相似文献