Controlled synthesis of polyepichlorohydrin with pendant cyclic carbonate functions for isocyanate‐free polyurethane networks

Poly(allyl glycidyl ether) and poly(allyl glycidyl ether‐co‐epichlorohydrin) were prepared by monomer‐activated anionic polymerization. Quantitative and controlled polymerization of allyl glycidyl ether (AGE) giving high molar mass polyether was achieved in a few hours at room temperature in toluene using tetraoctylammonium salt as initiator in presence of an excess of triisobutylaluminum ([i‐Bu₃Al]/[NOct₄Br] = 2?4). Following the same polymerization route, the copolymerization of AGE and epichlorohydrin yields in a living‐like manner gradient‐type copolymers with controlled molar masses. Chemical modification of the pendant allyl group into cyclic carbonate was then investigated and the corresponding polymers were used as precursors for the isocyanate‐free synthesis of polyurethane networks in presence of a diamine. Formation of crosslinked materials was followed and characterized by infrared and differential scanning calorimetry. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011     

Finiteness theorems for the Picard objects of an algebraic stack

We prove some finiteness theorems for the Picard functor of an algebraic stack, in the spirit of SGA 6, exp. XII and XIII. In particular, we give a stacky version of Raynaud?s relative representability theorem, we give sufficient conditions for the existence of the torsion component of the Picard functor, and for the finite generation of the Néron–Severi groups or of the Picard group itself. We give some examples and applications. In Appendix A, we prove the semicontinuity theorem for a (non-necessarily tame) algebraic stack.     

A GRASP-based approach for technicians and interventions scheduling for telecommunications

The Technicians and Interventions Scheduling Problem for Telecommunications embeds the scheduling of interventions, the assignment of teams to interventions and the assignment of technicians to teams. Every intervention is characterized, among other attributes, by a priority. The objective of this problem is to schedule interventions such that the interventions with the highest priority are scheduled at the earliest time possible while satisfying a set of constraints like the precedence between some interventions and the minimum number of technicians needed with the required skill levels for the intervention. We present a Greedy Randomized Adaptive Search Procedure (GRASP) for solving this problem. In the proposed implementation, we integrate learning to the GRASP framework in order to generate good-quality solutions using information brought by previous ones. We also compute lower bounds and present experimental results that validate the effectiveness of this approach.     

Lower bound of effective yield strength domain for random heterogeneous materials

A random heterogeneous material is represented by a finite family of microstructures, the environment of each microstructure being subjected to a perfect mix condition whose validity is justified both theoretically and numerically. Necessary conditions, satisfied by any permissible strain rate field on a representative and unlimited domain of the material, are highlighted. They enable one to obtain, by solving a discrete infmax problem, a lower bound of the effective yield strength domain of the material, that is rigorous and more predictive than the classical bound of Reuss. An analytical application on a porous medium illustrates the methodology.     

A high pressure-mediated route to (±)-11-deoxydaunomycinone and 4-demethoxy analog1

Abstract

A high pressure-mediated route for convergent, regiospecific syntheses of (±)-l1-deoxydaunomycinone and 4-demethoxy analog, by sequential Diels-Alder cycloadditions is described.     

Synthesis of nitrogen bicyclic scaffolds: pyrimido[1,2-a]pyrimidine-2,6-diones

The multi-step synthesis of 1,3,7-trisubstituted pyrimido[1,2-a]pyrimidinediones starting from isothiocyanates is described. These nitrogen bicycles were prepared by an iterative sequence of functionalization/cyclocondensation reactions. [4+2] Cycloaddition reactions took place between diazadienic chains and various acyl chlorides providing sophisticated heterobicycles.