Scope of the radical addition-cyclization-elimination reaction of oxime ether towards the synthesis of tricyclic lactam derivatives

The synthesis of tricyclic lactam building blocks by the radical addition-cyclization-elimination (RACE) reaction is presented. A range of oxime ethers carrying unsaturated ester part have been tested for the radical reaction. A variety of substituents were incorporated around the aromatic backbones and their effect on the RACE reaction has been examined. In addition, the power of RACE reaction is demonstrated by preparation of a key intermediate for the synthesis of constrained analogue of methoctramine.     

A rare unsupported iridium(II) dimer, [IrCl2(CO)2]2

Oxidative additions of dichloromethanes to a diiridium(i) core, bridged by 2-ferrocenyl-1,8-naphthyridines (NP-Fc), provide an iridium(II) dimer, [IrCl2(CO)2(eta 1-NP-Fc)]2, featuring an unsupported Ir-Ir single bond (2.7121(8) A).     

Wormhole supported by dark energy admitting conformal motion

In this article, we study the possibility of sustaining static and spherically symmetric traversable wormhole geometries admitting conformal motion in Einstein gravity, which presents a more systematic approach to search a relation between matter and geometry. In wormhole physics, the presence of exotic matter is a fundamental ingredient and we show that this exotic source can be dark energy type which support the existence of wormhole spacetimes. In this work we model a wormhole supported by dark energy which admits conformal motion. We also discuss the possibility of the detection of wormholes in the outer regions of galactic halos by means of gravitational lensing. Studies of the total gravitational energy for the exotic matter inside a static wormhole configuration are also performed.     

Convective flow of a Maxwell hybrid nanofluid due to pressure gradient in a channel

In this work, analytical solution of hybrid Maxwell nanofluid of the vertical channel due to pressure gradient is discussed. By introducing dimensionless variables the governing equations with all levied initial and boundary conditions is converted into dimensionless form. Fractional model for Maxwell fluid is developed by Caputo time fractional differential operator by using the constitutive relation. The dimensionless expression for temperature and velocity are found using Laplace transform. Draw graphs of temperature and velocity by Mathcad software and discuss the behavior of flow parameters and the effect of fractional parameters. As a result, we have found by increasing the volumetric fraction of copper and alumina temperature increases and velocity decreases. Also, fluid flow properties showed dual behavior for small and large time, respectively, by increasing fractional parameters values.

     

Double-beta decay Q values of Cd and Te

The Q values of the ¹¹⁶Cd and ¹³⁰Te double-beta decaying nuclei were determined by using a Penning trap mass spectrometer. The new atomic mass difference between ¹¹⁶Cd and ¹¹⁶Sn of 2813.50(13) keV differs by 4.5 keV and is 30 times more precise than the previous value of 2809(4) keV. The new value for ¹³⁰Te, 2526.97(23) keV is close to the Canadian Penning trap value of 2527.01 ± 0.32 keV (Scielzo et al., 2009) [1], but differs from the Florida State University trap value of 2527.518 ± 0.013 keV (Redshaw et al., 2009) [2] by 0.55 keV (2σ). These values are sufficiently precise for ongoing neutrinoless double-beta decay searches in ¹¹⁶Cd and ¹³⁰Te. Hence, our Q values were used to compute accurate phase-space integrals for these double-beta decay nuclei. In addition, experimental two-neutrino double-beta decay nuclear matrix elements were determined and compared with the theoretical values. The neutrinoless double-beta decay half-lives for these nuclei were estimated using our precise phase-space integrals and considering the range of the best available matrix elements values.     

A trinuclear bright red luminophore containing cyclometallated Ir(III) motifs

The trinuclear complex [{Ir(ppy)(2)}(3)(L(1))(2)](OTf)(3) (1) is a bright red luminophore whereas the monomer [Ir(ppy)(2)L(2)](OTf) (2) exhibits emission in the green region.     

