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排序方式: 共有1397条查询结果,搜索用时 62 毫秒
61.
Dr. Guo‐Qiang Kong Zhi‐Da Han Dr. Yabing He Sha Ou Dr. Wei Zhou Prof. Dr. Taner Yildirim Prof. Dr. Rajamani Krishna Dr. Chao Zou Prof. Dr. Banglin Chen Prof. Dr. Chuan‐De Wu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(44):14886-14894
Two new organic building units that contain dicarboxylate sites for their self‐assembly with paddlewheel [Cu2(CO2)4] units have been successfully developed to construct two isoreticular porous metal–organic frameworks (MOFs), ZJU‐35 and ZJU‐36, which have the same tbo topologies (Reticular Chemistry Structure Resource (RCSR) symbol) as HKUST‐1. Because the organic linkers in ZJU‐35 and ZJU‐36 are systematically enlarged, the pores in these two new porous MOFs vary from 10.8 Å in HKUST‐1 to 14.4 Å in ZJU‐35 and 16.5 Å in ZJU‐36, thus leading to their higher porosities with Brunauer–Emmett–Teller (BET) surface areas of 2899 and 4014 m2 g?1 for ZJU‐35 and ZJU‐36, respectively. High‐pressure gas‐sorption isotherms indicate that both ZJU‐35 and ZJU‐36 can take up large amounts of CH4 and CO2, and are among the few porous MOFs with the highest volumetric storage of CH4 under 60 bar and CO2 under 30 bar at room temperature. Their potential for high‐pressure swing adsorption (PSA) hydrogen purification was also preliminarily examined and compared with several reported MOFs, thus indicating the potential of ZJU‐35 and ZJU‐36 for this important application. Studies show that most of the highly porous MOFs that can volumetrically take up the greatest amount of CH4 under 60 bar and CO2 under 30 bar at room temperature are those self‐assembled from organic tetra‐ and hexacarboxylates that contain m‐benzenedicarboxylate units with the [Cu2(CO2)4] units, because this series of MOFs can have balanced porosities, suitable pores, and framework densities to optimize their volumetric gas storage. The realization of the two new organic building units for their construction of highly porous MOFs through their self‐assembly with [Cu2(CO2)4] units has provided great promise for the exploration of a large number of new tetra‐ and hexacarboxylate organic linkers based on these new organic building units in which different aromatic backbones can be readily incorporated into the frameworks to tune their porosities, pore structures, and framework densities, thus targeting some even better performing MOFs for very high gas storage and efficient gas separation under high pressure and at room temperature in the near future. 相似文献
62.
Zhi-Hua?Hu Yingxue?ZhaoEmail author Sha?Tao Zhao-Han?Sheng 《Annals of Operations Research》2015,235(1):37-49
This work addresses a new transportation problem in outbound logistics in the automobile industry: the finished-vehicle transporter routing problem (FVTRP). The FVTRP is a practical routing problem with loading constraints, and it assumes that dealers have deterministic demands for finished vehicles that have three-dimensional irregular shapes. The problem solution will identify optimal routes while satisfying demands. In terms of complex packing, finished vehicles are not directly loaded into the spaces of transporters; instead, loading patterns matching finished vehicles with transporters are identified first by mining successful loading records through virtual and manual loading test procedures, such that the packing problem is practically solved with the help of a procedure to discover loading patterns. This work proposes a mixed-integer linear programming (MILP) model for the FVTRP considering loading patterns. As a special class of routing models, the FVTRP is typically difficult to solve within a manageable computing time. Thus, an evolutionary algorithm is designed to solve the FVTRP. Comparisons of the proposed algorithm and a commercial MILP solver demonstrate that the proposed algorithm is more effective in solving medium- and large-scale problems. The proposed scheme for addressing the FVTRP is illustrated with an example and tested with benchmark instances that are derived from well-studied vehicle routing datasets. 相似文献
63.
Pd-catalyzed annulation of aryne and aryl ketone O-acetyloxime via C–H bond activation was realized. Through the C–H bond activation/insertion/cyclization/elimination reaction sequence, phenanthridines are successfully constructed, providing an attractive strategy to approach substituted heterocycle without preactivation of starting materials. 相似文献
64.
Xiaojuan Liao Lei Guo Junxia Chang Sha Liu Meiran Xie Guosong Chen 《Macromolecular rapid communications》2015,36(16):1492-1497
Pillararene‐containing thermoresponsive polymers are synthesized via reversible addition–fragmentation chain transfer polymerization using pillararene derivatives as the effective chain transfer agents for the first time. These polymers can self‐assemble into micelles and form vesicles after guest molecules are added. Furthermore, such functional polymers can be further applied to prepare hybrid gold nanoparticles, which integrate the thermoresponsivity of polymers and molecular recognition of pillararenes.
