排序方式: 共有87条查询结果,搜索用时 531 毫秒
41.
In this article, we present a simple and efficient method to synthesize a magnetic NiFe2O4 nanocatalyst under hydrothermal conditions. Fourier transform infrared spectroscopy (FT‐IR), X‐ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X‐ray spectroscopy (EDX) analyses confirmed the synthesis of NiFe2O4 nanoparticles. These nanoparticles showed satisfactory catalytic activity for determination of norepinephrine (NE) in the presence of folic acid (FA) using cyclic voltammetry (CV) and differential pulse voltammetry (DPV) methods. Differential pulse voltammetry peak currents of NE increased linearly with their concentrations in the range of 1.0 × 10?7–5.0 × 10?4 M, and the detection limit for NE was 2.3 × 10?8 M, respectively. The modified electrode displayed strong function for resolving the overlapping voltammetric responses of NE and FA into two well‐defined voltammetric peaks. In the mixture containing NE and FA, the two compounds can well separate from each other with a potential difference of 510 mV between NE and FA, which was large enough to determine NE and FA individually and simultaneously. Additionally, the prepared electrochemical sensor demonstrated a practical feasibility for real sample determination. 相似文献
42.
Modeling the cohesive energy and melting point of nanoparticles by their average coordination number
M. Attarian Shandiz A. Safaei S. Sanjabi Z.H. Barber 《Solid State Communications》2008,145(9-10):432-437
We present a relation between the average coordination number and the cohesive energy for nanoparticles that shows that the ratio of nanoparticles cohesive energy to the bulk value is equal to the ratio of the nanoparticles average coordination number to that of the bulk. We consider the effect of lattice and surface packing factors on the average coordination numbers of the atoms in the nanoparticle. The melting temperature of nanoparticles has been calculated from the obtained relation for cohesive energy, and predictions for the cohesive energy and melting temperature of the nanoparticles have been compared with other theoretical models and available experimental data and the results of molecular dynamics simulations. 相似文献
43.
Ebrahimi Dariush Yousefzadeh Shahrouz Akbari Omid Ali Montazerifar Farnaz Rozati Seyed Alireza Nakhjavani Shima Safaei Mohammad Reza 《Journal of Thermal Analysis and Calorimetry》2021,144(6):2295-2316
Journal of Thermal Analysis and Calorimetry - The current survey’s primary purpose is to conduct the computational modeling of laminar mixed convection heat transfer of nanofluids inside a... 相似文献
44.
Javad Safaei‐Ghomi 《中国化学会会志》2007,54(6):1561-1563
Sulfonyl hydrazides and sulfonyl semicarbazides are readily prepared by the reacting of hydrazine derivatives with sulfonyl chlorides in the presence of basic alumina under solvent‐free conditions. Reaction of a sulfonyl chloride with t‐butylcarbazate, followed by hydrolysis provides the corresponding sulfonyl hydrazides in higher yield and shorter time than previously reported. 相似文献
45.
Heterogeneous nanoscale catalyst was successfully synthesized via anchoring of V‐bis(2‐aminobenzamide) complex on the Al‐SBA‐15. This modified mesoporous was identified by several characterization techniques, such as X‐ray diffraction, field emission‐scanning electron microscopy, Fourier transform‐infrared, Brunauer–Emmett–Teller and transmission electron microscopy. V‐Bis(2‐aminobenzamide)@Al‐SBA‐15 was found to be an efficient heterogeneous catalyst for the rapid and desirable synthesis of various spirooxindole dihydroquinazolinones derivatives. In addition, the heterogeneous nanocatalyst was chemically stabilized in organic and aqueous solutions as well as can be expeditiously reused for at least seven cycles without a significant loss in catalytic activity. 相似文献
46.
Sarafraz M. M. Tlili I. Tian Zhe Khan Ahmad Raza Safaei Mohammad Reza 《Journal of Thermal Analysis and Calorimetry》2020,139(4):2413-2422
Journal of Thermal Analysis and Calorimetry - In this research, flow boiling heat transfer of zirconia–water nanofluid inside a heat exchanger was experimentally investigated. The system was... 相似文献
47.
