全文获取类型
收费全文 | 753篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 565篇 |
晶体学 | 5篇 |
力学 | 11篇 |
数学 | 65篇 |
物理学 | 110篇 |
出版年
2023年 | 8篇 |
2022年 | 4篇 |
2021年 | 11篇 |
2020年 | 9篇 |
2019年 | 16篇 |
2018年 | 7篇 |
2017年 | 9篇 |
2016年 | 8篇 |
2015年 | 10篇 |
2014年 | 13篇 |
2013年 | 23篇 |
2012年 | 44篇 |
2011年 | 63篇 |
2010年 | 23篇 |
2009年 | 35篇 |
2008年 | 42篇 |
2007年 | 48篇 |
2006年 | 68篇 |
2005年 | 44篇 |
2004年 | 56篇 |
2003年 | 42篇 |
2002年 | 34篇 |
2001年 | 8篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 8篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1991年 | 3篇 |
1987年 | 5篇 |
1986年 | 4篇 |
1985年 | 10篇 |
1984年 | 6篇 |
1982年 | 11篇 |
1981年 | 8篇 |
1980年 | 6篇 |
1979年 | 6篇 |
1978年 | 2篇 |
1977年 | 7篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1971年 | 3篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1959年 | 1篇 |
1936年 | 1篇 |
1928年 | 1篇 |
1923年 | 2篇 |
排序方式: 共有756条查询结果,搜索用时 31 毫秒
71.
Shin-ichi Suzuki 《Archive of Applied Mechanics (Ingenieur Archiv)》1971,40(2):131-144
Summary The behaviours of dynamical stresses acting in the circular plate subjected to transverse impulsive loads are investigated. The cases are treated where a rigid body with spring collides with the circular plate having a hole at its center along its inner edge. The relationships between dynamic load factors (D.L.F.) with respect to bending moments, solid viscosities and spring are obtained. Experiments are carried out and theoretical results are compared with experimental ones.
The author wishes to thank Mr. Toda at National Aeronautical Laboratory for his help with numerical calculations. 相似文献
Übersicht Es werden die dynamischen Spannungen untersucht, die in einer Kreisplatte durch stoßartige Querkräfte hervorgerufen werden. Es wird angenommen, daß ein mit Federn versehener starrer Körper so auf die mit einem konzentrischen Loch versehene Platte fällt, daß der Stoß am inneren Rande der Platte erfolgt. Es werden Beziehungen zwischen den dynamischen Belastungsfaktoren bezüglich der Biegemomente, den viskoelastischen Materialeigenschaften der Platte und den Federkonstanten abgeleitet. Die theoretischen Ergebnisse werden mit Versuchsergebnissen verglichen.
The author wishes to thank Mr. Toda at National Aeronautical Laboratory for his help with numerical calculations. 相似文献
72.
Shin-ichi Matsuoka Shintaro ShimakawaKoji Takagi Masato Suzuki 《Tetrahedron letters》2011,52(50):6835-6838
The head-to-tail dimerization of methacrolein via the conjugate addition of methanol is catalyzed by various organic bases, such as an amine, phosphine, and N-heterocyclic carbene, to give 2,4-dimethyl-2-methoxymethylpentane-1,5-dial in moderate yields. Based on the interpretation of the key intermediates by electrospray ionization mass spectrometry, we propose a reaction mechanism involving the initial conjugate addition of the organic bases to methacrolein to generate a zwitterionic base followed by the activation of methanol. 相似文献
73.
