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61.
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63.
Unoccupied titanium 3d states due to subcluster formation in stoichiometric TiO2 nanoparticles 下载免费PDF全文
Sami Auvinen Matti Lahti Matti Alatalo 《International journal of quantum chemistry》2015,115(17):1175-1180
The source of unoccupied Ti 3d states in the case of stoichiometric anatase structured (TiO2)n clusters has been investigated using ab initio methods. These unoccupied gap states appear for example in the case of a stoichiometric (TiO2)38 cluster. We show that the origin of these gap states is related to effective subcluster formation which gives rise to empty defect‐like gap states, when these states are split off from conduction band. © 2015 Wiley Periodicals, Inc. 相似文献
64.
Zouhaier Bouallagui Mohamed Bouaziz Salwa Lassoued Jean Marc Engasser Mohamed Ghoul Sami Sayadi 《Applied biochemistry and biotechnology》2011,163(5):592-599
We previously reported the production of high yields of hydroxytyrosol through the bioconversion of tyrosol. In the present
work, hydroxytyrosol was subjected to the lipase catalyzed acylation aiming for the recovery of more lipophilic esters that
might be easily incorporated in cosmetic and food preparations. Hydroxytyrosyl acetate and hydroxytyrosyl oleate were produced
with respective molar esterification yields of 98% and 78%. DPPH free radical quenching potency demonstrated that the acylation
of hydroxytyrosol did not alter its antioxidant activity. The acylated esters were shown to be more effective than the natural
antioxidant: caffeic acid and two synthetic ones as BHA and BHT. Antiproliferative activity on human cervical cells (HeLa)
resulted in IC50 values of 0.46, 0.42 and 0.33 mM for hydroxytyrosol and its acetyl and oleyl esters, respectively. Additionally, when used
at a non-cytotoxic concentration (100 μM), these compounds showed significant effectiveness in preventing iron-induced oxidative
stress, resulting in a reduction of 30%, 36% and 38% in thiobarbituric acid-reactive substance production, respectively. 相似文献
65.
Abdelhalim B. Mahmoud Shereen Abd Algaffar Wendy van de Sande Sami Khalid Marcel Kaiser Pascal Mser 《Molecules (Basel, Switzerland)》2021,26(13)
Redox-active drugs are the mainstay of parasite chemotherapy. To assess their repurposing potential for eumycetoma, we have tested a set of nitroheterocycles and peroxides in vitro against two isolates of Madurella mycetomatis, the main causative agent of eumycetoma in Sudan. All the tested compounds were inactive except for niclosamide, which had minimal inhibitory concentrations of around 1 µg/mL. Further tests with niclosamide and niclosamide ethanolamine demonstrated in vitro activity not only against M. mycetomatis but also against Actinomadura spp., causative agents of actinomycetoma, with minimal inhibitory concentrations below 1 µg/mL. The experimental compound MMV665807, a related salicylanilide without a nitro group, was as active as niclosamide, indicating that the antimycetomal action of niclosamide is independent of its redox chemistry (which is in agreement with the complete lack of activity in all other nitroheterocyclic drugs tested). Based on these results, we propose to further evaluate the salicylanilides, niclosamide in particular, as drug repurposing candidates for mycetoma. 相似文献
66.
The approximate solutions of Dirac equation with Morse potential in the presence of Coulomb-like tensor potential are obtained by using Laplace transform (LT) approach. The energy eigenvalue equation of the Dirac particles is found and some numerical results are obtained. By using convolution integral, the corresponding radial wave functions are presented in terms of confluent hypergeometric functions. 相似文献
67.
Systems with singular-higher order Lagrangians are investigated by two methods: Dirac method and Hamilton-Jacobi method. An example is studied and it is shown that the Hamilton-Jacobi method gives the correct canonical generalized equations of motion, contrary to Dirac method, where Dirac conjecture is invalid. 相似文献
68.
A method which employs an integrating sphere and a single-wavelength (1.6 μm) pyrometer for measuring the spectral effective emissivities of superalloys in the temperature range (=650–1050°C) is described. The spectral effective emissivities for five superalloys, namely, MARM-247, MARM-509, CMSX-4, Inconel-718, N-155 and two René-N6 samples coated with YSZ thermal barrier coating were measured. Correcting the pyrometer measurements for the variations in the object emissivity would reduce the uncertainty in the temperature measurements to <±1%. 相似文献
69.
The formyl carbonyl group in bis(4-methoxyphenyl)-acetaldehyde does not contribute to the formation of the carbonyl group in 4,4′-dimethoxydeoxybenzoin when the former rearranges to the latter by treatment with 50% (w/w) sulfuric acid. 相似文献
70.
Sami A. Shakir 《Physics letters. A》1983,93(9):510-512
We describe two methods for employing materials with giant Kerr nonlinearities for modulating waveguides. A beam, of relatively intense light, is used to vary the propagation constant of a waveguide with the guiding layer, or the substrate, made from a nonlinear material. 相似文献