Phase diagrams of poly(siloxane)/liquid crystal blends

Phase diagrams of blends of poly(methylphenylsiloxane) in short PMPS and two low molecular weight liquid crystals (4‐cyano‐4′‐n‐pentyl‐biphenyl and an eutectic mixture of paraphenylenes) are reported. Two polymers with very different weight‐average molar masses are considered in an evaluation of the loss of miscibility resulting from a known increase in the weight‐average molar mass. The experimental diagrams have been constructed via polarized optical microscopy and are rationalized in terms of the Flory–Huggins theory of isotropic mixtures and the Maier–Saupe theory of nematic order. The results show a good agreement between the theory and experiments and reveal a remarkable enhancement of miscibility with respect to similar systems involving poly(dimethylsiloxane). Variations of the interaction parameter with the temperature are compared for different systems of polysiloxanes. The effects of the nature of the liquid crystal and the polymer molar mass on the χ parameter are evaluated. © 2002 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 39–43, 2003     

An oxathiaphospholane approach to one-pot phosphorothioylation of isoprenoid alcohols

[reaction: see text] Allyl, isopentenyl, geranyl, citronellyl, farnesyl, and phytyl alcohols were transformed in good yield (>60%) into their phosphorothioates via a DBU-assisted 1,3,2-oxathiaphospholane ring-opening condensation with 2-(2-cyanoethoxy)-2-thiono-1,3,2-oxathiaphospholane, a reagent that is stable and easy to handle, followed by subsequent removal of the 2-cyanoethyl group from the intermediate phosphorothioate diester under basic conditions.     

Applying spectrum analysis and cepstrum analysis to examine the cavitation threshold in water and in salt solution

The paper presents the way of determining the cavitation threshold by means of classical spectral analysis and proposes the usage of cepstrum analysis in examining the cavitation phenomenon. Cepstrum analysis enables a more lucid interpretation of signals generated in the cavitation process than the universally used Fourier analysis. This refers above all to evaluating the relationship between particular frequencies as well as frequency groups. The research conducted allowed us to observe the changes of spectrum near the cavitation threshold in water, in water partly degassed and in salt solution in the free field and in the standing wave field. Differences of spectrum structure for particular cases were noted, especially for the third harmonic and the first subharmonic. The measurements done in the standing wave field showed differences in spectrum, depending on whether the measurements were done in the loop or in the node of the wave. In particular, what was not observed was the occurrence of subharmonics with a frequency two times lower than the basic frequency which were typical of the free field. Other characteristic spectrum elements that could unmistakably point to reaching the cavitation threshold were not noticed either. The cepstrum analysis proved the existence of irregularities, hardly visible in the classical Fourier spectrum. This refers especially the range below the signal's basic frequency.     

Homologous series of dendronized polymethacrylates with a methyleneoxycarbonyl spacer between the backbone and dendritic side chain: synthesis, characterization, and some bulk properties

First through fourth generation (G1-G4) dendronized macromonomers, 3, 5, 7, and 9, with a methyleneoxycarbonyl spacer between the polymerizable group and dendritic side chain (dendron) were synthesized, and their polymerization behavior to the corresponding dendronized polymers PG1s, PG2s, PG3s, and PG4s, respectively, was investigated by heating the monomers to 55 degrees C without intentional addition of initiator. This self-induced polymerization is referred to as thermally induced radical polymerization (TRP). The molar masses of PG1s-PG4s were determined by gel permeation chromatography in DMF calibrated to a recently developed G1 dendronized polymer standard (PG1). A comparison of this homologous series' polymerization results with those of an already existing one, which differed only by the lack of this spacer (referred to as PG1-PG4), was made to contribute to the issue of whether short spacers have an effect on polymerization. Several representatives of both series were also used in the first systematic and generation-dependent investigation of these unusual comb polymers' bulk properties. Both structure and dynamics were investigated by DSC, X-ray diffraction, and dynamic mechanical measurements.     

Trapping of microparticles in the near field of an ultrasonic transducer

We are investigating means of handling microparticles in microfluidic systems, in particular localized acoustic trapping of microparticles in a flow-through device. Standing ultrasonic waves were generated across a microfluidic channel by ultrasonic microtransducers integrated in one of the channel walls. Particles in a fluid passing a transducer were drawn to pressure minima in the acoustic field, thereby being trapped and confined at the lateral position of the transducer. The spatial distribution of trapped particles was evaluated and compared with calculated acoustic intensity distributions. The particle trapping was found to be strongly affected by near field pressure variations due to diffraction effects associated with the finite sized transducer element. Since laterally confining radiation forces are proportional to gradients in the acoustic energy density, these near field pressure variations may be used to get strong trapping forces, thus increasing the lateral trapping efficiency of the device. In the experiments, particles were successfully trapped in linear fluid flow rates up to 1mm/s. It is anticipated that acoustic trapping using integrated transducers can be exploited in miniaturised total chemical analysis systems (microTAS), where e.g. microbeads with immobilised antibodies can be trapped in arrays and subjected to minute amounts of sample followed by a reaction, detected using fluorescence.     

Synthetic aperture imaging using sources with finite aperture: deconvolution of the spatial impulse response

A method for ultrasonic synthetic aperture imaging using finite-sized transducers is introduced that is based on a compact, linear, discrete model of the ultrasonic measurement system developed using matrix formalism. Using this model a time-domain algorithm for deconvolution of the transducer's spatial impulse responses (SIRs) is developed that is based on a minimum mean square error (MMSE) criterion. The algorithm takes the form of a spatiotemporal filter that compensates for the SIRs associated with a finite-sized transducer at every point of the processed image. A major advantage of the proposed method is that it can be used for any transducer, provided that its associated SIRs are known. This is in contrast to the synthetic aperture focusing technique (SAFT), which treats the transducer as a point source. The performance of the method is evaluated with simulations and experiments, performed in water using a linear phased array. The results obtained using the proposed method are compared to those obtained with a classical time-domain SAFT algorithm. For a finite aperture source, it is clearly shown that the resolution obtained using the proposed method is superior to that obtained using the SAFT algorithm.     

Hyperbolic Coxeter groups of large dimension

We construct examples of Gromov hyperbolic Coxeter groups of arbitrarily large dimension. We also extend Vinbergs theorem to show that if a Gromov hyperbolic Coxeter group is a virtual Poincaré duality group of dimension n, then n 61.Coxeter groups acting on their associated complexes have been extremely useful source of examples and insight into nonpositively curved spaces over last several years. Negatively curved (or Gromov hyperbolic) Coxeter groups were much more elusive. In particular their existence in high dimensions was in doubt.In 1987 Gabor Moussong [M] conjectured that there is a universal bound on the virtual cohomological dimension of any Gromov hyperbolic Coxeter group. This question was also raised by Misha Gromov [G] (who thought that perhaps any construction of high dimensional negatively curved spaces requires nontrivial number theory in the guise of arithmetic groups in an essential way), and by Mladen Bestvina [B2].In the present paper we show that high dimensional Gromov hyperbolic Coxeter groups do exist, and we construct them by geometric or group theoretic but not arithmetic means.     

A New Approach to Multiobjective Programming with a Modified Objective Function

In this paper, optimality for multiobjective programming problems having invex objective and constraint functions (with respect to the same function ) is considered. An equivalent vector programming problem is constructed by a modification of the objective function. Furthermore, an -Lagrange function is introduced for a constructed multiobjective problem and modified saddle point results are presented.