Ligand-bridged dinuclear cyclometalated Ir(III) complexes: from metallamacrocycles to discrete dimers

Metallamacrocycles 1, 2, and 3 of the general formula [{Ir(ppy)(2)}(2)(μ-BL)(2)](OTf)(2) (ppyH = 2-phenyl pyridine; BL = 1,2-bis(4-pyridyl)ethane (bpa) (1), 1,3-bis(4-pyridyl)propane (bpp) (2), and trans-1,2-bis(4-pyridyl)ethylene (bpe) (3)) have been synthesized by the reaction of [{(ppy)(2)Ir}(2)(μ-Cl)(2)], first with AgOTf to effect dechlorination and later with various bridging ligands. Open-frame dimers [{Ir(ppy)(2)}(2)(μ-BL)](OTf)(2) were obtained in a similar manner by utilizing N,N'-bis(2-pyridyl)methylene-hydrazine (abp) and N,N'-(bis(2-pyridyl)formylidene)ethane-1,2-diamine (bpfd) (for compounds 4 and 5, respectively) as bridging ligands. Molecular structures of 1, 3, 4, and 5 were established by X-ray crystallography. Cyclic voltammetry experiments reveal weakly interacting "Ir(ppy)(2)" units bridged by ethylene-linked bpe ligand in 3; on the contrary the metal centers are electronically isolated in 1 and 2 where the bridging ligands are based on ethane and propane linkers. The dimer 4 exhibits two accessible reversible reduction couples separated by 570 mV indicating the stability of the one-electron reduced species located on the diimine-based bridge abp. The "Ir(ppy)(2)" units in compound 5 are noninteracting as the electronic conduit is truncated by the ethane spacer in the bpfd bridge. The dinuclear compounds 1-5 show ligand centered (LC) transitions involving ppy ligands and mixed metal to ligand/ligand to ligand charge transfer (MLCT/LLCT) transitions involving both the cyclometalating ppy and bridging ligands (BL) in the UV-vis spectra. For the conjugated bridge bpe in compound 3 and abp in compound 4, the lowest-energy charge-transfer absorptions are red-shifted with enhanced intensity. In accordance with their similar electronic structures, compounds 1 and 2 exhibit identical emissions. The presence of vibronic structures in these compounds indicates a predominantly (3)LC excited states. On the contrary, broad and unstructured phosphorescence bands in compounds 3-5 strongly suggest emissive states of mixed (3)MLCT/(3)LLCT character. Density functional theory (DFT) calculations have been carried out to gain insight on the frontier orbitals, and to rationalize the electrochemical and photophysical properties of the compounds based on their electronic structures.     

Scenario of Accelerating Universe: Role of Phenomenological Λ Models

Dark matter, the major component of the matter content of the Universe, played a significant role at early stages during structure formation. But at present the Universe is dark energy dominated as well as accelerating. Here, the presence of dark energy has been established by including a time-dependent Λ term in the Einstein’s field equations. This model is compatible with the idea of an accelerating Universe so far as the value of the deceleration parameter is concerned. Possibility of a change in sign of the deceleration parameter is also discussed. The impact of considering the speed of light as variable in the field equations has also been investigated by using a well known time-dependent Λ model.     

A New Class of Stable (2+1) Dimensional Thin Shell Wormhole

Few years ago, Bañados, Teitelboim and Zanelli (BTZ) (in Phys. Rev. Lett. 69:1849 (1992)) has discovered an explicit vacuum solution of (2+1)-dimensional gravity with negative cosmological constant. It has been argued that the existence of such physical systems with an event horizon and thermodynamic properties similar to (3+1) dimensional black holes. These vacuum solutions of (2+1)-dimensional gravity are asymptotically anti-de Sitter and are known as BTZ black holes. We provide a new type of thin-shell stable wormhole from the BTZ black holes. This is the first example of stable thin shell wormhole in (2+1)-dimension. Several characteristics of this thin-shell wormhole have been discussed.