全文获取类型
收费全文 | 1892篇 |
免费 | 85篇 |
国内免费 | 8篇 |
专业分类
化学 | 1360篇 |
晶体学 | 19篇 |
力学 | 74篇 |
数学 | 291篇 |
物理学 | 241篇 |
出版年
2023年 | 18篇 |
2022年 | 14篇 |
2021年 | 42篇 |
2020年 | 55篇 |
2019年 | 41篇 |
2018年 | 31篇 |
2017年 | 25篇 |
2016年 | 55篇 |
2015年 | 50篇 |
2014年 | 68篇 |
2013年 | 118篇 |
2012年 | 127篇 |
2011年 | 169篇 |
2010年 | 76篇 |
2009年 | 77篇 |
2008年 | 134篇 |
2007年 | 130篇 |
2006年 | 108篇 |
2005年 | 109篇 |
2004年 | 94篇 |
2003年 | 95篇 |
2002年 | 104篇 |
2001年 | 22篇 |
2000年 | 16篇 |
1999年 | 22篇 |
1998年 | 26篇 |
1997年 | 27篇 |
1996年 | 21篇 |
1995年 | 12篇 |
1994年 | 12篇 |
1993年 | 10篇 |
1992年 | 8篇 |
1991年 | 7篇 |
1989年 | 9篇 |
1988年 | 4篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1985年 | 8篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 4篇 |
1981年 | 4篇 |
1980年 | 3篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1976年 | 3篇 |
1974年 | 2篇 |
1895年 | 1篇 |
1887年 | 2篇 |
排序方式: 共有1985条查询结果,搜索用时 256 毫秒
11.
Catherine Cordier-Robert Thierry Grosdidier Gang Ji Jacques Foct 《Hyperfine Interactions》2006,168(1-3):951-957
Microstructured (atomized) and nanostructured (milled) Fe60Al40 powders together with their corresponding coatings synthesized by High Velocity Oxy-fuel (HVOF) or Atmospheric Plasma Spray (APS) thermal spraying techniques have been characterized by Mössbauer Spectroscopy (MS) and X-ray Diffraction (XRD). The evolution of the microstructure and the atomic ordering degree in the powders and coatings are discussed at the light of the various processing conditions. The operational correlation between the parameters of the duplex morphology of coatings and the processing parameters is discussed. 相似文献
12.
We show that there is a threshold in energy for the onset of chaos in cosmology for the Universe described as a dynamical system derived from the Einstein equations of General Relativity (GR). In the case of the mixmaster model (homogeneous and anisotropic cosmology with a Bianchi IX metric), the chaos occurs precisely at the prescribed necessary value H
vac=0 of the GR for the energy of the Universe while the system is found to be regular for H<0 and chaotic for H>0 with respect to its pure vacuum part. In the case of generalized scalar tensor theories within the Bianchi IX model, we show using the ADM formalism and a conformal transformation that the energy of the dynamical system as compared to vacuum lies below the zero energy threshold. The system is thus not exhibiting chaos and the conclusion still holds in the presence of ordinary matter as well. The suppression of chaos occurs in a similar way for stiff matter alone. 相似文献
13.
Sedimentation and erosion processes in sedimentary basins can be modeled by a parabolic equation with a limiter on the fluxes and a constraint on the time variation.This limiter happens to satisfy a stationary scalar hyperbolic inequality,within a constraint,for which the authors prove the existence and the uniqueness of the solution.Actually,this solution is shown to be the maximal element of a convenient convex set of functions.The existence proof is obtained thanks to the use of a numerical scheme. 相似文献
14.
The synthesis of tocopherol fatty alcohols (TFAs), potent microglial activation modulators, was achieved via C-alkylation of trimethylhydroquinone. Several analogs, in particular water-soluble prodrugs, have been synthesized using a Wittig reaction and their antioxidant activities have been evaluated. 相似文献
15.
Frédéric Coquel Thierry Gallouët Jean-Marc Hérard Nicolas Seguin 《Comptes Rendus Mathematique》2002,334(10):927-932
Closure laws for interfacial pressure and interfacial velocity are proposed within the frame work of two-pressure two-phase flow models. These enable us to ensure positivity of void fractions, mass fractions and internal energies when investigating field by field waves in the Riemann problem. To cite this article: F. Coquel et al., C. R. Acad. Sci. Paris, Ser. I 334 (2002) 927–932. 相似文献
16.
