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961.
Langmuir-Blodgett (LB) films consisting of the hybrid of a polymer having the azobenzene (Az) side chain and 4î-pentyl-4-cyanobiphenyl (5CB) are prepared. Microscopic observations and spectroscopic data both indicate that the Az side chain and 5CB are homogeneously mixed at a molecular level without phase separation in the layer. This provides a satisfactory model of the command surface system. Time course accumulation of spectroscopic data for multilayered hybrid films reveals the cooperative nature of the photo-motivated molecular motions. 相似文献
962.
A radical chain addition of allyl bromides 2 to alkenylcyclopropanes 1 resulted in [3+2] annulation to give 2-bromomethylalkenylcyclopentanes 3 in good yields(16 examples). In this reaction, two kinetically fast radical reactions, cyclopropylcarbinyl radical-ring-opening and 5-exo-radical cyclization, preceded the β-fragmentation of a bromine radical to make the formal cycloaddition possible. 相似文献
963.
Analytical and numerical studies of the boundary slip in the immersed boundary‐thermal lattice Boltzmann method 下载免费PDF全文
We analytically and numerically investigate the boundary slip, including the velocity slip and the temperature jump, in immersed boundary‐thermal lattice Boltzmann methods (IB‐TLBMs) with the two‐relaxation‐time collision operator. We derive the theoretical equation for the relaxation parameters considering the effect of the advection velocity on the temperature jump of the IB‐TLBMs. The analytical and numerical solutions demonstrate that the proposed iterative correction methods without the computational cost of the sparse matrix solver reduce the boundary slip and boundary‐value deviation as effectively as the implicit correction method for any relaxation time. Because the commonly used multi‐direct forcing method does not consider the contributions of the body force to the momentum flux, it cannot completely eliminate the boundary slip because of the numerical instability for a long relaxation time. Both types of proposed iterative correction methods are more numerically stable than the implicit correction method. In simulations of flow past a circular cylinder and of natural convection, the present iterative correction methods yield adequate results without the errors of the velocity slip, the temperature jump, and the boundary‐value deviation for any relaxation time parameters and for any number of Lagrangian points per length. The combination of the present methods and the two‐relaxation‐time collision operator is suitable for simulating fluid flow with thermal convection in the multiblock method in which the relaxation time increases in inverse proportion to the grid size. 相似文献
964.
Hidemitsu Aoki Makoto Hara Takuro Masuzumi Motaharu K. Mazumder Naoki Ooi Daisuke Watanabe Chiharu Kimura Takashi Sugino 《Applied Surface Science》2009,255(6):3719-3722
Cu electroplating is required for the fabrication of Cu/low-k interconnections. The permeation of a plating solution into low-k films during Cu electroplating is a serious challenge for 45-nm nodes and more complex devices. We investigated the influence of Cu electroplating solutions on boron carbon nitride (BCN) as a low-k film. After dipping it into a Cu electroplating solution that contained additives, the BCN film's hydrophilic surface changed to a hydrophobic surface, and the incorporation of water into the BCN film was suppressed by surfactant adsorption. Sulfuric residue was detected on the BCN sample by thermal desorption spectroscopy after treatment in the Cu electroplating solution with additives; however, it was found through electrical measurements that this solution did not affect the leakage current or the dielectric constant of the BCN film. We successfully fabricated an electroplating Cu layer on a BCN film with good adhesion, and we believe that this BCN film is a sufficiently useful material for Cu/BCN integration in LSI. 相似文献
965.
Keiko Matsunouchi Naoyoshi Komatsu Chiharu Kimura Hidemitsu Aoki Takashi Sugino 《Applied Surface Science》2009,255(9):5021-5024
YAlO films are synthesized on (1 0 0)-oriented Si substrates by RF magnetron sputtering method. Al2O3 wafer is used as a target material, and some small pieces of Y bulk material are put on the Al2O3 target to synthesize YAlO films. Y composition ratio is varied from 0 to 34%. Amorphous YAlO films are characterized. An electrical resistivity as high as 3.4 × 1014 Ω-cm is achieved for the YAlO film with Y composition ratio of 10%. The dielectric constant increases with increasing Y composition ratio, and the YAlO film with Y composition ratio of 34% has a dielectric constant of 10.2. The bandgap energy of the YAlO film is suggested to be wider than 6.5 eV. YAlO films with a surface roughness of 0.4-1.3 nm are obtained irrespective of the Y composition ratio. 相似文献
966.
