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41.
The effect of pressure drop on the performance of supercritical fluid chromatography systems using a modified mobile phase (carbon dioxide + ethanol) was studied. Experiments were performed on a Lichrospher-RP-18 column with phenanthrene as a solute. A wide range of back pressures (130 to 210 bar) and modifier concentrations (2 to 7% w/w) have been explored. Experiments yielding both small and large pressure drops were performed. From these experiments, parameters to describe pressure drop, retention, and column efficiency were extracted, and were used to simulate the dynamics of the chromatographic column. A good match between the experimentally measured and calculated values of pressure drop, retention times, and column efficiency was observed. At low back pressure and modifier composition, significant loss of column efficiency was observed. 相似文献
42.
Bourhim M Rajendran A Ramos Y Srikrishnan T Sulkowski E 《Journal of chromatographic science》2008,46(6):574-576
An investigation of the binding of native and recombinant human serum albumin and bovine serum albumin on three thiophilic gels, PyS, 2S, and 3S was performed. In addition to these proteins, we studied serum albumins from several species such as goat, rabbit, guinea pig, rat, hamster, baboon, and pig. Our results reveal that recombinant human serum albumin (rHSA) binds completely to PyS whereas native human serum albumin and bovine serum albumin bind only partially to PyS. The binding affinities of rHSA, human serum albumin and bovine serum albumin to 2S and 3S gels are less than their binding to PyS. Serum albumins from goat, rabbit, guinea pig, rat, hamster, baboon, and pig bind much stronger to 3S gel than human and bovine serum albumins. The binding of pig and hamster serum albumins is stronger than that of rat, goat, baboon, and rabbit. 相似文献
43.
Subramaniam Gopalakrishnan Vijayabharathi Rajendran Sathya Arumugam Hari C. Sharma Srinivas Vadlamudi Ratna Kumari Bhimineni 《Natural product research》2016,30(24):2760-2769
Helicoverpa armigera, an important pest causes serious damage to grain legumes. The main objective of this study was to isolate and identify the metabolite against H. armigera from a previously characterised Streptomyces sp. CAI-155. The culture filtrate of CAI-155 was extracted using Diaion HP-20 and the active fractions were fractionated on Silica and C18 column chromatography. The C18 active fraction was further fractionated on Silica gel 60 F254 thin layer chromatography (TLC). The most active fraction (Rf 0.64) purified from TLC led to the identification of a novel metabolite N-(1-(2,2-dimethyl-5-undecyl-1,3-dioxolan-4-yl)-2-hydroxyethyl)stearamide by spectral studies. The purified metabolite showed 70–78% mortality in 2nd instar H. armigera by diet impregnation assay, detached leaf assay and greenhouse assay. The LD50 and LD90 values of the purified metabolite were 627 and 2276 ppm, respectively. Hence, this novel metabolite can be exploited for pest management in future. 相似文献
44.
T. Balakrishnan V. Rajendran 《Journal of polymer science. Part A, Polymer chemistry》1997,35(4):727-733
Crosslinked poly(4-vinylpyridine-co-styrene) was prepared and functionalized with titanium tetrachloride to afford the corresponding poly(4-vinylpyridine-co-styrene)-titanium tetrachloride complex. This insoluble functionalized polymer-supported catalyst shows good catalytic activity for esterification reactions. In this article, the kinetics of esterification of acrylic acid with n-butanol is reported. The rate of formation of product depends on many experimental parameters, viz., stirring speed, concentration of acrylic acid, catalyst amount, temperature, percent active site, percent crosslinking, and mesh size of the polymer catalyst. The reaction rates were found to increase with increase in the stirring speed, concentration of acrylic acid, catalyst amount, and temperature, and decreases with increasing percentage crosslinking and mesh size of the polymer beads. © 1997 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 35: 727–733, 1997 相似文献
45.
Devipriya Balu Kumaradhas Poomani Kalyanam Nagabushanam Sridhar Balasubramanium Rajendran Ramanujam Majeed Muhammed 《Journal of chemical crystallography》2011,41(5):697-702
Abstract
5-Lipoxygenase inhibitor 3-O-acetyl-9,11-dehydro-β-boswellic acid was detected in the extract of Boswellia serrata gum resulting from unstable 11-hydroxy precursor. It was reported more potent than other Boswellic acids in its inhibition of 5-Lipoxygenase. Here, we report the method of conversion of 3-acetoxy-β-boswellic acid to 3-O-acetyl-9,11-dehydro-β-boswellic acid, and the crystal structure of later. This compound crystallizes in orthorhombic space group P212121 with cell parameters of a = 12.726(1) ?, b = 16.597(1) ?, c = 27.332(2) ?, α = β = γ = 90°, V = 5772.7(5) ?3, D c = 1.143 Mg/m3, and Z = 8. The X-ray structure investigation indicates that the rings A, B, D and E are exhibit chair and the ring C adopts a distorted half chair conformation. The conformational difference of the two structures in the arrangement is due to crystal packing of 3-O-acetyl-9,11-dehydro-β-boswellic acid. The molecular packing is stabilized by C–H···O and O–H···O types of hydrogen bonding interactions. 相似文献46.
