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121.
Hong JH Hwang YK Hong JY Kim HJ Kim SJ Won YS Huh S 《Chemical communications (Cambridge, England)》2011,47(24):6963-6965
To simply reduce HAuCl(4) using 2-thiophenemethanol in an aqueous solution at room temperature, a novel metallic Au nanostructure with a high SERS activity was obtained. Flat sheet-like Au nanoleaves possessing many nanogap hotspots bound with a large percentage of high-index facets were obtained. 相似文献
122.
In a free solution of 10.0 mM Gly-Gly (pH 8.2), the flow directions of native-DNA and DNA molecules intercalated with the fluorescent dye YOYO-1 were reversed in the microchip channel. These results clearly showed that in a confined space and under specific environmental conditions, the fluorescent dye modified the original properties and behavior of the native-DNA molecule. 相似文献
123.
Lee BR Oh KT Oh YT Baik HJ Park SY Youn YS Lee ES 《Chemical communications (Cambridge, England)》2011,47(13):3852-3854
We report charge-switching ionic nanocomplexes comprised of glycol chitosan grafted with 2,3-dimethylmaleic acid (DMA) (denoted as 'GCS-g-DMA' hereafter) and a proapoptotic peptide. This system allowed for improved peptide delivery to tumor sites via a mechanism of selective peptide release when the pH was dropped from 7.4 to 6.8. 相似文献
124.
125.
Lee SJ Min A Kim Y Ahn A Chang J Lee SH Choi MY Kim SK 《Physical chemistry chemical physics : PCCP》2011,13(37):16537-16541
The conformational structures of jet-cooled acetaminophen were investigated in the gas phase by resonant 2-photon ionization and UV-UV hole-burning spectroscopy. In contrast to the results from a previous study, two nearly isoenergetic conformers were distinctly found in a supersonic molecular beam expansion and positively identified as the cis and trans isomers of acetaminophen by UV-UV hole-burning spectroscopy. The 0-0 bands of the cis and trans isomers were found at 33518.7 and 33485.6 cm(-1), respectively. The vibronic bands of the two isomers are close-lying and/or partially overlapping due to the small energy difference (33 cm(-1)) between the two 0-0 bands. As a consequence, the recorded resonant 2-photon ionization spectrum is highly congested in the low excitation energy region, which develops continuously into a featureless, broadened spectrum in the high energy region. 相似文献
126.
127.
Jong Seong Bae Kyoo Sung Shim Soung-soo Yi Young Soo Kim 《Applied Surface Science》2006,252(13):4564-4568
The influence of lithium doping on the crystallization, the surface morphology, and the luminescent properties of pulsed laser deposited Y2−xGdxO3:Eu3+ thin film phosphors was investigated. The crystallinity, the surface morphology, and the photoluminescence (PL) of films depended highly on the Li-doping and the Gd content. The relationship between the crystalline and morphological structures and the luminescent properties was studied, and Li+ doping was found to effectively enhance not only the crystallinity but also the luminescent brightness of Y2−xGdxO3:Eu3+ thin films. In particular, the incorporation of Li and Gd into the Y2O3 lattice could induce remarkable increase in the PL. The highest emission intensity was observed Li-doped Y1.35Gd0.6O3:Eu3+ thin films whose brightness was increased by a factor of 4.6 in comparison with that of Li-doped Y2O3:Eu3+ thin films. 相似文献
128.
Seong Soo Park Seog Tae Han Yong Moon Cho Do Heung Je Kwang Dong Kim Dong Chul Park 《International Journal of Infrared and Millimeter Waves》2003,24(6):941-951
In this paper, a design method of an iris-coupled waveguide bandpass filter having 0.1 dB passband ripple and 3.5% ripple bandwidth at the center frequency of 41 GHz is described. Mode matching method is used to analyze H-plane discontinuity of waveguide and an equivalent circuit of the thick inductive obstacle is obtained from the results of the analysis. Simulation and experimental results show the validity of waveguide bandpass filter design method using mode matching method. 相似文献
129.
Il Kim Hong Ki Choi Taek Kyu Han Seong Ihl Woo 《Journal of polymer science. Part A, Polymer chemistry》1992,30(10):2263-2271
A series of monoester catalysts has been studied, each catalyst prepared by the reaction of magnesium diethoxide with benzoyl chloride [BzCOCl, to produce ethyl benzoate (EB) in situ] in the presence of excess titanium tetrachloride. Solid product and catalysts obtained by subsequent treatments with titanium tetrachloride were characterized by elemental analysis, IR spectroscopy, x-ray diffraction, BET measurement, and thermal gravimetric analysis. The catalysts yielded very high activity (above 20 kg polymer/g Ti h atm) for the polymerization of propylene in slurry reactions. From the results of polymerization as well as catalyst characterization, the effects of internal and external Lewis bases on the isospecificity and stability of catalysts are discussed in detail. © 1992 John Wiley & Sons, Inc. 相似文献
130.
Kim SH Kim JH Kang BK Uhm HS 《Langmuir : the ACS journal of surfaces and colloids》2005,21(26):12213-12217
Stable superhydrophobic coatings on various substrates are attained with an in-line atmospheric rf plasma process using CF4, H2, and He. The coating layer is composed of CFx nanoparticulates and has an average roughness of approximately 10 nm. This roughness is much smaller than other surfaces reported for superhydrophobicity in the literature. The superhydrophobic coatings are produced on both metallic and insulating substrates without any need of separate microroughening or vacuum lines. 相似文献