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51.
52.
The hadronic and string cascade model and the corresponding event generator LUCIAE are used to study systematically the production
of the grey particles in (14.6, 60 and 200A GeV)0 + Em, (2004 GeV)Si + Em, (200A GeV)S + Em and (11.6A GeV)Au + Em reactions. The dependences of the mean multiplicity,
the multiplicity distributions and the polar angular distributions of the grey particles on the incident energy, the projectile
mass and the collision centrality observed in emulsion experiments, respectively, are all reproduced by LUCIAE calculations.
In addition the effects of the rescattering on the grey particle production are also investigated.
Project supported by the National Natural Science Foundation of China (Grant Nos. 19575071 and 19875019) and DFG of Germany. 相似文献
53.
Saéda Didaoui Ahmed Ait-Kaci Mareck Rogalski 《The Journal of chemical thermodynamics》2010,42(10):1261-1264
(Solid + liquid) equilibrium (SLE) of thiophene or diethylsulfide with n-heptane, n-octane or n-dodecane mixtures was measured by a static method. All the systems under study are simple eutectic systems. The DISQUAC group contribution model is fairly successful in predicting SLE. 相似文献
54.
Palladium-based catalysts were prepared by the ion-exchange method with dealuminated HY zeolite as support. The support dealumination
was realised using acid solution of HNO3, HCl or H2SiF6. The high activity of prepared catalysts for methane combustion was observed. This activity was dependent on the Al concentration,
structural and textural properties of the support changed after the dealumination. Especially, Pd loaded on supports developing
a second pore system, and having the highest Si/Al ratio, was more active than that on unmodified supports. It was also expected
that the active sites in the methane combustion, which are suspected to be PdO, were influenced by the acidic properties of
the support. 相似文献
55.
A separation/preconcentration procedure based on the coprecipitation of Pb(II), Fe(III), Co(II), Cr(III) and Zn(II) ions with copper(II)-N-benzoyl-N-phenyl-hydroxylamine complex (Cu-BPHA) has been developed. The analytical variables including pH, amount of BPHA, amount of copper(II) as carrier element, and sample volume were investigated for the quantitative recoveries of the elements. No interfering effects were observed from the concomitant ions when present in real samples. The recoveries of the analyte ions were in the range of 95–100%. The detection limits (3 s) for Pb(II), Co(II), Fe(III), Cr(III) and Zn(II) ions were found to be 2.3, 0.7, 0.7, 0.3 and 0.4 µg L?1, respectively. The validation of the procedure was performed by the analysis of CRM (SRM NIST-1547 peach leaves and LGC6019 river water) standard reference materials. The method was applied to the determination of the analytes in real samples including natural waters, hair, urine, soil, sediment and peritoneal fluids samples etc., and good results were obtained (relative standard deviations <4%, recoveries >95%). 相似文献
56.
Sałdyka M 《Physical chemistry chemical physics : PCCP》2010,12(45):15111-15118
The structure, isomerization pathways and vibrational spectra of the important N-hydroxyurea (HU) molecule were studied by matrix isolation FT-IR spectroscopy and molecular orbital calculations undertaken at the MP2/6-311++G(2d,2p) level of theory. In agreement with theoretical predictions, 1Ea represents the most stable keto isomer in the gas-phase, being the dominant species trapped in argon matrices, while the 1Za isomer also contributes to the spectrum of isolated HU molecules. According to the calculated abundance values at the temperature of evaporation of the compound (393 K), the 1Ea and 1Za isomers together with a small contribution of 1Eb are expected to appear in the experimental spectra. Since the barrier for interconversion 1Ea? 1Eb is only ~2 kJ mol(-1), these two isomers are in equilibrium in the matrices and, at low temperature, the population of the less stable 1Eb form is too small to be observed. Full assignment of the observed spectra of N-hydroxyurea and its deuterium analogue was undertaken on the basis of comparison with theoretical data. 相似文献
57.
Hu BW Zhao JP Yang Q Zhang XF Evangelisti M Sañudo EC Bu XH 《Dalton transactions (Cambridge, England : 2003)》2010,39(46):11210-11217
Two new azido-Co(II) complexes with pyrazine carboxylato ligands, [Co(N(3))(L)·H(2)O](n) (L = pyrazine-2-carboxylato) (1) and [CoNa(N(3))(2)(L)](n) (2), have been obtained by carefully tuning the Co(II):N(3)(-) ratio. Here we present the structural and magnetic characterization of these new species. Modulation of the coordination environment of Co(II) leads to a variation of the magnetic properties of the obtained compounds. Complex 1 exhibits ferromagnetically coupled [Co(2)] units that form the rungs of the ladder with a nearly negligible coupling between these units, while complex 2 is a 2D arrangement of 1D Co(II) single-chain magnets. 相似文献
58.
Clustering of Ti on carbon nanostructures has proved to be an obstacle in their use as hydrogen storagematerials. Using density functional theory we show that Ti atoms will not cluster at moderate concentrations when doped into nanoporous graphene. Since each Ti atom can bind up to three hydrogen molecules with an average binding energy of 0.54 eV/H2, this material can be ideal for storing hydrogen under ambient thermodynamic conditions. In addition, nanoporous graphene is magnetic with or without Ti doping, but when it is fully saturated with hydrogen, the magnetism disappears. This novel feature suggests that nanoporous graphene cannot only be used for storing hydrogen, but also as a hydrogen sensor. 相似文献
59.
We study laser cooling of atomic gases by collisional redistribution, a technique applicable to ultradense atomic ensembles at a pressure of a few hundred bars. Frequent collisions of an optically active atom with a buffer gas shift atoms into resonance with a far red detuned laser beam, while spontaneous decay occurs close to the unperturbed resonance frequency. In such an excitation cycle, a kinetic energy of the order of the thermal energy k B T is extracted from the sample. Here we report of recent experiments investigating the cooling of a potassium?Cargon gas mixture, which compared to a rubidium?Cargon mixture investigated in earlier experiments has a smaller fine structure of the optically active alkali atoms. We observe a relative cooling of the potassium?Cargon gas mixture by 120?K. 相似文献
60.
Mohamed Saïdi 《Mathematische Zeitschrift》2014,277(1-2):361-372
We show the existence of group-theoretic sections of the “étale-by-geometrically abelian” quotient of the arithmetic fundamental group of hyperbolic curves over $p$ -adic local fields relative to a proper and flat model which are non-geometric, i.e., which do not arise from rational points. 相似文献