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61.
Muniz-Miranda M Del Rosso T Giorgetti E Margheri G Ghini G Cicchi S 《Analytical and bioanalytical chemistry》2011,400(2):361-367
We investigated the chemisorption of self-assembled monolayers of sulfur-functionalized 4-amino-7-nitrobenzofurazan on gold
and silver nanoisland films (NIFs) by means of surface-enhanced fluorescence (SEF) and surface-enhanced Raman scattering (SERS).
The ligand is a push–pull molecule, where an intramolecular charge transfer occurs between an electron-donor and an electron-acceptor
group, thus exhibiting nonlinear optical properties that are related to both SERS and SEF effects. The presence of different
heteroatoms in the molecule ensures the possibility of chemical interaction with both silver and gold substrates. The SERS
spectra suggest that furazan is bound to silver via lone pairs of the nitrogen atoms, whereas the ligand is linked to gold
via a sulfur atom. Silver NIFs provide more efficient enhancement of both fluorescence and Raman scattering in comparison
with gold NIFs. The present SEF and SERS investigation could provide useful information for foreseeing changes in the nonlinear
responses of this push–pull molecule. 相似文献
62.
Tommaso Leonori Francesco Petitta 《Calculus of Variations and Partial Differential Equations》2011,42(1-2):153-187
In this paper we deal with local estimates for parabolic problems in ${\mathbb{R}^N}$ with absorbing first order terms, whose model is $$\left\{\begin{array}{l@{\quad}l}u_t- \Delta u +u |\nabla u|^q = f(t,x) \quad &{\rm in}\, (0,T) \times \mathbb{R}^N\,,\\u(0,x)= u_0 (x) &{\rm in}\, \mathbb{R}^N \,,\quad\end{array}\right.$$ where ${T >0 , \, N\geq 2,\, 1 < q \leq 2,\, f(t,x)\in L^1\left( 0,T; L^1_{\rm loc} \left(\mathbb{R}^N\right)\right)}$ and ${u_0\in L^1_{\rm loc}\left(\mathbb{R}^{N}\right)}$ . 相似文献
63.
Salice P Maity P Rossi E Carofiglio T Menna E Maggini M 《Chemical communications (Cambridge, England)》2011,47(32):9092-9094
This communication demonstrates a straightforward continuous-flow method for efficient exohedral functionalisation of carbon nanotubes which affords soluble samples in a much shorter time over conventional batch processing. 相似文献
64.
Tommaso Moraschini 《Annals of Pure and Applied Logic》2019,170(7):805-824
We prove that the problem of determining whether a finite logical matrix determines an algebraizable logic is complete for EXPTIME. The same result holds for the classes of order algebraizable, weakly algebraizable, equivalential and protoalgebraic logics. Finally, the same problem for the class of truth-equational logic is shown to be hard for EXPTIME. 相似文献
65.
Paolo Gibilisco Tommaso Isola 《Annals of the Institute of Statistical Mathematics》2007,59(1):147-159
A family of inequalities, related to the uncertainty principle, has been recently proved by S. Luo, Z. Zhang, Q. Zhang, H.
Kosaki, K. Yanagi, S. Furuichi and K. Kuriyama. We show that the inequalities have a geometric interpretation in terms of
quantum Fisher information. Using this formulation one may naturally ask if this family of inequalities can be further extendend,
for example to the RLD quantum Fisher information. We show that this is impossible by producing a family of counterexamples. 相似文献
66.
67.
The B-spline density-functional method has been applied to the conformers of the (1R, 2R)-1,2-dibromo-1,2-dichloro-1,2-difluoroethane molecule. The cross section, asymmetry, and dichroic parameters relative to core and valence orbitals, which do not change their nature along the conformational curve, have been systematically studied. While the cross section and the asymmetry parameter are weakly affected, the dichroic parameter appears to be rather sensitive to the particular conformer of the molecule, suggesting that this dynamical property could be a useful tool for conformational analysis. The computational method has also been applied to methyl rotation in methyloxirane. Unexpected and dramatic sensitivity of the dichroic-parameter profile to the methyl rotation, both in the core and valence states, has been found. Boltzmann averaging over the conformers reproduces quite closely the profiles previously obtained for the minimum-energy conformation, which is in good agreement with the experimental results. 相似文献
68.
Tommaso Pacini 《Transactions of the American Mathematical Society》2003,355(8):3343-3357
Given a compact Riemannian manifold together with a group of isometries, we discuss MCF of the orbits and some applications: e.g., finding minimal orbits. We then specialize to Lagrangian orbits in Kaehler manifolds. In particular, in the Kaehler-Einstein case we find a relation between MCF and moment maps which, for example, proves that the minimal Lagrangian orbits are isolated.
69.
70.