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21.
Myint MT Kitsomboonloha R Baruah S Dutta J 《Journal of colloid and interface science》2011,354(2):810-815
The synthesis and properties of superhydrophobic surfaces based on binary surface topography made of zinc oxide (ZnO) microrod-decorated micropatterns are reported. ZnO is intrinsically hydrophilic but can be utilized to create hydrophobic surfaces by creating artificial roughness via microstructuring. Micron scale patterns consisting of nanocrystalline ZnO seed particles were applied to glass substrates with a modified ink-jet printer. Microrods were then grown on the patterns by a hydrothermal process without any further chemical modification. Water contact angle (WCA)(1) up to 153° was achieved. Different micro array patterned surfaces with varying response of static contact angle or sessile droplet analysis are reported. 相似文献
22.
23.
Summary Kinetics of formation of ternary complexes in the reaction of Ni(NTA)(H2O)
2
–
with several amino acids, LH± (glycine, -alanine, -alanine, L-valine and L-phenylalanine) have been studied by a pH indicator method using stopped-flow spectrophotometry. The results conform to 1/kobs = 1/k + [H+]/ kKTL where K is the equilibrium constant for formation of Ni(NTA)(–L)(H2O)2–, and k is the specific rate constant for the subsequent rate-determining ring-closure step leading to Ni(NTA)(=L)2–. For the different amino acids studied, the k values decrease in the sequence: glycine > -alanine > L-phenylalanine > L-valine > -alanine. These k values areca. 1000 times lower than the values for complexation of Ni(NTA)(H2O)
2
–
with NH3 and imidazole and the spread in k values is much less than the pKa values of the amino acids. The relative rates are enthalpy controlled and the S values are highly negative in conformity with ring closure as the rate determining step. 相似文献
24.
Debasish Manna Basudeb Maji Soumyashree A. Gangopadhyay Kurt J. Cox Qingxuan Zhou Benjamin K. Law Ralph Mazitschek Amit Choudhary 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(19):6351-6355
Several genome engineering applications of CRISPR‐Cas9, an RNA‐guided DNA endonuclease, require precision control of Cas9 activity over dosage, timing, and targeted site in an organism. While some control of Cas9 activity over dose and time have been achieved using small molecules, and spatial control using light, no singular system with control over all the three attributes exists. Furthermore, the reported small‐molecule systems lack wide dynamic range, have background activity in the absence of the small‐molecule controller, and are not biologically inert, while the optogenetic systems require prolonged exposure to high‐intensity light. We previously reported a small‐molecule‐controlled Cas9 system with some dosage and temporal control. By photocaging this Cas9 activator to render it biologically inert and photoactivatable, and employing next‐generation protein engineering approaches, we have built a system with a wide dynamic range, low background, and fast photoactivation using a low‐intensity light while rendering the small‐molecule activator biologically inert. We anticipate these precision controls will propel the development of practical applications of Cas9. 相似文献
25.
26.
A p‐Hydroxyphenacyl–Benzothiazole–Chlorambucil Conjugate as a Real‐Time‐Monitoring Drug‐Delivery System Assisted by Excited‐State Intramolecular Proton Transfer 下载免费PDF全文
Shrabani Barman Sourav K. Mukhopadhyay Sandipan Biswas Surajit Nandi Moumita Gangopadhyay Satyahari Dey Anakuthil Anoop N. D. Pradeep Singh 《Angewandte Chemie (International ed. in English)》2016,55(13):4194-4198
Among the well‐known phototriggers, the p‐hydroxyphenacyl (pHP) group has consistently enabled the very fast, efficient, and high‐conversion release of active molecules. Despite this unique behavior, the pHP group has been ignored as a delivery agent, particularly in the area of theranostics, because of two major limitations: Its excitation wavelength is below 400 nm, and it is nonfluorescent. We have overcome these limitations by incorporating a 2‐(2′‐hydroxyphenyl)benzothiazole (HBT) appendage capable of rapid excited‐state intramolecular proton transfer (ESIPT). The ESIPT effect also provided two unique advantages: It assisted the deprotonation of the pHP group for faster release, and it was accompanied by a distinct fluorescence color change upon photorelease. In vitro studies showed that the p‐hydroxyphenacyl–benzothiazole–chlorambucil conjugate presents excellent properties, such as real‐time monitoring, photoregulated drug delivery, and biocompatibility. 相似文献
27.