Bastakoti BP Guragain S Yokoyama Y Yusa S Nakashima K 《Langmuir : the ACS journal of surfaces and colloids》2011,27(1):379-384
An asymmetric triblock copolymer, poly(styrene-b-acrylic acid-b-ethylene glycol) (PS-b-PAA-b-PEG), was synthesized via reversible addition-fragmentation chain transfer controlled radical polymerization. Micelles of PS-b-PAA-b-PEG with PS core, PAA shell, and PEG corona were then prepared in aqueous solutions, followed by extensive characterization based on dynamic light scattering, zeta-potential, and transmission electron microscopy (TEM) measurements. The well-characterized micelles were used to fabricate hollow nanospheres of CaCO(3) as a template. It was elucidated from TEM measurements that the hollow nanospheres have a uniform size with cavity diameters of ca. 20 nm. The X-ray diffraction analysis revealed a high purity and crystallinity of the hollow nanospheres. The hollow CaCO(3) nanospheres thus obtained have been used for the controlled release of an anti-inflammatory drug, naproxen. The significance of this study is that we have overcome a previous difficulty in the synthesis of hollow CaCO(3) nanospheres. After mixing of Ca(2+) and CO(3)(2-) ions, the growth of CaCO(3) is generally quite rapid to induce large crystal, which prevented us from obtaining hollow CaCO(3) nanospheres with controlled structure. However, we could solve this issue by using micelles of PS-b-PAA-b-PEG as a template. The PS core acts as a template that can be removed to form a cavity of hollow CaCO(3) nanospheres, the PAA shell is beneficial for arresting Ca(2+) ions to produce CaCO(3), and the PEG corona stabilizes the CaCO(3)/micelle nanocomposite to prevent secondary aggregate formation. 相似文献
74.
Ghosh A Yusa S Matsuoka H Saruwatari Y 《Langmuir : the ACS journal of surfaces and colloids》2011,27(15):9237-9244
Cationic amphiphilic diblock copolymers of poly(n-butylacrylate)-b-poly(3-(methacryloylamino)propyl)trimethylammonium chloride) (PBA-b-PMAPTAC) with various hydrophobic and hydrophilic chain lengths were synthesized by a reversible addition-fragmentation chain transfer (RAFT) process. Their molecular characteristics such as surface activity/nonactivity were investigated by surface tension measurements and foam formation observation. Their micelle formation behavior and micelle structure were investigated by fluorescence probe technique, static and dynamic light scattering (SLS and DLS), etc., as a function of hydrophilic and hydrophobic chain lengths. The block copolymers were found to be non-surface active because the surface tension of the aqueous solutions did not change with increasing polymer concentration. Critical micelle concentration (cmc) of the polymers could be determined by fluorescence and SLS measurements, which means that these polymers form micelles in bulk solution, although they were non-surface active. Above the cmc, the large blue shift of the emission maximum of N-phenyl-1-naphthylamine (NPN) probe and the low micropolarity value of the pyrene probe in polymer solution indicate the core of the micelle is nonpolar in nature. Also, the high value of the relative intensity of the NPN probe and the fluorescence anisotropy of the 1,6-diphenyl-1,3,5-hexatriene (DPH) probe indicated that the core of the micelle is highly viscous in nature. DLS was used to measure the average hydrodynamic radii and size distribution of the copolymer micelles. The copolymer with the longest PBA block had the poorest water solubility and consequently formed micelles with larger size while having a lower cmc. The "non-surface activity" was confirmed for cationic amphiphilic diblock copolymers in addition to anionic ones studied previously, indicating the universality of non-surface activity nature. 相似文献
75.
Yu BY Kuo CH Wang WB Yen GJ Iida S Chen SZ Lin WC Lee SH Kao WL Liu CY Chang HY You YW Chang CJ Liu CP Jou JH Shyue JJ 《The Analyst》2011,136(4):716-723
The nanostructure of the light emissive layer (EL) of polymer light emitting diodes (PLEDs) was investigated using force modulation microscopy (FMM) and scanning time-of-flight secondary ion mass spectrometry (ToF-SIMS) excited with focused Bi(3)(2+) primary beam. Three-dimensional nanostructures were reconstructed from high resolution ToF-SIMS images acquired with different C(60)(+) sputtering times. The observed nanostructure is related to the efficiency of the PLED. In poly(9-vinyl-carbazole) (PVK) based EL, a high processing temperature (60 °C) yielded less nanoscale phase separation than a low processing temperature (30 °C). This nanostructure can be further suppressed by replacing the host polymer with poly[oxy(3-(9H-9-carbazol-9-ilmethyl-2-methyltrimethylene)] (SL74) and poly[3-(carbazol-9-ylmethyl)-3-methyloxetane] (RS12), which have similar chemical structures and energy levels as PVK. The device efficiency increases when the phase separation inside the EL is suppressed. While the spontaneous formation of a bicontinuous nanostructure inside the active layer is known to provide a path for charge carrier transportation and to be the key to highly efficient polymeric solar cells, these nanostructures are less efficient for trapping the carrier inside the EL and thus lower the power conversion efficiency of the PLED devices. 相似文献
76.
Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly Prussian blue analogs, which have unique properties. In this perspective, we describe a charge-transfer phase transition, reversible photomagnetism, second harmonic generation and magnetization-induced second harmonic generation, ferroelectric ferromagnetism, humidity-sensitive magnetism, high ionic conductivity, and a coupling effect (which we named spin-ionics) between ionic conduction and magnetic ordering with Prussian blue analogs. 相似文献
77.
Matsumoto J Sugiura Y Yuki D Hayasaka T Goto-Inoue N Zaima N Kunii Y Wada A Yang Q Nishiura K Akatsu H Hori A Hashizume Y Yamamoto T Ikemoto K Setou M Niwa S 《Analytical and bioanalytical chemistry》2011,400(7):1933-1943
Schizophrenia is one of the major psychiatric disorders, and lipids have focused on the important roles in this disorder. In fact, lipids related to various functions in the brain. Previous studies have indicated that phospholipids, particularly ones containing polyunsaturated fatty acyl residues, are deficient in postmortem brains from patients with schizophrenia. However, due to the difficulties in handling human postmortem brains, particularly the large size and complex structures of the human brain, there is little agreement regarding the qualitative and quantitative abnormalities of phospholipids in brains from patients with schizophrenia, particularly if corresponding brain regions are not used. In this study, to overcome these problems, we employed matrix-assisted laser desorption/ionization imaging mass spectrometry (IMS), enabling direct microregion analysis of phospholipids in the postmortem brain of a patient with schizophrenia via brain sections prepared on glass slides. With integration of traditional histochemical examination, we could analyze regions of interest in the brain at the micrometric level. We found abnormal phospholipid distributions within internal brain structures, namely, the frontal cortex and occipital cortex. IMS revealed abnormal distributions of phosphatidylcholine molecular species particularly in the cortical layer of frontal cortex region. In addition, the combined use of liquid chromatography/electrospray ionization tandem mass spectrometry strengthened the capability for identification of numerous lipid molecular species. Our results are expected to further elucidate various metabolic processes in the neural system. 相似文献
78.
This work is to survey the quantum control for free elementary particle numerically. Without considering of the magnetic and electronic fields, control theory of nucleus (nucleons and meson) will be proposed. Furthermore, computational approach will be preformed for control landscape in two dimensions (2D) to illustrate the theoretic results. 相似文献
79.
Pardo E Train C Gontard G Boubekeur K Fabelo O Liu H Dkhil B Lloret F Nakagawa K Tokoro H Ohkoshi S Verdaguer M 《Journal of the American Chemical Society》2011,133(39):15328-15331
A complex-as-ligand strategy to get a multifunctional molecular material led to a metal-organic framework with the formula (NH(4))(4)[MnCr(2)(ox)(6)]·4H(2)O. Single-crystal X-ray diffraction revealed that the anionic bimetallic coordination network adopts a chiral three-dimensional quartz-like architecture. It hosts ammonium cations and water molecules in functionalized channels. In addition to ferromagnetic ordering below T(C) = 3.0 K related to the host network, the material exhibits a very high proton conductivity of 1.1 × 10(-3) S cm(-1) at room temperature due to the guest molecules. 相似文献
80.
Watanuki S Matsuura K Tomura Y Okada M Okazaki T Ohta M Tsukamoto S 《Chemical & pharmaceutical bulletin》2011,59(11):1376-1385
We synthesized and evaluated inhibitory activity against T-type Ca(2+) channels for a series of 1-alkyl-N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]piperidine-4-carboxamide derivatives. Structure-activity relationship studies have revealed that the isopropyl substituent at the benzylic position plays an important role in exerting potent inhibitory activity, and the absolute configuration of the benzylic position was found to be opposite that of mibefradil, which was first launched as a new class of T-type Ca(2+) channel blocker. Oral administration of N-[(1R)-1-(4-fluorophenyl)-2-methylpropyl]-1-[2-(3-methoxyphenyl)ethyl]piperidine-4-carboxamide (17f) lowered blood pressure in spontaneously hypertensive rats without inducing reflex tachycardia, an adverse effect often caused by traditional L-type Ca(2+) channel blockers. 相似文献