Regioselective Alkylation of the Polyfunctional Nucleophile 1-(Methylthio)-3-triethylsilyloxypentadienyllithium

γ-Selective sulfenylation of the triethysilyloxypentadienyllithium 1 gave the versatile alkylthiodene 4 which on successive deprotonation and alkylation furnished with high regioselectivity the γ-products 6 . Fluoride-promoted silylether cleavage 6 → 7 may be followed by intramolecular [4 + 2]-addition 7c → 8 and sulfoxide elimination 8 → 9 . The conversions 7b → 12 and 7a → 17 demonstrate the feasibility of 5 to serve as an equivalent of the hypothetical β-deprotonated divinylketone 13 whose two enone units may be unmasked separately.     

A short comment on the effect of a shear layer on nonlinear water waves

In this paper we study nonlinear periodic deep water waves propagating on a background shear current,which decays exponentially with depth.We extend the study of Cheng,Cang and Liao(2009) by introducing a second parameter which measures the depth of the shear current.A high-order convergent analytical series solution is obtained by the homotopy analysis method(HAM).A detailed analysis of the impact of the depth parameter is given.We find that increasing this parameter so that the shear current is thinner re...     

Swern Oxidation of α-Ketols to α-Diketones1

The Swern oxidation of acyclic and cyclic α-ketols delivered α-diketones or the tautomeric diosphenols in good yield.