半导体远红外反射镜中反射率和相位研究

以GaAs材料为例，研究了半导体远红外反射镜中的反射率和相位.通过拟合不同掺杂浓度下样品的远红外反射谱，得到了自由载流子的弛豫时间随掺杂浓度变化的经验公式，并把该规律应用到数值计算中.详细讨论了反射镜的结构和材料参数对反射率R和相位φ的影响.根据腔体内吸收率最高的判据得到了最优的反射镜的参数，并计算了这种优化后的反射镜的波长选择特性.最后，通过远红外反射光谱的测量，从实验上验证了这种反射镜的实际效果. 所得结论为半导体远红外器件中的反射镜设计提供了参考. 关键词： 远红外反射镜 反射率 相位     

超光滑表面加工方法的新进展

通过回顾超光滑表面加工技术的发展历程,对多种具有代表性的超光滑表面加工方法的原理和应用作了简单阐述,并重点提出和介绍了一种大气等离子体抛光方法。该方法实现了利用常压等离子体激发化学反应来完成超光滑表面的无损伤抛光加工,并首次引入电容耦合式炬型等离子体源,为高质量光学表面的加工提供了一条新的途径。试验结果表明,在针对单晶硅的加工过程中实现了1μm/min的加工速率和Ra 0.6nm的表面粗糙度。     

Decay of 1.643 h <Superscript>95</Superscript>Ru and its daughter's level structure

The decay of ⁹⁵Ru has been investigated by means of γ-ray spectroscopy. The ⁹⁵Ru nuclei were produced by the reaction ⁹²Mo( α, n) ⁹⁵Ru at a beam energy of 17MeV. High-purity Ge detectors have been used singly and in coincidence to study γ-rays in the decay of ⁹⁵Ru to ⁹⁵Tc. 132 γ-rays are reported, among them, energies and intensities for 127 transitions have been determined. A decay scheme of ⁹⁵Ru with 31 levels is proposed which accommodates 127 of these transitions. Spins and parities for three new levels are proposed from calculated log ft values, measured γ-ray branching ratios, and in-beam experiment results of the daughter nucleus ⁹⁵Tc. Combining with the high-spin states observed by in-beam γ-ray spectroscopy of previous decay works, the structure of the excited states of ⁹⁵Tc is discussed in the framework of the projected shell model.     

A Comparative ESR Study on Blood and Tissue Nitric Oxide Concentration during Renal Ischemia-Reperfusion Injury

Electron paramagnetic resonance (EPR) spin trapping technology is a sensitive and unambiguous method for detection of nitric oxide (NO). Due to the short lifetime, NO must be trapped before EPR measurement. There are two EPR spin trapping techniques used currently, including the detections of EPR signals of diethyldithiocarbamate-iron-nitric oxide (DETC₂-Fe²⁺-NO) and nitrosyl hemoglobin (HbNO). In this study, we firstly investigated the kinetics of the EPR signal of DETC₂-Fe²⁺-NO in normal and ischemia-reperfused kidneys. In normal rat kidneys, the signal of DETC₂-Fe²⁺-NO was found at 5 min after the spin trappers Fe²⁺/DETC were administrated, the peak concentration was at 15 min and the period with relatively stable signal intensity was at the time range from 15 to 70 min. In the ischemia-reperfused rat kidneys, the signal of DETC₂-Fe²⁺-NO was increased at 30 min of ischemia and decreased at 60 min of ischemia after the occlusion of renal artery (corresponding to the time course of 60 and 90 min after Fe²⁺/DETC injection respectively). We then investigated the EPR signal of HbNO in blood. No characteristic HbNO signal was found in the rats of the sham control and 30 min of ischemia. An HbNO signal occurred in the rats exposed to 60 min of ischemia and it became pronounced with increased duration of reperfusion. The signal intensity reached a plateau at 150 min of reperfusion. The results suggest that the DETC₂-Fe²⁺-NO signal can be only suitable for the NO measurement in the short-term ischemia-reperfusion model, whereas the HbNO signal can be applied to represent NO in the relatively long-term ischemia-reperfusion model. In addition, N^G-nitro-L-arginine (L-NAME) and allopurinol were used to identify the source of NO. By detecting the HbNO signal, we demonstrated that the activation of xanthine oxidase is an important source of NO formation at the long-term period of ischemia and reperfusion. Authors' address: Jiangang Shen, School of Chinese Medicine, University of Hong Kong, 10 Sassoon Road, Hong Kong SAR, China     

