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81.
M. Buendí a C. Rold n R. Cibri n R. Salvador M. Dolz R. Belda V. Herraez E. Ram n 《Optics & Laser Technology》1990,22(6):399-402
A device for automatically obtaining the information contained in holographic interferometry fringes is proposed. The method may be applied to any kind of interferometric fringes. Accuracy has been demonstrated by contrasting the results obtained with our prototype system and those with the single-beam speckle interferometry technique for the measurement of displacements in a plane. The results show good correlation between the two series of measurements. 相似文献
82.
83.
W. E. Garrigues 《Fresenius' Journal of Analytical Chemistry》1910,49(8):508
Ohne Zusammenfassung 相似文献
84.
85.
Laura Escuder‐Gilabert María Amparo Martínez‐Gómez Rosa María Villanueva‐Camañas Salvador Sagrado María José Medina‐Hernández 《Biomedical chromatography : BMC》2009,23(3):225-238
Stereoselectivity in protein binding can have a significant effect on the pharmacokinetic and pharmacodynamic properties of chiral drugs. The investigation of enantioselectivity of drugs in their binding with human plasma proteins and the identification of the molecular mechanisms involved in the stereodiscrimination by the proteins represent a great challenge for clinical pharmacology. In this review, the separation techniques used for enantioselective protein binding experiments are described and compared. An overview of studies on enantiomer–protein interactions, enantiomer–enantiomer interactions as well as chiral drug–drug interactions, including allosteric effects, is presented. The contribution of individual plasma proteins to the overall enantioselective binding and the animal species variability in drug–plasma protein binding stereoselectivity are reviewed. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
86.
The metabolic profiling of kiwifruit (Actinidia deliciosa, Hayward cultivar) aqueous extracts and the water status of entire kiwifruits were monitored over the season (June-December) using nuclear magnetic resonance (NMR) methodologies. The metabolic profiling of aqueous kiwifruit extracts was investigated by means of high field NMR spectroscopy. A large number of water-soluble metabolites were assigned by means of 1D and 2D NMR experiments. The change in the metabolic profiles monitored over the season allowed the kiwifruit development to be investigated. Specific temporal trends of aminoacids, sugars, organic acids and other metabolites were observed.The water status of kiwifruits was monitored directly on the intact fruit measuring the T2 spin-spin relaxation time by means of a portable unilateral NMR instrument, fully non-invasive. Again, clear trends of the relaxation time were observed during the monitoring period.The results show that the monitoring of the metabolic profiling and the monitoring of the water status are two complementary means suitable to have a complete view of the investigated fruit. 相似文献
87.
Julia Kuligowski Guillermo Quintás Salvador Garrigues Miguel de la Guardia 《Chromatographia》2010,72(3-4):201-202
On-line gel permeation chromatography Fourier transform infrared (GPC-FTIR) is proposed as detection technique for the determination of the total polymer triacylglyceride (PTG) content in olive oil as an alternative to other conventional detectors such as the evaporative light scattering detector (ELSD) or the refraction index detector (RID). FTIR detection allowed confirmation additionally to quantification of the analytes via their characteristic infrared spectra. For the extraction of chromatograms, a multivariate method called science based calibration (SBC) was used. The SBC method employed a reference spectrum of triacylglycerides (TG) extracted from the injection of a fresh olive oil sample and data obtained from a blank injection as ‘noise’ matrix, to estimate a regression vector subsequently used to predict the relative concentration of the analyte during the GPC run. Results found evidenced that the use of SBC improved the selectivity, sensitivity and repeatability of the GPC-FTIR measurements as compared to the ‘classical’ approach based on the measurement of the spectral area in a defined spectral range. The developed method provided a limit of detection for PTGs of 0.19 mg mL?1, which corresponds to a 0.65% w/w for an oil sample mass of 300 mg. 相似文献
88.
Marina López-Nogueroles Alberto ChisvertAmparo Salvador 《Journal of chromatography. A》2010,1217(18):3150-3160
A chemometric treatment of the data obtained by gas chromatography (GC) with flame ionization detector (FID) has been proposed to study the maceration time involved in perfumes manufacture with the final purpose of reducing this time but preserving the organoleptic characteristics of the perfume that is being elaborated. In this sense, GC–FID chromatograms were used as a fingerprint of perfume samples subjected to different maceration times, and data were treated by linear discriminant analysis (LDA), by comparing to a set of samples known to be macerated or not, which were used as calibration objects. The GC–FID methodology combined with the treatment of data by LDA has been applied successfully to seven different perfumes. The constructed LDA models exhibited excellent Wilks’ lambdas (0.013–0.118, depending on the perfume), and up to a reduction of 57% has been achieved with respect to the maceration time initially established. 相似文献
89.
Julia Kuligowski David CarriónGuillermo Quintás Salvador GarriguesMiguel de la Guardia 《Journal of chromatography. A》2010,1217(43):6733-6741
A background correction method for the on-line coupling of gradient liquid chromatography and Fourier transform infrared spectrometry (LC–FTIR) is proposed. The developed approach applies univariate background correction to each variable (i.e. each wave number) individually. Spectra measured in the region before and after each peak cluster are used as knots to model the variation of the eluent absorption intensity with time using cubic smoothing splines (CSS) functions. The new approach has been successfully tested on simulated as well as on real data sets obtained from injections of standard mixtures of polyethylene glycols with four different molecular weights in methanol:water, 2-propanol:water and ethanol:water gradients ranging from 30 to 90, 10 to 25 and from 10 to 40% (v/v) of organic modifier, respectively. Calibration lines showed high linearity with coefficients of determination higher than 0.98 and limits of detection between 0.4 and 1.4, 0.9 and 1.8, and 1.1 and 2.7 mg mL−1 in methanol:water, 2-propanol:water and ethanol:water, respectively. Furthermore the method performance has been compared with a univariate background correction approach based on the use of a reference spectra matrix (UBC-RSM) to discuss the potential as well as pitfalls and drawbacks of the proposed approach. This method works without previous variable selection and provides minimal user-interaction, thus increasing drastically the feasibility of on-line coupling of gradient LC–FTIR. 相似文献
90.
Inma Peral Jonathan McKinlay Michael Knapp Salvador Ferrer 《Journal of synchrotron radiation》2011,18(6):842-850
A concept is given for describing multicrystal analyser detectors (MADs), as they are in use for synchrotron powder diffraction, on the basis of the Rowland circle construction. The Rowland circle is typically used to describe focusing geometries and can be adapted for the case of MADs working at a single energy as well as in a limited energy range. With this construction it is also possible to quantify and optimize the walk of the beam along non‐central crystals which is inevitable in certain detector designs. The results of this geometrical inspection are correlated with a real detector design that is implemented at the ALBA synchrotron facility in Spain. An error budget is given to estimate the influence and amount of tolerance of the manufacturing process. 相似文献