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61.
The electronic structures of the laser crystal MgF2:V2+ were obtained with the spinpolarized MS-X
method. The calculated value of 10Dq and the energies of the lowest doublet states were given for the first time. The relations between the laser properties and the electronic structures were discussed. 相似文献
62.
B. Yang J. Zhou H. Hu L. Li J. Qiu J. Guo P. He J. Lu C. Ye 《Applied magnetic resonance》1995,9(3):379-388
Four Ib-type synthetic diamond crystals were studied by dynamic nuclear polarization (DNP)-enhanced high resolution solid state13C nuclear magnetic resonance (NMR) spectroscopy. The home built DNP magic-angle-spinning (MAS) NMR spectrometer operates at a field strength of 1.9 T and the highest DNP enhancement factor of synthetic diamonds came near to 103. Comparing with Ib-type natural diamonds, the13C NMR linewidths of synthetic diamonds in static spectra are broader. The13C spin-lattice relaxation time and DNP polarization time of synthetic diamond are shorter than those of Ib-type natural diamond. From the hyperfine structure of the DNP enhancement curve, four kinds of nitrogen-centred free radicals could be identified in synthetic diamond. 相似文献
63.
结合1H NMR,13C NMR,DEPT,HSQC,HMBC谱和碳氟偶合裂分行为, 对氧氟沙星(ofloxacin, OFL)哌嗪部分的甲基化产物-甲基氧氟沙星(methyl-ofloxacin,Me-OFL)的结构进行归属,并探讨了Me-OFL在酸性及碱性溶液中的1H和13C谱的变化。碱性溶液中, 5H的化学位移较酸性向高场移动1.02, 推测此变化与形成C—H…O弱氢键有关。6C、13C、羰基碳7C和羧基碳15C分别向低场位移12.04,7.46,4.33,2.88 ppm, 推测此变化与羧基和羧酸根的转变有关。另外, 还比较了OFL哌嗪环4’N上质子化产物与烷基化产物的正电荷分布。当哌嗪环质子化形成季铵盐时,正电荷分布在氢原子上;当其烷基化形成季铵盐时, 正电荷分布在氮原子上。 相似文献
64.
Yikai Chen Douguo Zhang Dong Qiu Liangfu Zhu Sisheng Yu Peijun Yao Pei Wang Hai Ming Ramachandram Badugu Joseph R. Lakowicz 《Laser \u0026amp; Photonics Reviews》2014,8(6):933-940
The unique optical properties of Tamm plasmons (TPs) – such as flexible wavevector matching conditions including inplane wavevector within the light line, and existing both S‐ and P‐polarized TPs − facilitate them for direct optical excitation. The Tamm plasmon‐coupled emission (TPCE) from a combined photonic–plasmonic structure sustaining both surface plasmons (SPs) and TPs is described in this paper. The sensitivity of TPCE to the emission wavelength and polarization is examined with back focal plane imaging and verified with the numerical calculations. The results reveal that the excited probe can couple with both TPs and SPs, resulting in surface plasmon‐coupled emission (SPCE) and TPCE, respectively. The TPCE angle is strongly dependent on the wavelength allowing for spectral resolution using different observation angles. These Tamm structures provide a new tool to control the optical emission from dye molecules and have many potential applications in fluorescence‐based sensing and imaging. 相似文献
65.
66.
Lie Shen Du Xu Yukun Jian Wenlian Qiu Qipeng Guo 《Journal of Macromolecular Science: Physics》2017,56(4):254-261
The mutual diffusion process and interphase development taking place at the interface between disks of polystyrene (PS) and carbon black filled polystyrene (CB-PS) in the molten state were investigated by a small-amplitude, oscillatory shear, rheological technique. The rheological method was employed to probe the thermorheological complexity of these polymer disks. It was found that the dynamic complex shear modulus, G*(t), increased with the time of contact in two time regimes at a fixed frequency. The time of transition between the two regimes was observed to be close to the time needed for the transition from the Rouse mode to the reptation mode. The results showed that the content of the carbon black and the temperature affected the slope of the G*(t) – t curve. Scanning electron microscopy revealed the interface disappeared when the diffusion process was complete. 相似文献
67.
La0.8Sr0.2MnO3 (LSMO) thin films were fabricated on alumina substrates by an improved sol-gel dip-coating process. It was found that multiple dip-coating process could not be performed until the pre-firing temperature reached 600 °C. Different amounts of LSMO powders were added to precursor solution with an aim to avoid cracks in LSMO thin films during calcining caused by the shrinkage mismatch between the film and the substrate. The structure and surface morphology of the films prepared from precursors with and without LSMO powders were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM). It was found that the addition of 56.4 wt.% LSMO powders into the sol-gel precursor solution significantly modified the microstructure of films. A single LSMO perovskite phase was obtained on alumina substrate after calcining at 800 °C for 4 h by the improved sol-gel method. The sheet resistance of the films prepared with different processing parameters was measured by four-point dc method. Results indicated that the sheet resistance of films decreased with increasing the number of coating applications and the amount of LSMO powders. 相似文献
68.
69.
液态水微观结构研究的新进展 总被引:1,自引:0,他引:1
液态水有很多奇异特性.近年来,对液态水以何种微观结构形式存在的问题争议激烈.文章介绍了当前对水的微观结构的一些研究及其进展,讨论了液态水中的氢键模式与水的结构关系,进而用一个简化模型探讨了氢键的取向性与强弱性对水的异常行为的作用. 相似文献
70.