The applicability of laser processing for small-lot micro-electromechanical system devices is discussed in this paper. This simple process could replace conventional complex processes designed with mass production in mind. Ablation, protrusions or surface modification is revealed to occur by argon ion laser scanning into silicon. Which of them occurs depends on the laser power. It is found that the protrusions are covered by a thin layer of oxide; however, oxidation of the modified surface is not established even though some results suggest it. Surface modification is more applicable to surface patterning than coarse protrusion is because the laser-modified surface can be used as a mask in KOH etching to make sharp patterns. The applicability of this method is indicated by demonstrating pattern width control, patterning over a large area and the fabrication of a 16-bit linear scale. 相似文献
967.
Takashi Nagatani 《Physica A》2009,388(14):2911-2921
We study the dynamic behavior of vehicular traffic through a series of traffic lights on selected paths in a two-dimensional (2d) traffic network. The city traffic network is made of one-way perpendicular streets arranged in a square lattice with traffic signals where vertical streets are oriented upwards and horizontal streets are oriented rightwards. A vehicle moves through the series of signals on a path selected by the driver. The selected path is one of the straight, zigzag, and random paths in a 2d traffic network. The vehicular motion on a selected path is presented by the nonlinear-map model. Vehicular traffic exhibits very complex behavior with varying selected paths, cycle times, and vehicular density. The dependence of the arrival time on cycle time, selected path, and density is clarified for 2d city traffic. 相似文献
968.
Angular and spatial profiles of undulator radiation have been investigated to derive a universal function that evaluates the brilliance of undulator radiation and takes into account the effects of electron beam emittance and energy spread. It has been found that the effects of energy spread on the angular divergence and source size can be expressed by simple analytic expressions, and a universal brilliance function has been derived by convolution with the electron beam distribution functions. Comparisons with numerical results have been carried out to show the validity and applicability of the universal function. 相似文献
969.
Takashi Harumoto Javed Iqbal Xiaofang Liu Ji Shi Yoshio Nakamura Ronghai Yu 《Applied Physics A: Materials Science & Processing》2009,97(1):211-215
Co doped SnO2 nanoparticles have been prepared via a wet chemical method with different precipitation processes. The structure and morphology
of Co doped SnO2 nanoparticles demonstrate that the nanoparticles are in a rutile single phase and uniform, respectively. X-ray photoelectron
spectroscopy shows that the Co dopants are in 2+ oxidation valence state and doped ∼2 atm% in SnO2 nanoparticles. Moreover, Raman spectroscopy further confirms that Co doped SnO2 nanoparticles have single phase crystallinity without forming any extra modes related to secondary phases. The magnetic measurements
reveal that all nanoparticles exhibit room temperature ferromagnetism (RTFM) due to the presence of disorders and defects
introduced by hydroxyls in the crystal structure. In addition, it has been clearly observed that the saturated magnetic moments
are strongly affected by the precipitation processes which control the incorporation of hydroxyls into the lattice. 相似文献
970.
Kazuaki Sakoda Takashi Kuroda NaokiI keda Takaaki Mano Yoshimasa Sugimoto Tetsuyuki Ochiai Keiji Kuroda Shunsuke Ohkouchi Nobuyuki Koguchi Kiyoshi Asakawa 《中国光学快报(英文版)》2009,7(10):879-881
We fabricate photonic crystal slab microcavities embedded with GaAs quantum dots by electron beam lithography and droplet epitaxy. The Purcell effect of exciton emission of the quantum dots is confirmed by the micro photoluminescence measurement. The resonance wavelengths, widths, and polarization are consistent with numerical simulation results. 相似文献