We report a study on the effect of seeding on glass substrates with zinc oxide nanocrystallites towards the hydrothermal growth
of ZnO nanorods from a zinc nitrate hexahydrate and hexamethylenetetramine solution at 95 °C. The seeding was done with pre-synthesized
ZnO nanoparticles in isopropanol with diameters of about 6–7 nm as well as the direct growth of ZnO nanocrystallites on the
substrates by the hydrolysis of pre-deposited zinc acetate film. The nanorods grown on ZnO nanoparticle seeds show uniform
dimensions throughout the substrate but were not homogenously aligned vertically from the substrate and appeared like nanoflowers
with nanorod petals. Nanorods grown from the crystallites formed in situ on the substrates displayed wide variations in dimension
depending upon the preheating and annealing conditions. Annealing the seed crystals below 350 °C led to scattered growth directions
whereupon preferential orientation of the nanorods perpendicular to the substrates was observed. High surface to volume ratio
which is vital for gas sensing applications can be achieved by this simple hydrothermal growth of nanorods and the rod height
and rod morphology can be controlled through the growth parameters. 相似文献
28.
The formulated ABCD matrix formalism is employed to prescribe analytical expression of coupling efficiency of a laser diode to single-mode circular core dispersion-shifted as well as dispersion-flattened fiber via hyperbolic microlens on the tip of the fiber. We assume that field distribution in case of both the source and the fiber is one parameter Gaussian type. For maximum excitation efficiency, it is required that the lens transmitted spot size of the source should match with the spot size of the fiber. Further, as regards the spot size of the fiber, we use Petermann II spot size in order to take care of non Gaussian nature of field of such fibers and to make the estimations more realistic thereby. The investigations are carried out for two different wavelengths 1.3 and 1.5 μm. Our simple method predicts the concerned coupling optics excellently and the necessary evaluations require little computations. This simple but accurate technique is expected to benefit the system designers who work in the field of optical technology. 相似文献
29.
Sukhendu Jana Sayan Das Debasish De Utpal Gangopadhyay Prajit Ghosh Anup Mondal 《Applied Physics A: Materials Science & Processing》2014,114(3):965-972
The annealing effect on structural and optical properties of the Diamond-like Nanocomposite (DLN) thin film deposited on glass substrate by Plasma Assisted Chemical Vapor Deposition (PACVD) method has been investigated. The films were annealed at temperature ranging from 300 to 600 °C, with 100 °C interval for 9 minutes by rapid thermal process (RTP) under vacuum. The structural changes of the annealed films have been studied using Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, Scanning Electron Microscope (SEM), and optical parameters have been determined using transmittance and reflectance spectra in UV-UIS-NIR range. The result shows that the refractive index increases gradually from 1.79 to 2.84 with annealing temperature due to out-diffusion of H by breaking Si–H and C–H bond leads to Si–C bond, i.e. more cross linking structure. In higher temperature range, graphitization also enhanced the refractive index. However, the optical band gap at up to 400 °C initially increases from 3.05 to 3.20 eV and then decreases due to graphitization. The film has a great potential to be used as anti-reflection coating (ARC) on silicon-based solar cell. 相似文献
30.
Wang WN An WJ Ramalingam B Mukherjee S Niedzwiedzki DM Gangopadhyay S Biswas P 《Journal of the American Chemical Society》2012,134(27):11276-11281
A facile development of highly efficient Pt-TiO(2) nanostructured films via versatile gas-phase deposition methods is described. The films have a unique one-dimensional (1D) structure of TiO(2) single crystals coated with ultrafine Pt nanoparticles (NPs, 0.5-2 nm) and exhibit extremely high CO(2) photoreduction efficiency with selective formation of methane (the maximum CH(4) yield of 1361 μmol/g-cat/h). The fast electron-transfer rate in TiO(2) single crystals and the efficient electron-hole separation by the Pt NPs were the main reasons attributable for the enhancement, where the size of the Pt NPs and the unique 1D structure of TiO(2) single crystals played an important role. 相似文献