Synthesis and crystal structure of AlH2P3O10.2H2O; a new structure-type for layered acid phosphates

The crystal structure of the layered acid phosphate, AlH2P3O10.2H2O, has been determined and provides a new structure-type for a series of metal phosphates with interlamellar regions likely to be highly suited to intercalation behaviour.     

Unprecedented SnCl2-mediated cyclization of nitro arenes via N-N bond formation

[reaction: see text] A mild, efficient, one-pot protocol for the cyclization of nitro-aryl substrates using SnCl(2) has been described. The mechanistic course of the reaction suggests the involvement of a hydroxylamine intermediate leading to an intramolecular cyclization via N-N bond formation. The versatility of the methodology has been demonstrated by using two nitro-aryl substrates derived from dihydroisoquinolines and dihydro-beta-carbolines. The intramolecular cyclization led to the formation of indazoles in high yields and purities.     

Collective modes in asymmetric ultracold Fermi systems

We derive the long wavelength effective action for the collective modes in systems of fermions interacting via a short-range s-wave attraction, featuring unequal chemical potentials for the two fermionic species (asymmetric systems). As a consequence of the attractive interaction, fermions form a condensate that spontaneously breaks the U(1) symmetry associated with total number conservation. Therefore at sufficiently small temperatures and asymmetries, the system is a superfluid. We reproduce previous results for the stability conditions of the system as a function of the four-fermion coupling and asymmetry. We obtain these results analyzing the coefficients of the low energy effective Lagrangian of the modes describing fluctuations in the magnitude (Higgs mode) and in the phase (Nambu-Goldstone, or Anderson-Bogoliubov, mode) of the difermion condensate. We find that for certain values of parameters, the mass of the Higgs mode decreases with increasing mismatch between the chemical potentials of the two populations, if we keep the scattering length and the gap parameter constant. Furthermore, we find that the energy cost for creating a position dependent fluctuation of the condensate is constant in the gapped region and increases in the gapless region. These two features may lead to experimentally detectable effects. As an example, we argue that if the superfluid is put in rotation, the square of the radius of the outer core of a vortex should sharply increase on increasing the asymmetry, when we pass through the relevant region in the gapless superfluid phase. Finally, by gauging the global U(1) symmetry, we relate the coefficients of the effective Lagrangian of the Nambu-Goldstone mode with the screening masses of the gauge field.     

Understanding changes in DTI metrics in patients with different stages of neurocysticercosis

Diffusion tensor imaging (DTI) was performed on 25 patients with neurocysticercosis (NCC). The aim of this study was to investigate the changes in DTI measures during the evolutionary course of NCC lesions from vesicular to calcified stage in the brain. DTI measures were quantified from the NCC lesions of all patients. On the basis of conventional imaging findings, NCC lesions were classified into vesicular, vesicular colloidal, granular nodular and calcified stages. Significant inverse correlation was observed between the evolutionary stage of NCC lesion and mean diffusivity (MD; r=−0.748, P<0.001) and spherical anisotropy (CS; r=−0.585, P<.001) values. Significant direct correlations were observed between evolutionary stages of NCC lesion and mean fractional anisotropy (FA; r=0.575, P<0.001), linear anisotropy (CL; r=0.478, p<0.001) and planar anisotropy (CP; r=0.561, p<0.001) values. Successive decrease in MD values calculated from NCC lesions was observed, moving from vesicular to granular nodular stage. On FA, CL and CP maps, a significant increase in signal intensity value was observed in calcified as compared to other stages. We conclude that DTI measures may indicate the evolutionary changes in NCC from vesicular to calcified stage.     

Influence of Aprotic Solvents on the Transmission of Anomalous Substituent Effects on 13C NMR Chemical Shifts at the Carboxyl Carbon (δco) in Meta-Substituted Benzoic Acids: A Strong Evidence for π-Polarization Mechanism

Anomalous (reverse) substituent-induced ¹³C nuclear magnetic resonance chemical shifts at the carboxyl carbon (δ_co) in meta-substituted benzoic acids have been studied for 11 substituents having varying electronic effects in 4 aprotic (nonhydroxylic) solvents of varying polarity by employing different dual substituent parameter models. The regression results for apolar aprotic solvents provide a strong evidence for through space π-polarization mode of transmission of reverse meta-substituent effects on the carboxyl carbon in benzoic acids. The results for dipolar aprotic solvents indicate significant specific solvation of π-polarized forms of the acids. The study showed further that an apolar aprotic solvent has a distinct preference over a dipolar aprotic one for investigating intrinsic substituent effects on chemical shifts in aromatic molecules.     

Kβ′ satellite of the Kβ1 X-ray emission line of Fe(NH4)2β(SO4)2β6H2O

The origin of the Kβ′ satellite of the Kβ₁ X-ray emission line of Fe(NH₄)₂β(SO₄)₂β6H₂O, observed by Tsutsumi has been explained for the first time in a more satisfactory way than by any of the previous workers. Plasmon oscillations in solid theory can give a better fit with the experimentally observed values for energy separation and relative intensity than the Molecular Orbital theory of Tsutsumi.     

Thin layer chromatographic separation of a few food dyes over scolecite as a new adsorbent

Summary A naturally occurring Zeolite mineral collected from Pawagad (Gujrat) india was shown to be a Scolecite of the natrolite group of Zeolites. After physico chemical characterization it was used as a new adsorbent for the separation of food dyes by TLC.     

An optical topographic technique to study the dissolution kinetics at dislocation sites in sodium chloride crystals

A technique has been developed to study the dissolution kinetics at dislocation sites in sodium chloride single crystals. A parallel beam of light is allowed to fall upon the silvered etched surface of the crystals and the reflected beam is received back on a photographic film. The pattern thus obtained on the photographic film gives information about (i) the structure of the etched surface (ii) the nature of the surface forming the pit and (iii) the slope of the pit at the source of dissolution.     

On Reflection and Transmission of Electromagnetic Waves Obliquely Incident on Relativistically Moving Uniaxial and Isotropic Plasma Slabs

The oscillations in the power reflection coefficient as a function of the normalized slab velocity are shown for electromagnetic waves obliquely incident on a relativistically moving uniaxial plasma slab with an infinitely strong magneto-static field parallel to the slab boundaries. This paper also summarizes and concludes the sequence on the reflection and transmission of electromagnetic waves obliquely incident on relativistically moving uniaxial and isotropic plasma slabs.