Tramadol is a centrally acting analgesic‐anodyne agent of high oral bioavailability. The tramadol contains a weakly absorbing chromophore in its molecule and it was determined by kinetic spectrophotometric method in pharmaceutical, urine, and blood plasma. Response surface methodology and the central composite design was applied to study the influence of maximum sensitivity, reagents concentration, temperature, and time on the UV–Vis spectrophotometry analysis of tramadol. Analysis of variance showed a high coefficient of determination (R2) value for responses, confirming adjustment of the models with experimental data. The change in absorbance was followed spectrophotometrically at 478 nm. Under optimum experimental conditions, calibration curve was linear over the range 0.45–100.0 μg/L of tramadol. The limit of detection was 0.12 μg/L of tramadol. The developed method was successfully applied for the determination of tramadol in real samples. 相似文献
48.
Ali Safaei 《Journal of nanoparticle research》2010,12(3):759-776
The size dependency of the cohesive energy of nanocrystals is obtained in terms of their averaged structural and energetic
properties, which are in direct proportion with their cohesive energies. The significance of the effect of the geometrical
shape of nanoparticles on their thermal stability has been discussed. The model has been found to have good prediction for
the case of Cu and Al nanoparticles, with sizes in the ranges of 1–22 nm and 2–22 nm, respectively. Defining a new parameter,
named as the surface-to-volume energy-contribution ratio, the relative thermal stabilities of different nanoclusters and their
different surface-crystalline faces are discussed and compared to the molecular dynamic (MD) simulation results of copper
nanoclusters. Finally, based on the size dependency of the cohesive energy, a formula for the size-dependent diffusion coefficient
has been presented which includes the structural and energetic effects. Using this formula, the faster-than-expected interdiffusion/alloying
of Au(core)–Ag(shell) nanoparticles with the core–shell structure, the Au-core diameter of 20 nm and the Ag-shell thickness of 2.91 nm, has been
discussed and the calculated diffusion coefficient has been found to be consistent with its corresponding experimental value. 相似文献
49.
S Safaei I Mohammadpoor-Baltork AR Khosropour M Moghadam S Tangestaninejad V Mirkhani 《Molecular diversity》2012,16(3):591-600
A variety of pyrazolo[3,4-d]pyrimidine-6(7H)-thione derivatives were easily synthesized with a novel, simple, efficient, and regioselective method via three-component condensation reaction of 5-methyl-1H-pyrazol-3-amine, arylisothiocyanates, and aldehydes in the presence of catalytic amount of p-toluenesulfonic acid (p-TSA) in 1-butyl-3-methylimidazolium bromide ionic liquid with excellent yields and short reaction times. 相似文献
50.
Elham Safaei Iraj SaberikiaAndrzej Wojtczak Zvonko Jagli?i?Anna Kozakiewicz 《Polyhedron》2011,30(6):1143-1148
Two aminoethanol derivatives of aminophenol ligands were synthesized and characterized by IR and 1H NMR spectroscopies. The binuclear iron(III) complexes of these ligands have been prepared and characterized by IR, 1H NMR and UV-Vis spectroscopic techniques, cyclic voltammetry, single crystal X-ray diffraction and magnetic susceptibility studies. X-ray analysis revealed binuclear complexes, Fe2(L2), in which Fe(III) centers are surrounded by two phenolate and hydroxyl oxygen atoms, and amine nitrogens of the ligands. The metal active sites of both complexes are held together by the two above mentioned hydroxyl bridges. Variable temperature magnetic susceptibility indicates antiferromagnetic coupling between the iron centers of both complexes. This exchange coupling is stronger for Fe2(Lae)2, such that it shows a room temperature strong coupling between the two iron centers. The investigated complexes undergo irreversible electrochemical oxidation and reduction. 相似文献