Selective Separation of Uranium(VI), Thorium(IV), and Lanthanum(III) from Their Aqueous Solutions using a Chelating Resin Containing Amine Functionality

A glycidyl methacrylate/divinylbenzene resin containing triethylenetetramine functional group was synthesized. The adsorption behavior of the obtained resin toward U(VI), Th(IV), and La(III) in aqueous solutions was investigated by batch and column techniques at different experimental conditions. Kinetic and thermodynamic characteristics of the adsorption process have been investigated. The regeneration of the loaded resin was also studied.     

Experimental and modeling study of ice melting

Differential scanning calorimetry (DSC) is applied to analyse the process of ice melting. Experimental results were compared to those obtained by a numerical simulation in which a conventional enthalpy formulation was applied. The effects of various parameters on the kinetics of transformations and therefore the shape of curves has been analysed and the importance of temperature gradients inside the sample evaluated.     

Energetics of phase transformations in polyethylene

The molecular mechanisms involved in the orthorhombic-to-monoclinic phase transformation in polyethylene were investigated by the computer simulation of a structure–energy map based on empirically justified intermolecular potential functions. Stable packing structures for the orthorhombic and monoclinic form were isolated as relative minima, cohesive energies were determined from the energy minima, specific chain motions involved in the transformation were identified by the minimum energy path connecting the packing minima, and the activation energy for the transformation was determined from the energy barrier along the minimum energy transformation path. The packing structure parameters predicted from the energy map were in excellent agreement with unit cell dimensions observed near 0°K. The activation energy predicted for the transformation is relatively low (～0.5 kcal/mole of ethylene at 0°K and 0.25 kcal/mole of ethylene near the melting point, 411°K). Monoclinic packing was predicted to be slightly more stable than orthorhombic. Since this result is inconsistent with a large body of observations, we propose that the intramolecular energy of chain folds plays a dominant role in establishing chain-packing geometry. The inclusion of fold-transition energetics could give rise to transformation mechanisms which differ in details from those proposed in this work.     

Comparative investigation of operational performance characteristics of axially grooved and arterial heat pipes

The thermal performance characteristics of an axially grooved heat pipe (AGHP) and an arterial heat pipe (ArHP) sharing a similar external configuration are investigated. A mathematical model is developed to predict the capillary heat transfer limit for both heat pipes. The meniscus attachment point, contact angle and liquid–vapor interfacial shear stress are taken into account in this model. In particular, for predicting the ArHP dry-out, a novel model is proposed by introducing two different failure mechanisms. The results of the mathematical model are experimentally verified.     

Integrated production planning and order acceptance under uncertainty: A robust optimization approach

The aim of this paper is to formulate a model that integrates production planning and order acceptance decisions while taking into account demand uncertainty and capturing the effects of congestion. Orders/customers are classified into classes based on their marginal revenue and their level of variability in order quantity (demand variance). The proposed integrated model provides the flexibility to decide on the fraction of demand to be satisfied from each customer class, giving the planner the choice of selecting among the highly profitable yet risky orders or less profitable but possibly more stable orders. Furthermore, when the production stage exceeds a critical utilization level, it suffers the consequences of congestion via elongated lead-times which results in backorders and erodes the firm’s revenue. Through order acceptance decisions, the planner can maintain a reasonable level of utilization and hence avoid increasing delays in production lead times. A robust optimization (RO) approach is adapted to model demand uncertainty and non-linear clearing functions characterize the relationship between throughput and workload to reflect the effects of congestion on production lead times. Illustrative simulation and numerical experiments show characteristics of the integrated model, the effects of congestion and variability, and the value of integrating production planning and order acceptance decisions.     

Improved Aerodynamics of a Hollow-Blade Axial Flow Fan by Controlling the Leakage Flow Rate by Air Injection at the Rotating Shroud

Axial flow fans are used in many fields in order to ensure the mass and heat transfer from air, chiefly in the heating, ventilation and air conditioning industry (HVAC). A more proper understanding of the airflow behavior through the systems is necessary to manage and optimize the fan operation. Computational fluid dynamics (CFD) represents a real tool providing the ability to access flow structures in areas that measuring equipment cannot reach. Reducing the leakage flow rate, inherent in operation, by synthetic-jet techniques improves performance. This paper presents the CFD results performed on a hollow blade fan developed by our team. The leakage flow is controlled by blowing air from 16 designated circular holes and arranged on the fan shroud. We discuss the results for two rotational speeds (1000 and 2000 rpm) and two injection rates (400 and 800 L/min). The numerical results consistent with the experimental show, for the low rotation speed and high injection ratio, significant gains in power (53%), torque (80%) and leakage flow rate (80%).     