Solid polymer electrolytes (SPEs) with high ionic conductivity and acceptable mechanical properties are of particular interest for increasing the performance of batteries. In the present work, SPEs based on poly(ethylene oxide)/poly (vinyl pyrrolidone) (PEO/PVP) with various lithium salts were prepared by solvent casting technique. The amorphous nature of the polymer-salt complex was studied by X-ray diffraction analysis. The complexation of the prepared electrolytes was confirmed by Fourier transform infrared analysis. Ionic conductivity as a function of frequency was studied at various temperatures in the range of 303–353 K. The maximum ionic conductivity value was found to be 1.08 × 10?5 S/cm for the film containing lithium bis trifluoromethane sulfonoimide (LiN[CF3SO2]2) at room temperature and the temperature dependent ionic conductivity values seem to obey Vogel-Tamman-Fulcher relation. Thermogravimetry was used to ascertain the thermal stability of the electrolytes. Photoluminescence measurements demonstrated that the sample having maximum ionic conductivity shows the minimum luminescence intensity. Ultra violet-visible analysis reveals that the values of the band gap energies were changed with the addition of various lithium salts. Porosity of the sample containing lithium bis trifluoromethane sulfonoimide (LiN[CF3SO2]2) was studied by Atomic force microscope. 相似文献
47.
Mathematical model describing the oxidation of glucose in a multiscale porous biocatalytic electrode is discussed. The model considers herein is composed of two nonlinear differential equations accounting for reaction and diffusion within the hydrogel film. In this letter, approximate analytical expressions for the concentration of mediator, substrate and current have been obtained using the Adomian decomposition method (ADM). Furthermore, a comparison confirmed that our analytical result fitted very well with the numerical solution (Matlab). Sensitivity analysis of the parameters is also reported. 相似文献
48.
Prof. Arivazhagan Rajendran Kirankumar Krishnamurthy Seojeong Park Prof. Eiji Nakata Prof. Youngjoo Kwon Prof. Takashi Morii 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(22):e202200108
DNA minicircles exist in biological contexts, such as kinetoplast DNA, and are promising components for creating functional nanodevices. They have been used to mimic the topological features of nucleosomal DNA and to probe DNA-protein interactions such as HIV-1 and PFV integrases, and DNA gyrase. Here, we synthesized the topologically-interlocked minicircle rotaxane and catenane inside a frame-shaped DNA origami. These minicircles are 183 bp in length, constitute six individual single-stranded DNAs that are ligated to realize duplex interlocking, and adopt temporary base pairing of single strands for interlocking. To probe the DNA-protein interactions, restriction reactions were carried out on DNAs with different topologies such as free linear duplex or duplex constrained inside origami and free or topologically-interlocked minicircles. Except the free linear duplex, all tested structures were resistant to restriction digestion, indicating that the topological features of DNA, such as flexibility, curvature, and groove orientation, play a major role in DNA-protein interactions. 相似文献
49.
50.
S. Sankarrajan S. Aravindan R. Yuvakkumar K. Sakthipandi V. Rajendran 《Journal of magnetism and magnetic materials》2009,321(21):3611-3620
Nd1−xSrxMnO3 perovskite manganite material with different compositions (x=0.31, 0.35, 0.37, 0.39 and 0.41) have been prepared employing solid-state reaction technique. The ultrasonic velocities and attenuation of the above samples have been measured employing through transmission method operated at a fundamental frequency of 5 MHz over wide range of temperatures. The temperature dependence of ultrasonic velocities, attenuation, relative percentage variation in velocities and elastic constants show an interesting anomaly in all compositions. The observed anomalies in ultrasonic parameters at Tc in all compositions have been revealed in terms of existence of ferromagnetic (FM) state. Similarly, the anomalies at Tco show the transition from FM to charge-ordered antiferromagnetic (AFM) state. The observed results have been used to explore the competitions between FM and AFM. 相似文献