65.
Jun Zhou Prof. Sha Yang Yesen Tan Huaisheng Cheng Dr. Jinsong Chai Prof. Manzhou Zhu 《化学:亚洲杂志》2021,16(19):2973-2977
The change in the valence state of nanocluster can induce remarkable changes in the properties and structure. However, achieving the valence state changes in nanoclusters is still a challenge. In this work, we use Cu2+ as dopant to “oxidize” [Ag62S12(SBut)32]2+ (4 free electrons) to obtain the new nanocluster: [Ag62−xCuxS12(SBut)32]4+ with 2 free electrons. As revealed by its structure, the [Ag62−xCuxS12(SBut)32]4+ (x=10∼21) has a similar structure to that of [Ag62S12(SBut)32]2+ precursor and all the Cu atoms occupy the surface site of nanocluster. It′s worth noting that with the Cu atoms doping, the [Ag62−xCuxS12(SBut)32]4+ nanocluster is more stable than [Ag62S12(SBut)32]2+ at higher temperature and in electrochemical cycle. This result has laid a foundation for the subsequent application and exploration. Overall, this work reveals crystals structure of a new Ag−Cu nanocluster and offers a new insight into the electron reduction/oxidation of nanocluster. 相似文献
66.
硅氧化物(SiOx, 0<x≤2)具有高的比容量和低的嵌锂电位, 且体积膨胀率显著低于纯硅负极, 因而被认为是替代传统石墨负极材料的理想选择之一. 然而SiOx负极在首次嵌锂过程中表面形成的固体电解质界面膜(SEI)以及大量的不可逆产物, 造成其首次库伦效率偏低, 严重阻碍了SiOx负极的实际应用. 本文从SiOx的结构模型出发, 系统阐述了SiOx负极的嵌锂机理以及首次库伦效率低的原因; 归纳了SiOx负极首次库伦效率的提升策略及其研究进展; 并对提升SiOx负极首次库伦效率的未来发展方向进行了展望. 相似文献
67.
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69.
Xiaofeng Wang Zheng You Hailiang Sha Zhaolan Sun Wei Sun 《Journal of Solid State Electrochemistry》2014,18(1):207-213
In this paper, a Fe3O4@SiO2 core-shell structure microsphere was synthesized and used to investigate the direct electron transfer of myoglobin (Mb) with a 1-butylpyridinium hexafluorophosphate based carbon ionic liquid electrode (CILE) as the substrate electrode. The mixture of Mb and Fe3O4@SiO2 microsphere could form an organic–inorganic composite, which was immobilized on the surface of CILE with a chitosan (CS) film. Cyclic voltammetric experiments indicated that a pair of well-defined quasi-reversible redox peaks appeared on CS/Mb-Fe3O4@SiO2/CILE with the formal peak potential (E 0′) located at ?0.31 V (vs. saturated calomel electrode), which was corresponded to the electroactive center of Mb heme Fe(III)/Fe(II) redox couples. Direct electrochemical behaviors of Mb in CS-Fe3O4@SiO2 composite film were carefully investigated with the electrochemical parameters calculated. The CS/Mb-Fe3O4@SiO2/CILE showed good electrocatalytic behaviors to the reduction of trichloroacetic acid in the concentration range from 0.2 to 11.0 mmol L?1 with the detection limit of 0.18 mmol L?1 (3σ). Based on CS/Mb-Fe3O4@SiO2/CILE, a new third-generation reagentless electrochemical biosensor was constructed with higher sensitivity and reproducibility. 相似文献
70.
Two‐Component Supramolecular Gels Derived from Amphiphilic Shape‐Persistent Cyclo[6]aramides for Specific Recognition of Native Arginine 下载免费PDF全文
Youzhou He Min Xu Rongzhao Gao Xiaowei Li Fengxue Li Xuedan Wu Prof. Dingguo Xu Dr. Huaqiang Zeng Prof. Lihua Yuan 《Angewandte Chemie (International ed. in English)》2014,53(44):11834-11839
A unique supramolecular two‐component gelation system was constructed from amphiphilic shape‐persistent cyclo[6]aramides and diethylammonium chloride (or triethylammonium chloride). This system has the ability to discriminate native arginine from 19 other amino acids in a specific fashion. Cyclo[6]aramides show preferential binding for the guanidinium residue over ammonium groups. This specificity was confirmed by both experimental results and theoretical simulations. These results demonstrated a new modular displacement strategy, exploring the use of species‐binding hydrogen‐bonded macrocyclic foldamers for the construction of two‐component gelation systems for selective recognition of native amino acids by competitive host–guest interactions. This strategy may be amenable to developing a variety of functional two‐component gelators for specific recognition of various targeted organic molecular species. 相似文献