Comparison of Facially Amphiphilic versus Segregated Monomers in the Design of Antibacterial Copolymers

A direct comparison of two strategies for designing antimicrobial polymers is presented. Previously, we published several reports on the use of facially amphiphilic (FA) monomers which led to polynorbornenes with excellent antimicrobial activities and selectivities. Our polymers obtained by copolymerization of structurally similar segregated monomers, in which cationic and non‐polar moieties reside on separate repeat units, led to polymers with less pronounced activities. A wide range of polymer amphiphilicities was surveyed by pairing a cationic oxanorbornene with eleven different non‐polar monomers and varying the comonomer feed ratios. Their properties were tested using antimicrobial assays and copolymers possessing intermediate hydrophobicities were the most active. Polymer‐induced leakage of dye‐filled liposomes and microscopy of polymer‐treated bacteria support a membrane‐based mode of action. From these results there appears to be profound differences in how a polymer made from FA monomers interacts with the phospholipid bilayer compared with copolymers from segregated monomers. We conclude that a well‐defined spatial relationship of the whole polymer is crucial to obtain synthetic mimics of antimicrobial peptides (SMAMPs): charged and non‐polar moieties need to be balanced locally, for example, at the monomer level, and not just globally. We advocate the use of FA monomers for better control of biological properties. It is expected that this principle will be usefully applied to other backbones such as the polyacrylates, polystyrenes, and non‐natural polyamides.     

A covariance fitting approach for correlated acoustic source mapping

Microphone arrays are commonly used for noise source localization and power estimation in aeroacoustic measurements. The delay-and-sum (DAS) beamformer, which is the most widely used beamforming algorithm in practice, suffers from low resolution and high sidelobe level problems. Therefore, deconvolution approaches, such as the deconvolution approach for the mapping of acoustic sources (DAMAS), are often used for extracting the actual source powers from the contaminated DAS results. However, most deconvolution approaches assume that the sources are uncorrelated. Although deconvolution algorithms that can deal with correlated sources, such as DAMAS for correlated sources, do exist, these algorithms are computationally impractical even for small scanning grid sizes. This paper presents a covariance fitting approach for the mapping of acoustic correlated sources (MACS), which can work with uncorrelated, partially correlated or even coherent sources with a reasonably low computational complexity. MACS minimizes a quadratic cost function in a cyclic manner by making use of convex optimization and sparsity, and is guaranteed to converge at least locally. Simulations and experimental data acquired at the University of Florida Aeroacoustic Flow Facility with a 63-element logarithmic spiral microphone array in the absence of flow are used to demonstrate the performance of MACS.     

Unified Lyapunov functional for an age-structured virus model with very general nonlinear infection response

The aim of this paper is to provide a unified Lyapunov functional for an age-structured model describing a virus infection. Our main contribution is to consider a very general nonlinear infection function, gathering almost all usual ones, for the following problem:

$$\begin{aligned} \left\{ \begin{array}{lll} T'(t)=A- dT(t)-f(T(t),V(t)) \;\;\ t \ge 0,\\ i_t(t,a)+i_a(t,a)=-\delta (a) i(t,a), \\ V'(t)=\int _0^{\infty } p(a)i(t,a)da-cV(t), \end{array} \right. \end{aligned}$$

(0.1)

where T(t),  i(t, a) and V(t) are the populations of uninfected cells, infected cells with infection age a and free virus at time t respectively. The functions \(\delta (a),\) p(a),  are respectively, the age-dependent per capita death, and the viral production rate of infected cells with age a. The global asymptotic analysis is established, among other results, by the use of compact attractor and strongly uniform persistence. Finally some numerical simulations illustrating our results are presented.