全文获取类型
收费全文 | 4969篇 |
免费 | 789篇 |
国内免费 | 564篇 |
专业分类
化学 | 3435篇 |
晶体学 | 46篇 |
力学 | 350篇 |
综合类 | 24篇 |
数学 | 608篇 |
物理学 | 1859篇 |
出版年
2024年 | 25篇 |
2023年 | 104篇 |
2022年 | 164篇 |
2021年 | 200篇 |
2020年 | 201篇 |
2019年 | 197篇 |
2018年 | 185篇 |
2017年 | 137篇 |
2016年 | 278篇 |
2015年 | 234篇 |
2014年 | 260篇 |
2013年 | 384篇 |
2012年 | 479篇 |
2011年 | 464篇 |
2010年 | 312篇 |
2009年 | 288篇 |
2008年 | 306篇 |
2007年 | 249篇 |
2006年 | 244篇 |
2005年 | 210篇 |
2004年 | 185篇 |
2003年 | 158篇 |
2002年 | 133篇 |
2001年 | 111篇 |
2000年 | 96篇 |
1999年 | 100篇 |
1998年 | 75篇 |
1997年 | 74篇 |
1996年 | 75篇 |
1995年 | 62篇 |
1994年 | 46篇 |
1993年 | 46篇 |
1992年 | 28篇 |
1991年 | 39篇 |
1990年 | 35篇 |
1989年 | 29篇 |
1988年 | 13篇 |
1987年 | 12篇 |
1986年 | 14篇 |
1985年 | 19篇 |
1984年 | 9篇 |
1983年 | 10篇 |
1982年 | 7篇 |
1981年 | 4篇 |
1974年 | 2篇 |
1944年 | 4篇 |
1943年 | 1篇 |
1942年 | 3篇 |
1941年 | 1篇 |
1940年 | 1篇 |
排序方式: 共有6322条查询结果,搜索用时 15 毫秒
941.
942.
The periods of states for Markov chains in a random environmentare introduced and some properties about periods are investigated. An open problem(Orey, 1991; Problem 1.3.3) is studied under the assumption that states have periods. 相似文献
943.
944.
Dong-Liang Zhang Cheng-Long Deng Bin Xie Yu-Long Li Chuan Lai Wen-Yu Mou Lin-Xin He Xiao-Xue Bai Tao Li Jia-Xi Cao Jun Wang 《应用有机金属化学》2020,34(1):e5261
Six new O-alkyldithiophosphate nickel complexes with dcpf ligand, [(dcpf)Ni(S2P{O}OR)] (dcpf = 1,1′-bis (dicyclohexylphosphino)ferrocene, R = CH3 ( 1 ), CH3CH2 ( 2 ), Ph ( 3 ), 4-MeC6H4 ( 4 ), PhCH2 ( 5 ) and PhCH2CH2 ( 6 )), have been synthesized by the treatment of dcpf with ((RO)2PS2)2Ni in satisfactory yields. These complexes were characterized by elemental analysis, spectroscopy (FTIR, UV–vis, 1H, 13C, and 31P NMR), thermogravimetric analysis and single crystal X-ray diffraction. The nickel atom in 1 , 2 ·CH2Cl2, 3 ·CH2Cl2, 4 ·2CH2Cl2·THF, and 2( 5 )·hexane adopts a slightly distorted square-planar coordination environment finished by two phosphorus atoms of dcpf ligand and two sulfur atoms of O-alkyldithiophosphate ligand. Furthermore, the electrochemical properties for complexes 1 – 6 were also investigated by cyclic voltammetry. With the addition of 120 mM trifluoroacetic acid (TFA), the turnover frequency (TOF) values for 1 – 6 are estimated to be 1243.83, 1046.54, 1331.71, 2545.29, 1899.03, and 1191.37 s−1, with the overpotential (η) values of 0.62, 0.58, 0.71, 0.67, 0.60, and 0.56 V, respectively. The result of electrochemical studies indicates that all complexes can be used as efficient molecular eletrocatalysts for the reduction of protons to hydrogen in the presence of TFA in MeCN. 相似文献
945.
Nonlinear Dynamics - As an unmanned system, the multirotor has gained widespread attention in practical aviation engineering, because of its ease of use, reliability and maintainability. From the... 相似文献
946.
Lifen Wang Lei Liu Ji Chen Ali Mohsin Jung Hwan Yum Todd W. Hudnall Christopher W. Bielawski Tijana Rajh Xuedong Bai Shang-Peng Gao Gong Gu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(36):15864-15870
Using high-resolution transmission electron microscopy and electron energy-loss spectroscopy, we show that beryllium oxide crystallizes in the planar hexagonal structure in a graphene liquid cell by a wet-chemistry approach. These liquid cells can feature van-der-Waals pressures up to 1 GPa, producing a miniaturized high-pressure container for the crystallization in solution. The thickness of as-received crystals is beyond the thermodynamic ultra-thin limit above which the wurtzite phase is energetically more favorable according to the theoretical prediction. The crystallization of the planar phase is ascribed to the near-free-standing condition afforded by the graphene surface. Our calculations show that the energy barrier of the phase transition is responsible for the observed thickness beyond the previously predicted limit. These findings open a new door for exploring aqueous-solution approaches of more metal-oxide semiconductors with exotic phase structures and properties in graphene-encapsulated confined cells. 相似文献
947.
Zengbing Bai Chuangxu Cai Wangjian Sheng Yuxiang Ren Prof. Dr. Huan Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(34):14794-14800
Transition-metal-catalyzed C−H activation has shown potential in the functionalization of peptides with expanded structural diversity. Herein, the development of late-stage peptide macrocyclization methods by palladium-catalyzed site-selective C(sp2)−H olefination of tryptophan residues at the C2 and C4 positions is reported. This strategy utilizes the peptide backbone as endogenous directing groups and provides access to peptide macrocycles with unique Trp–alkene crosslinks. 相似文献
948.
Liu Yuanyuan Zhou Weibo Liu Haiyan Wei Qianglin Gao Bai Chen Gongxin 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):33-42
Journal of Radioanalytical and Nuclear Chemistry - The concentrations of 238U, 226Ra, 232Th and 40K and gross α, β were measured in soils and sediments around a uranium tailings reservoir... 相似文献
949.
Chen Xiao-Lu Li Xiang-Yu Li Shuai-Shuai Bai Xue Li Tao Goud Erukala Yadaiah Zhong Chong-Min Zuo Ya-Jie 《Russian Journal of General Chemistry》2020,90(11):2163-2169
Russian Journal of General Chemistry - The Grubbs–Hoveyda catalysts have a wide range of applications in catalyzed formation of the carbon-carbon double bonds. In this study, several... 相似文献
950.
Su X. F. Zhang Y. L. Maximov A. L. Zhang K. Xin Q. Feng C. Q. Bai X. F. Wu W. 《Russian Journal of Applied Chemistry》2020,93(1):127-136
Russian Journal of Applied Chemistry - Nanoscale ZSM-5 (AlZ5-D) and Ga-substituted ZSM-5 zeolites ((Al,Ga)Z5-D and GaZ5-D) were synthesized by a green dry-gel conversion strategy. For comparison,... 相似文献