全文获取类型
收费全文 | 69篇 |
免费 | 2篇 |
专业分类
化学 | 35篇 |
力学 | 1篇 |
数学 | 2篇 |
物理学 | 33篇 |
出版年
2022年 | 1篇 |
2017年 | 2篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 5篇 |
2012年 | 4篇 |
2011年 | 1篇 |
2010年 | 1篇 |
2009年 | 4篇 |
2007年 | 6篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 2篇 |
2002年 | 2篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 1篇 |
1998年 | 1篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1990年 | 2篇 |
1989年 | 2篇 |
1987年 | 1篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1981年 | 1篇 |
1938年 | 1篇 |
1935年 | 1篇 |
排序方式: 共有71条查询结果,搜索用时 781 毫秒
51.
52.
A three-component one-pot condensation of 2-naphthol, ureas/amides and aldehydes catalyzed by sulfamic acid, under ultrasound irradiation and ambient conditions gives 1-amidoalkyl-2-naphthols in excellent yield and in short time. 相似文献
53.
Upreti Shobha Pandey Satish Chandra Bisht Ila Samant Mukesh 《Molecular diversity》2022,26(3):1823-1835
Molecular Diversity - Cancer is among one of the most fatal diseases leading to millions of death around the globe. Chemotherapy is the most popular conventional approach for the treatment of... 相似文献
54.
Synthesis of highly dispersed,block copolymer‐grafted TiO2 nanoparticles within neat block copolymer films 下载免费PDF全文
Shimelis T. Hailu Saumil Samant Christopher Grabowski Michael Durstock Alamgir Karim Dharmaraj Raghavan 《Journal of polymer science. Part A, Polymer chemistry》2015,53(3):468-478
The objective of the study is to formulate exclusive block copolymer (BCP) nanocomposites by dispersing bcp end‐grafted nanoparticles (bcp‐g‐nps) of PMMA‐b‐PS‐g‐TiO2 within PS‐b‐PMMA matrix. PMMA‐b‐PS‐g‐TiO2 is synthesized using a “grafting‐to” approach and characterized by XPS and TGA to establish that the copolymer chains were bonded to NPs. Good dispersion of bcp‐g‐nps in PMMA and PS‐PMMA bcp films is observed, in contrast to poor dispersion in PS films. In PS‐PMMA films, the compatible and identical bcp nature of the end‐grafted polymer, and large NP size caused it to span across entire PS‐PMMA domains. Poor and good dispersion in PS and PMMA matrices, respectively, can be rationalized by the fact that NPs interactions are driven by the PMMA at the outer corona of the bcp‐g‐nps. Developing bcp‐g‐nps as a strategic route to preparation of highly dispersed high permittivity NPs like titanium dioxide (TiO2) in bcp matrix can have important ramifications for energy storage devices. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 468–478 相似文献
55.
The selective addition of arylmethylmagnesium halides with formaldehyde giving arylethyl alcohols is extremely challenging. To circumvent the difficulties, in the current communication, we have reported on the nucleophilic addition of benzyl zinc reagents derived from inexpensive and abundant benzyl chlorides to paraformaldehyde. The reaction investigated herein is hitherto unknown and was found to be selective, operationally simple, atom- and step-economical and high yielding to deliver phenethyl alcohols utilized as key perfumery ingredients in 60–83% yields. After successful establishment of the reaction condition, the reaction was also scaled up successfully to deliver a large-scale preparation of the phenethyl alcohol. 相似文献
56.
M S Samant R P Anand R K Choudhury S S Kapoor K Kumar D M Nadkarni A Saxena 《Pramana》1993,40(4):299-309
The emission spectra of prompt fission neutrons from mass and kinetic energy selected fission fragments have been measured
in235U(n
th,f). Neutron energies were determined from the measurement of the neutron time of flight using a NE213 scintillation detector.
The fragment energies were measured by a pair of surface barrier detectors in one set of measurements and by a back-to-back
gridded ionization chamber in the second set of measurements. The data were analysed event by event to deduce neutron energy
in the rest frame of the emitting fragment for the determination of neutron emission spectra and multiplicities as a function
of the fragment mass and total kinetic energy. The results are compared with statistical model calculations using shell and
excitation energy dependent level density formulations to deduce the level density parameters of the neutron rich fragment
nuclei over a large range of fragment masses. 相似文献
57.
A. Ney R. Rajaram E. Arenholz J.S. Harris Jr. M. Samant R.F.C. Farrow S.S.P. Parkin 《Journal of magnetism and magnetic materials》2006
We present a detailed magnetic characterization of Cr and Mn doped InN films be means of superconducting quantum interference device magnetometry and X-ray magnetic circular dichroism. The InN:Cr films exhibit ferromagnetic behavior up to 300 K in a doping region from 2% to 8% without detectable phase segregation. The easy axis of magnetization is found to be in the film plane. On the contrary, Mn-doped films show signatures of phase segregation and paramagnetic behavior. 相似文献
58.
Copolyimides were prepared in two steps by ring-opening polyaddition of pyromellitic dianhydride (PMDA) with oxalyl dihydrazide (0) and an aromatic diamine; viz., diaminodiphenyl methane (M), p-phenylene diamine (P), or benzidine (B) in dimethylsulfoxide (DMSO), followed by thermal cyclodehydration. O content was restricted to 10%. Kinetics of imidization of polyamic acid samples was studied. The effect of structure and composition of copolymers on thermal properties was evaluated. 相似文献
59.
Mahendra Varne Vaishali Samant Dr. Jahur A. Mondal Dr. Sandip K. Nayak Dr. Hirendra N. Ghosh Dr. Dipak K. Palit Dr. 《Chemphyschem》2009,10(17):2979-2994
The dynamics of the excited states of 1‐aminofluoren‐9‐one (1AF) and 1‐(N,N‐dimethylamino)‐fluoren‐9‐one (1DMAF) are investigated by using steady‐state absorption and fluorescence as well as subpicosecond time‐resolved absorption spectroscopic techniques. Following photoexcitation of 1AF, which exists in the intramolecular hydrogen‐bonded form in aprotic solvents, the excited‐state intramolecular proton‐transfer reaction is the only relaxation process observed in the excited singlet (S1) state. However, in protic solvents, the intramolecular hydrogen bond is disrupted in the excited state and an intermolecular hydrogen bond is formed with the solvent leading to reorganization of the hydrogen‐bond network structure of the solvent. The latter takes place in the timescale of the process of solvation dynamics. In the case of 1DMAF, the main relaxation pathway for the locally excited singlet, S1(LE), or S1(ICT) state is the configurational relaxation, via nearly barrierless twisting of the dimethylamino group to form the twisted intramolecular charge‐transfer, S1(TICT), state. A crossing between the excited‐state and ground‐state potential energy curves is responsible for the fast, radiationless deactivation and nonemissive character of the S1(TICT) state in polar solvents, both aprotic and protic. However, in viscous but strong hydrogen‐bond‐donating solvents, such as ethylene glycol and glycerol, crossing between the potential energy surfaces for the ground electronic state and the hydrogen‐bonded complex formed between the S1(TICT) state and the solvent is possibly avoided and the hydrogen‐bonded complex is weakly emissive. 相似文献
60.
The selectivity pattern of nickel-catalyzed hydrogenolysis-hydrogenation of aryl ethers has been studied in the micellar media. The micellar conditions selectively formed arenes and alcohols with enhanced yields. 相似文献