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81.
A theoretical analysis of the temperature-dependent (31)P NMR signals for the ambient pressure vanadyl pyrophosphate AP-(VO)(2)P(2)O(7) and the oxovanadium hemihydrate hydrogenophosphate VO(HPO(4)).0.5H(2)O phases is reported. The ab initio calculation of the magnetic exchange parameters and the hyperfine constants gives access to an original ab initio simulation of NMR spectra. Such a strategy allows one to clarify the crystallographic nature of the different experimentally studied phases. For the vanadyl pyrophosphate ambient pressure structure, our simulations strongly support the presence of a monoclinic phase. Based on this assumption, hyperfine constants are extracted from the fit of the experimental data. These values are directly compared to the ab initio ones. 相似文献
82.
Schaller RD Pietryga JM Goupalov SV Petruska MA Ivanov SA Klimov VI 《Physical review letters》2005,95(19):196401
We observe ultrafast 1P-to-1S intraband relaxation in PbSe and CdSe nanocrystals (NCs) that have distinct energy spectra. While ultrafast dynamics in CdSe NCs has typically been interpreted in terms of electron-hole energy transfer, this mechanism is not active in PbSe NCs because of sparse densities of states in the conduction and valence bands. Our observations of temperature activation and confinement-enhanced relaxation in PbSe NCs can be explained by efficient multiphonon emission triggered by nonadiabatic electron-phonon interactions and are indicative of large, size-dependent, intraband Huang-Rhys parameters. 相似文献
83.
Zolotukhin M Fomine S Salcedo R Khalilov L 《Chemical communications (Cambridge, England)》2004,(8):1030-1031
Reaction of carbonyl compounds bearing electron-withdrawing substituents with non-activated aromatic hydrocarbons proceeds selectively in trifluoromethanesulfonic acid (TFSA) at room temperature to give linear, high-molecular-weight polymers. 相似文献
84.
85.
Susanne Langer Serguei A Nazarov Maria Specovius-Neugebauer 《Comptes Rendus Mecanique》2004,332(8):591-596
For a three-dimensional exterior problem in the framework of anisotropic elasticity, artificial boundary conditions are constructed on a polyhedral truncation surface. These conditions do not need an explicit formula for the fundamental matrix. An approach to adapt the shape of truncation surfaces to the shape of the enclosed cavity is discussed. To cite this article: S. Langer et al., C. R. Mecanique 332 (2004). 相似文献
86.
Two approaches are proposed for the modelling of problems with small geometrical defects. The first approach is based on the theory of self adjoint extensions of differential operators. In the second approach function spaces with separated asymptotics and point asymptotic conditions are introduced, and the variational formulation is established. For both approaches the accuracy estimates are derived. Finally, the spectral problems are considered and the error estimates for eigenvalues are given. To cite this article: S.A. Nazarov, J. Sokolowski, C. R. Mecanique 331 (2003). 相似文献
87.
We consider a discrete-time process adapted to some filtration which lives on a (typically countable) subset of ? d , d≥2. For this process, we assume that it has uniformly bounded jumps, and is uniformly elliptic (can advance by at least some fixed amount with respect to any direction, with uniformly positive probability). Also, we assume that the projection of this process on some fixed vector is a submartingale, and that a stronger additional condition on the direction of the drift holds (this condition does not exclude that the drift could be equal to 0 or be arbitrarily small). The main result is that with very high probability the number of visits to any fixed site by time n is less than $n^{\frac{1}{2}-\delta}$ for some δ>0. This in its turn implies that the number of different sites visited by the process by time n should be at least $n^{\frac{1}{2}+\delta}$ . 相似文献
88.
Arkhipova Ekaterina A. Strokova Natalia E. Tambovtseva Yulia A. Ivanov Anton S. Chernyak Sergei A. Maslakov Konstantin I. Egorova Tolganay B. Savilov Serguei V. Lunin Valery V. 《Journal of Thermal Analysis and Calorimetry》2020,140(6):2641-2648
Journal of Thermal Analysis and Calorimetry - Combustion heats of graphene nanoflakes (GNFs) of different thicknesses produced by chemical vapor deposition method were measured for the first time... 相似文献
89.
90.
It is well known that a finite graph can be viewed, in many respects, as a discrete analogue of a Riemann surface. In this paper, we pursue this analogy further in the context of linear equivalence of divisors. In particular, we formulate and prove a graph-theoretic analogue of the classical Riemann-Roch theorem. We also prove several results, analogous to classical facts about Riemann surfaces, concerning the Abel-Jacobi map from a graph to its Jacobian. As an application of our results, we characterize the existence or non-existence of a winning strategy for a certain chip-firing game played on the vertices of a graph. 相似文献