The valence state of M-ions in the chemically stabilized YSr2Cu3-xMxO7+δ (M=Mo, W and Re) superconductors

 Single phase Ba-free Sr-based YSr₂Cu _3-x M _x O_7+δ (M=Mo, W and Re) compounds have been stabilized by chemical doping. Superconductivity is observed for these phases in the range 30–45 K. X-ray diffraction studies suggest a relatively small orthorhombicity compared to Ba-analogue. X-ray photoelectron spectroscopic investigations reveal that the stabilizing cations are in the hexavalent state. The observation of the higher oxidation state of M-ions accounts for the excess oxygen content in these phases which is in accordence with the diffraction results. Received: 10 June 1996 / Accepted: 20 September 1996     

Charged particles on surfaces: coexistence of dilute phases and periodic structures at interfaces

We consider a mixture of two immiscible oppositely charged molecules strongly adsorbed to an interface, with a neutral nonselective molecular background. We determine the coexistence between a high density ionic periodic phase and a dilute isotropic ionic phase. We use a strong segregation approach for the periodic phase and determine the one-loop free energy for the dilute phase. Lamellar and hexagonal patterns are calculated for different charge stoichiometries of the mixture. Molecular dynamics simulations exhibit the predicted phase behavior. The periodic length scale of the solid phase is found to scale as epsilon/(lB psi3/2), where psi is the effective charge density, lB is the Bjerrum length, and epsilon is the cohesive energy.     

Aprotic metal-oxygen batteries: recent findings and insights

During the last two decades, we have observed a dramatic increase in the electrification of many technologies. What has enabled this transition to take place was the commercialization of Li-ion batteries in the early nineties. Mobile technologies such as cellular phones, laptops, and medical devices make these batteries crucial for our contemporary lifestyle. Like any other electrochemical cell, the Li-ion batteries are restricted to the thermodynamic limitations of the materials. It might be that the energy density of the most advance Li-ion battery is still too low for demanding technologies such as a full electric vehicle. To really convince future customers to switch from the internal combustion engine, new batteries and chemistry need to be developed. Non-aqueous metal-oxygen batteries—such as lithium–oxygen, sodium–oxygen, magnesium–oxygen, and potassium–oxygen—offer high capacity and high operation voltages. Also, by using suitable polar aprotic solvents, the oxygen reduction process that occurs during discharge can be reversed by applying an external potential during the charge process. Thus, in theory, these batteries could be electrically recharged a number of times. However, there are many scientific and technical challenges that need to be addressed. The current review highlights recent scientific insights related to these promising batteries. Nevertheless, the reader will note that many conclusions are applicable in other kinds of batteries as well.     

Experimental Studies of the Flow of Ferrofluid in Porous Media

This paper presents laboratory-scale experimental results of the behavior of ferrofluids in porous media consisting of sands and sediments. Ferrofluids are colloidal suspensions of magnetic particles stabilized in various carrier liquids. In the presence of an external magnetic field, a ferrofluid becomes magnetized as the particles align with the magnetic field. We investigate the potential for controlling fluid emplacement in porous media using magnetic fields. These experiments show that in laboratory-scale porous media experiments (up to 0.25m), with both vertical gravitational forces and lateral magnetic forces acting simultaneously, the magnetic field produces strong attractive forces on the ferrofluid, particularly in the vicinity of the magnet. These holding forces result in a predictable configuration of the fluid in the porous medium which is dependent on the magnetic field and independent of flow pathway or heterogeneity of the porous medium. No significant retention effects due to flow through variably saturated sands are observed. While the proposed field engineering applications of ferrofluids are promising, the observations to date are particularly relevant at the laboratory scale where the decrease in magnetic field strength with distance from a magnet is less of a limitation than in larger scale applications. Ferrofluids may find immediate application in any situation where it is desirable to control the motion or final configuration of fluid in an experimental flow apparatus without direct physical contact.