Thierry Woignier G. Pochet H. Doumenc P. Dieudonné L. Duffours 《Journal of Sol-Gel Science and Technology》2007,41(1):25-30
Volcanic (allophanic) soils are interesting in terms of the control of the greenhouse effect and the knowledge of the porous
features is of importance to understand the mechanism of C and N sequestration. These soils contain a peculiar clay: allophane
aggregates quite close to the synthetic mineral gels aggregates. These volcanic materials behave as gels during drying with
a large irreversible shrinkage that can modify the soil physical properties. Consequently, as for silica gels, we use the
CO2 supercritical drying procedure (SD) to control the drying step and to preserve the structural and textural properties of
the soils. The experimental results show that the N and C content in the soils is clearly dependent on the allophane content.
We also show that the textural properties, such as specific surface area, are higher for the supercritically dried samples,
compared to the classically dried samples, and SAXS results confirm the preserving effect of the SD. With these data, we propose
possible effects of the specific surface area on the C and N content of the allophanic soils. 相似文献
17.
18.
Dominique Margelin Anny Fourtanier Thierry Thevenin Chantal Medaisko Monique Breton Jacques Picard 《Photochemistry and photobiology》1993,58(2):211-218
Abstract— The effect of UVB exposure on the distribution and synthesis of dermal proteoglycans was measured in the skin of hairless mice. Two groups of mice were included: one was irradiated for 10 weeks; the other was kept as control. After intraperitoneal injection of sodium 35 S-sulfate, punch biopsies were taken for histology and proteoglycans were extracted from the remaining skin with 4 M guanidinium chloride, containing 3–[(3-cholamidopropyl)dimethylammonio]-1-propanesulfonate (0.5%, weight per volume). Following proteolytic digestion, the glycosaminoglycan constituents were isolated and analyzed by quantitative cellulose acetate electrophoresis and enzymatic digestibility.
Under the influence of UVB radiation, newly synthesized proteoglycans measured by35 SO4 uptake increased as much as 60%. In addition, the irradiated skin had a higher average content of proteoglycan than had control skin (4981 μg vs 4134 μg/g dry weight). This could be ascribed to an increase in heparin (1400 vs 533 μ g/g dry weight) and heparan sulfate (472 vs 367 μg/g dry weight), whereas no change in the concentration of hyaluronic acid (1243 vs 1372 μg/g dry weight) and dermatan sulfate (1866 vs 1863 μg/g dry weight) was observed. The irradiated animals also exhibited a marked increase in the synthesis of heparan sulfate and heparin (62% and 71%, respectively). These results demonstrate that chronic doses of UVB altered proteoglycan metabolism through both quantitative and qualitative changes. 相似文献
Under the influence of UVB radiation, newly synthesized proteoglycans measured by
19.
Mikhael Balabane Thierry Cazenave Luis Vázquez 《Communications in Mathematical Physics》1990,133(1):53-74
We prove the existence of stationary states for nonlinear Dirac equations of the form (E) $$i\sum\limits_{\mu = 0}^3 {\gamma ^\mu \partial _\mu \psi - M\psi + F\left( {\bar \psi \psi } \right)\psi = 0,} $$ whereM>0 andF is a singular self-interaction. In particular, in the model case whereF(s)=?s ?α, for some 0<α<1, and for every ω>M, there exists a solution of (E) of the form ψ(t, x)=e iωt?(x), wherex 0=t andx=(x 1,x 2,x 3), such that ? has compact support. IF 0<α<1/3, then ? is of classC 1. If 1/3<α<1, then ? is continuously differentiable, except on some sphere {|x|=R}, where |??| is infinite. 相似文献
20.
Thierry Boulanger Daniel P. Vercauteren Guy Evrard François Durant 《Journal of chemical crystallography》1987,17(5):561-573
The crystal structure of 2-(carboxy-3-propyl)-3-amino-6-cyclohexylpyridazinium bromide has been determined by single-crystal X-ray diffraction techniques and refined by full-matrix least squares. The compound crystallized in the tri-clinic space groupP ¯1 witha=10.275(1),b=11.215(1),c=7.082(1) Å,=91.84(1),=102.21(1), =106.77(1)°, andZ=2. FinalR-factor is 0.045. The main structural results are very similar to the ones observed for the 6-phenyl analog. These two compounds are GABA-A antagonists.Ab initio molecular orbital calculations, with STO-3G and 4-31G basis sets, suggest that the exocyclic nitrogen accurately mimics the nitrogen atom of GABA. 相似文献