Calculation of triaxial superdeformation in <Superscript>174</Superscript>Hf

A two-dimensional Total Routhian Surface (TRS) calculation with the fixed hexadecapole deformation ε4 = 0.03 was carried out for several configurations of 174Hf. Results indicate that the shell corrections have an important contribution to the formation of triaxial superdeformation in 174Hf and some possible configuration assignments are made to the 4 TSD bands experimentally found in 174Hf.     

Negative permeability in a <Emphasis Type="Bold">Λ</Emphasis>-type three-level atomic vapor

A new approach is suggested to realize negative magnetic permeability that follows directly from quantum mechanics. It is shown that a Λ-type three-level atomic system with proper atomic parameters can give rise to striking magnetic responses, which could exhibit negative permeability in an optical frequency band. Both steady and transient behaviors of the magnetic permeability in the atomic vapor are studied. The present negative-permeability vapor could be mixed with a quantum coherent vapor whose electric permittivity is negative. Such a mixed vapor may give an isotropic left-handed vapor medium at the atomic-scale level. PACS 32.10.Dk; 42.50.Gy; 78.20.Ci     

Study of K<Superscript>*</Superscript><Subscript>0</Subscript>(1430) and a<Subscript>0</Subscript>(980) from B→K<Superscript>*</Superscript><Subscript>0</Subscript>(1430)π and B→a<Subscript>0</Subscript>(980)K decays

We use the decay modes B→K^* ₀(1430)π and B→a₀(980)K to study the scalar mesons K^* ₀(1430) and a₀(980) within the framework of perturbative QCD. For B→K^* ₀(1430)π, we perform our calculation in two scenarios for the scalar meson spectrum. The results indicate that scenario II is more favored by the experimental data than scenario I. The important contribution from annihilation diagrams can enhance the branching ratios by about 50% in scenario I and about 30% in scenario II. The direct CP-asymmetries in B→K^* ₀(1430)π are small, which is consistent with the present experiments. The predicted branching ratio of B→a₀(980)K in scenario I differs from the experiments by a factor of 2, which indicates that a₀(980) cannot be interpreted as q̄q.     

Initiation of petroleum formation and antioxidant function – a DFT study of sulfur?sulfur bond dissociation enthalpies

Experimental studies showed that sulfur radicals play the vital role in petroleum formation. 1 Sulfur‐ centered radicals also exhibit activities in antioxidant functions. Here we conduct a theoretical investigation of their precursor‐disulfides. By investigation into substituent effect on sulfur? sulfur bond dissociation enthalpies (S? S BDEs), we would like to find the most effective provider for sulfur radicals. In the present work, 50 alpha‐substituted disulfides and 16 para‐substituted aryl disulfides are studied systematically, with the general formula XS‐SX or HS‐SX. The substituent effect on S? S BDEs is found to be very eminent, ranging from 33.2 to 75.0 kcal/mol for alpha‐substituted disulfide, and from 43.7 to 59.7 kcal/mol for para‐substituted phenyl disulfides. We also evaluate the performance of 44 density functional methods to get an accurate prediction. A further study indicates that substituents play a major role in radical energies, instead of molecule energies, which is substantiated by the good linearity between XS‐SX bond dissociation enthalpy (BDE) and HS‐SX BDE. Copyright © 2007 John Wiley & Sons, Ltd.     

Growth of cubic MgxZn1−xO alloy films by electron beam evaporation

We report the growth of cubic Mg_xZn_1−xO alloy thin films on quartz by electron beam evaporation. It can be found that all the samples have sharp absorption edges by the absorption measurements. X-ray diffraction measurements indicate the Mg_xZn_1−xO films are cubic phase with preferred orientation along the (1 1 1) direction. Energy dispersive spectrometry (EDS) demonstrates that the Mg concentration in Mg_xZn_1−xO films is much higher than the ceramic target used, and the composition can be tuned in a small scope by varying the substrate temperature and the beam electric current. The reasons of this phenomenon are also discussed.