首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   9989篇
  免费   1540篇
  国内免费   1389篇
化学   7777篇
晶体学   85篇
力学   456篇
综合类   101篇
数学   1255篇
物理学   3244篇
  2024年   20篇
  2023年   150篇
  2022年   161篇
  2021年   234篇
  2020年   353篇
  2019年   367篇
  2018年   324篇
  2017年   263篇
  2016年   408篇
  2015年   451篇
  2014年   508篇
  2013年   706篇
  2012年   839篇
  2011年   789篇
  2010年   635篇
  2009年   603篇
  2008年   687篇
  2007年   606篇
  2006年   569篇
  2005年   496篇
  2004年   445篇
  2003年   410篇
  2002年   453篇
  2001年   315篇
  2000年   293篇
  1999年   262篇
  1998年   185篇
  1997年   157篇
  1996年   146篇
  1995年   113篇
  1994年   119篇
  1993年   85篇
  1992年   91篇
  1991年   77篇
  1990年   58篇
  1989年   62篇
  1988年   53篇
  1987年   41篇
  1986年   58篇
  1985年   50篇
  1984年   43篇
  1983年   34篇
  1982年   27篇
  1981年   18篇
  1980年   23篇
  1979年   16篇
  1978年   12篇
  1977年   17篇
  1976年   17篇
  1975年   19篇
排序方式: 共有10000条查询结果,搜索用时 250 毫秒
81.
In this paper, a projection method is presented for solving the flow problems in domains with moving boundaries. In order to track the movement of the domain boundaries, arbitrary‐Lagrangian–Eulerian (ALE) co‐ordinates are used. The unsteady incompressible Navier–Stokes equations on the ALE co‐ordinates are solved by using a projection method developed in this paper. This projection method is based on the Bell's Godunov‐projection method. However, substantial changes are made so that this algorithm is capable of solving the ALE form of incompressible Navier–Stokes equations. Multi‐block structured grids are used to discretize the flow domains. The grid velocity is not explicitly computed; instead the volume change is used to account for the effect of grid movement. A new method is also proposed to compute the freestream capturing metrics so that the geometric conservation law (GCL) can be satisfied exactly in this algorithm. This projection method is also parallelized so that the state of the art high performance computers can be used to match the computation cost associated with the moving grid calculations. Several test cases are solved to verify the performance of this moving‐grid projection method. Copyright © 2004 John Wiley Sons, Ltd.  相似文献   
82.
The central zinc(II) atom in the title complex is tetrahedrally coordinated by four nitrogen atoms derived from 4‐methyl‐5‐imidazolecarboxyaldehyde ligands with Zn? N in the range 2.007(3) to 2.026(4) Å. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
83.
A one‐dimensional zinc(II) coordination polymer has been constructed from zinc(II), 4,4′‐biphenyldicarboxylate and pyridine in which each zinc(II) atom is coordinated by two pyridine ligands and two monodentate 4,4′‐biphenyldicarboxylate ligands that define a distorted tetrahedral geometry. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
84.
85.
在变缓冲层高迁移率晶体管(MM_HEMT)器件中,二维电子气的输运性质对器件性能起着决定作用.通过低温下二维电子气横向电阻的量子振荡现象,结合变温度的Hall测量,系统研究了不同In组分沟道MM_HEMT器件中子带电子迁移率和浓度随温度的变化关系.结果表明,沟道中In组分为0.65的样品,材料电学性能最好,In组分高于0.65的样品,严重的晶格失配将产生位错,引起迁移率下降,大大影响材料和器件的性能. 关键词: 变缓冲层高迁移率晶体管 Shubnikov_de Hass 振荡  相似文献   
86.
In the present paper, we prove that the Bernstein-Kantorovič operators have the ability of preserving translation property in both C and Lp norms. Supported (in part) by the NSFC(10471130,10371024) of PRC and the Natural Science Foundation (Y604003) of Zhejiang Province.  相似文献   
87.
Coaxial cavities are used in high power gyrotrons as the beam-wave interaction structure. Much research has been devoted to their mode selective properties. A coaxial cavity lacks a sharp boundary at its open end, so it has some physical features that can only be observed using a spectral model, such as frequency-dependent field profiles and mode overlapping effects. These properties are important since cold tests are usually conducted in the frequency domain. This study applies the incident/reflected wave boundary condition to the wave equation of a weakly irregular coaxial waveguide. The resistivity of the wall is considered in the analysis. Calculations reveal that the fixed-position spectrum yields an uncertain resonant frequency and quality factor. Although the maximum-field spectrum can uniquely determine the properties of the coaxial cavity, the resonant frequency obtained using the maximum-field spectral model is inconsistent with that obtained using the temporal model. The field-energy spectrum explains the low Q nature of the coaxial cavity. Moreover, resonant frequencies evaluated using the field-energy spectrum agree precisely with those evaluated using the temporal model.  相似文献   
88.
N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine was synthesized from N‐(4‐nitrophenyl)‐diphenylamine by the Vilsmeier‐Haack reaction. Soluble aromatic poly(azomethine)s (PAMs) were prepared by the solution polycondensation of N‐(4‐nitrophenyl)‐4′,4″‐bisformyl‐diphenylamine and aromatic diamine in N‐methyl‐2‐pyrrolidone (NMP) at room temperature under reduced pressure. All the PAMs are highly soluble in various organic solvents, such as N,N‐dimethylacetamide (DMAc), chloroform (CHCl3), and tetrahydrofuran (THF). Differential scanning calorimetry (DSC) indicated that these PAMs had glass‐transition temperatures (Tgs) in the range of 170–230 °C, and a 10% weight‐loss temperatures in excess of 490 °C with char yield at 800 °C in nitrogen higher than 60%. These PAMs in NMP solution showed UV‐Vis charge‐transfer (CT) absorption at 405–421 nm and photoluminescence peaks around 462–466 nm with fluorescence quantum efficiency (ΦF) 0.10–0.99%. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) energy levels of these PAMs can be determined from cyclic voltammograms as 4.86–5.43 and 3.31–3.34 eV, respectively. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4921–4932, 2007  相似文献   
89.
测定了丝瓜种子萌芽及子叶不同生长阶段的谷氨酰胺合成酶(GS)的活性及其同工酶的变化.除了发育上的变化外,光和外源氮对GS活性及其同工酶影响也是显著的.无论外源氮(N)是否存在,GS活性在种子萌芽和子叶生长初期是逐渐升高的,于第6天达到最大,其后活性逐步降低.在光照下,外源氮对GS1诱导作用大于GS2;在无氮下,光对GS2的刺激大于GS1;在暗处,外源氮对GS1和GS2两者都有诱导作用.  相似文献   
90.
A New Bibenzyl Glycoside from Dendrobium moniliforme   总被引:1,自引:0,他引:1  
A new bibenzyl glycoside has been isolated from the stems of Dendrobium moniliforme (L.) Sw.(Orchidaceas).Its structure has been identified on the basis of spectroscopic and chemical methods.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号