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排序方式: 共有1327条查询结果,搜索用时 26 毫秒
91.
Roya Zahedi Faramarz Afshar Taromi Seyed Heidar Mirjahanmardi Mehdi Nekoomanesh Haghighi Roghayeh Jamjah Khosrow Jadidi 《Polymer Science Series B》2016,58(2):143-151
Two new ethers were synthesized using the Williamson reaction from related alcohols and were used as external donors in propylene polymerization in the presence of the industrial diisobutyl phthalate-based MgCl2-supported Ziegler-Natta catalyst. For comparison the propylene polymerization was carried out in the presence of silane and in the absence of external donors. The produced polymers were characterized by differential scanning calorimetry, xylene extraction, melt flow index, scanning electron microscopy and gel permeation chromatography. The isotacticity, molecular weight and molecular weight distribution, melt flow index, crystallinity degree and thermal properties of polypropylenes were influenced by the type of external donors. 相似文献
92.
Mohammad Hossein Tavakoli Hossein KarbaschiFeridoun Samavat Ebrahim Mohammadi-Manesh 《Journal of Crystal Growth》2010,312(21):3198-3203
A set of 2D finite element numerical simulation of induction heating process for an oxide Czochralski crystal growth system has been made for a range of f=1–100 kHz applied frequency of driving current. It was shown that the frequency selection has a marked effect in all basic induction phenomena, including electromagnetic field distribution, skin depth, coil efficiency, and intensity and structure of heating in the growth setup. 相似文献
93.
94.
Tofighi-Niaki Ebrahim Asgharifard-Sharabiani Pouya Ahmadian Hamid 《Nonlinear dynamics》2018,94(4):2937-2956
Nonlinear Dynamics - Rub–impact phenomenon occurring in hydrodynamic journal bearings is one of the main malfunctions in rotating machines and causes undesirable dynamic behavior. In order to... 相似文献
95.
96.
Kazem Jeddi Nader Taheri Qazvini Seyed Hassan Jafari Hossein Ali Khonakdar Javad Seyfi Uta Reuter 《Journal of Polymer Science.Polymer Physics》2011,49(4):318-326
Polymer–silicate nanocomposites based on poly (ethylene oxide), PEO, poly(methyl methacrylate), PMMA, and sodium montmorillonite clay were fabricated and characterized to investigate the effect of nanolayered silicates on segmental dynamics of PEO/PMMA blends. X‐ray results indicate the formation of an exfoliated morphology in the nanocomposites. At low silicate contents, an enhancement in segmental dynamics of blend nanocomposites and also PEO, minor component in blend, is observed at temperature region below blend glass transition. This result can be attributed to the improvement of the confinement effect of rigid PMMA matrix on the PEO chains by introducing a low amount of layered silicates. On the other hand, at high silicate contents, an enhancement in segmental dynamics of blend nanocomposites and PEO is observed at temperature region above blend glass transition. This behavior could be interpreted based on the reduction of monomeric friction between two polymer components, which can facilitate segmental motions of blend components in nanocomposite systems. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
97.
Silver nanoparticles supported on ionic‐tagged magnetic hydroxyapatite as a highly efficient and reusable nanocatalyst for hydrogenation of nitroarenes in water 下载免费PDF全文
A novel chemically modified magnetic hydroxyapatite (MHAp) was prepared and used as support and stabilizer for the synthesis of silver nanoparticles. First, 1,4‐diazabicyclo[2.2.2]octane (DABCO) was successfully grafted onto the surface of MHAp, and then silver nanoparticles were homogeneously loaded on mesoporous MHAp‐DABCO (ionic‐tagged MHAp) nanocomposite by in situ chemical reduction of silver nitrate using sodium borohydride. The structure and properties of the resulting MHAp‐DABCO‐Ag nanocomposite were confirmed using various techniques. The catalytic activity of ionic‐tagged MHAp‐Ag nanocatalyst was investigated for the hydrogenation reaction of nitroarenes in aqueous media. The results reveal that the Ag‐containing inorganic–organic nanocomposite is highly efficient for the reduction of a wide range of aromatic nitro compounds under green conditions. The superparamagnetic nature of the nanocatalyst leads to its being readily removed from solution via application of a magnetic field, and it can be easily stored and reused. 相似文献
98.
Ebrahim Ghorbani 《Graphs and Combinatorics》2013,29(5):1377-1389
We determine all graphs whose matching polynomials have at most five distinct zeros. As a consequence, we find new families of graphs which are determined by their matching polynomials. 相似文献
99.
Two main existence conditions for solutions of variational relation problems are established without convexity. The first one is based on a finite solvability property and the second one on generalized KKM mappings. These conditions unify and strengthen several existing results in the literature on the topic. A model of satisficing process by rejection is considered which gives an economic interpretation of the introduced concepts. 相似文献
100.
Matrix Heterogeneity Effects on Gas Transport and Adsorption in Coalbed and Shale Gas Reservoirs 总被引:2,自引:0,他引:2
In coalbeds and shales, gas transport and storage are important for accurate prediction of production rates and for the consideration
of subsurface greenhouse gas sequestration. They involve coupled fluid phenomena in porous medium including viscous flow,
diffusive transport, and adsorption. Standard approach to describe gas–matrix interactions is deterministic and neglects the
effects of local spatial heterogeneities in porosity and material content of the matrix. In this study, adopting weak-noise
and mean-field approximations and using a statistical approach in spectral domain, matrix heterogeneity effects are investigated
in the presence of non-equilibrium adsorption with random partition coefficient. It is found that the local heterogeneities
can generate non-trivial transport and kinetic effects which retard gas release from the matrix and influence the ultimate
gas recovery adversely. Macro-transport shows 1/[1 + N
Pe
/(1 + N
Pe
)] dependence on the Péclet number, and persists at the diffusive ultra-low permeability limit. Macro-kinetics is directly
related to Thiele modulus by the following expression: N
Th
/(1 + 2N
Pe
). It leads to trapping of gas in the adsorbed phase during its release from the matrix, and to an adsorption threshold during
the gas uptake by the matrix. Both effects are proportional to the initially available adsorbed gas amount and becomes more
pronounced with the increasing variance of the porosity field. Consequently, a new upscaled deterministic gas mass balance
is proposed for practical purposes. Numerical results are presented showing free and adsorbed gas distributions and fractional
gas sorption curves for unipore coal matrix exhibiting Gaussian porosity distribution. This study is a unique approach for
our further understanding of the coalbeds and gas shales, and it is important for the development of sound numerical gas production
and sequestration models. 相似文献