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21.
A hybrid meshless technique based on composition of meshless local Petrov–Galerkin method (for spatial variables) and Newmark finite difference method (for time domain) is developed for natural frequencies analysis of thick cylinder made of functionally graded materials (FGMs). The FG cylinder is assumed to be under suddenly thermal loading, axisymmetric and plane strain conditions. The dynamic behaviors and time history of displacements are obtained in time domain using Green–Naghdi (GN) theory of coupled thermo-elasticity (without energy dissipation). Using fast Fourier transform (FFT) technique, the displacements are transferred to frequency domain and all natural frequencies are illustrated for various grading patterns of FGMs. The variations of mechanical properties in FG thick hollow cylinder are considered to be in nonlinear volume fraction law through radial direction. The presented hybrid meshless technique furnishes a ground to analyze the effects of various grading patterns of FGMs on natural frequencies, which are obtained employing GN coupled thermo-elasticity governing equations. Also, the frequency history and natural frequencies are illustrated for various grading patterns at several points across thickness of cylinder. 相似文献
22.
Abbas Ghasempour Ardakani Mehdi Hosseini Ali Reza Bahrampour Seyed Mohammad Mahdavi 《Optics Communications》2012,285(7):1900-1904
We propose that spectral intensity of superconductor based random lasers can be made tunable by changing temperature. The two fluid model and wavelength dependent dispersion formula have been employed to describe the optical response of the superconducting materials. Random laser characteristics have been calculated using the one dimensional FDTD method. Our simulation results reveal that the emission spectrum can be manipulated through the ambient temperature of the system. It is observed that transition from metal phase to pure superconducting phase leads to the enhancement of the laser emission. Furthermore, spatial distribution of the fields in one dimensional disordered media is very sensitive to the system temperature. 相似文献
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Chemistry of Heterocyclic Compounds - This microreview describes recent approaches to the synthesis of thieno[2,3-b]pyridine derivatives. Selected works published in 2015–2019 are reviewed. 相似文献
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A palladium–fibroin complex (Pd/Fib.) was prepared by the addition of sonicated fibroin fiber in water to palladium acetate solution. Pd (OAc)2 was absorbed by fibroin and reduced with NaBH4 at room temperature to the Pd(0) nanoparticles. Powder‐X‐ray diffraction, scanning electron microscopy–energy‐dispersive X‐ray spectroscopy, Fourier transform‐infrared, CHN elemental analysis and inductively coupled plasma‐atomic emission spectroscopy were carried out to characterize the Pd/Fib. catalyst. Catalytic activity of this finely dispersed palladium was examined in the Heck coupling reaction. The catalytic coupling of aryl halides (‐Cl, ‐Br, ‐I) and olefins led to the formation of the corresponding coupled products in moderate to high yields under air atmosphere. A variety of substrates, including electron‐rich and electron‐poor aryl halides, were converted smoothly to the targeted products in simple procedure. Heterogeneous supported Pd catalyst can be recycled and reused several times. 相似文献
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In recent years ionic liquids (ILs) have attracted much interest because of their widespread use in various fields. Several trimerization and oligomerization catalysts have been evaluated in ILs with different organic–inorganic hybrid structures. High catalytic activity and selectivity, easy product separation, and recycling of the catalyst are the advantages of a biphasic catalyst system compared to the homogeneous catalysts. In this study, the influence of IL counter-anions on activity and selectivity of the ethylene trimerization catalysts based on Cr-SNS-R was investigated. All synthesized materials were characterized using Fourier-transform infrared spectroscopy, 1H NMR, 13C NMR, UV–Vis. spectroscopy, thin-layer chromatography, and elemental analysis (CHNS). In ethylene trimerization reaction, the dodecyl substituent in the SNS ligand exhibited better activity and selectivity than the butyl substituent. The results revealed that the presence of BF4− as a counter-anion in the IL led to an increase in activity and selectivity compared to Br− and I− counter-anions. It was found that the BF4− counter-anion plays a conclusive role in the development of 1-hexene activity and selectivity to a maximum amount of 71,132 g1-C6/(gCr × h) and more than 99%, respectively. Finally, the catalyst was reused thrice without losing its 1-hexene selectivity. 相似文献
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Seyed Ahmad Razavizadeh Setareh Sheikh 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2019,93(4):625-630
Russian Journal of Physical Chemistry A - A new simple and accurate functional form for an attractive parameter α is introduced for Peng–Robinson equation of state. The modified... 相似文献
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Novel functionalized graphene adsorbent was prepared and characterized using different techniques. The prepared adsorbent was applied for the removal of cadmium ions from aqueous solution. A response surface methodology was used to evaluate the simple and combined effects of the various parameters, including adsorbent dosage, pH, and initial concentration. Under the optimal conditions, the cadmium removal performance of 70% was achieved. A good agreement between experimental and predicted data in this study was observed. The experimental results revealed of cadmium adsorption with high linearity follow Langmuir isotherm model with maximum adsorption capacity of 502 mg g?1, and the adsorption data fitted well into pseudo‐second order model. Thermodynamic studies showed that adsorption process has exothermic and spontaneous nature. The recommended optimum conditions are: cadmium concentration of 970 mg L?1, adsorbent dosage of 1 g L?1, pH of 6.18, and T = 25 °C. The magnetic recovery of the adsorbent was performed using a magnetic surfactant to form a noncovalent magnetic functionalized graphene. After magnetic recovery of the adsorbent both components (adsorbent and magnetic surfactant) were recycled by tuning the surface charges through changing the pH of the solution. Desorption behavior studied using HNO3 solution indicated that the adsorbent had the potential for reusability. 相似文献
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