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61.
The temperature dependence of the Raman spectrum in the cubic phase of BaTiO3 is described. The cross section decreases when the temperature increases, which is contrary to a normal second order effect behaviour. The associated measurements of the optical absorption definitely prove that this variation is intrinsic. The anomalous Raman spectrum is related to the existence in the crystal of anisotropic fluctuation domains.  相似文献   
62.
The elastic scattering from a two-body bound system is investigated in order to determine what information about the nuclear structure and the projectile-nucleon interaction may be obtained at intermediate energies. Emphasis is placed on the kinematics and the importance of properly treating the overlapping potential region. The kinematics of the “fixed scatterer” and “impulse” approximations result in differences which are still significant at intermediate energies. As far as scattering information is concerned, the overlapping potential region is the interesting one since it requires explicit knowledge of the interaction. Our results suggest that for nucleon scattering at intermediate energies the corrections due to properly taking into account off-energy-shell effects are likely to be comparable with the contributions due to the short-range two-body correlations. The relevance of the above results to various models currently employed in analyzing high- and intermediate-energy nuclear scattering is also discussed.  相似文献   
63.
64.
Under highly oxygen rich conditions palladium/alumina catalysts exhibit strongly enhanced NOx reduction activity in the presence of CO:H2 mixtures due to in situ generation of ammonia via the formation and subsequent hydrolysis of isocyanate (NCO) species.  相似文献   
65.
From the New Zealand ascidian, Lissoclinum notti a new natural product, N2,N2,7-trimethylguanine (1) has been isolated. The structure of 1 was elucidated by analysis of spectroscopic data.  相似文献   
66.
The best algorithm known for finding logarithms on an elliptic curve is the (parallelized) Pollard lambda collision search. We show how to apply a Pollard lambda search on a set of equivalence classes derived from , which requires fewer iterations than the standard approach. In the case of anomalous binary curves over , the new approach speeds up the standard algorithm by a factor of .

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67.
Various indolenine squarylium dyes with additional electron-donating amine redox centres have been synthesised and their redox chemistry has been studied. A combination of cyclic voltammetry, spectro-electrochemistry and DFT calculations has been used to characterise the electronic structure of the mono-, di- and, in one case, trications. All monocations still retain the cyanine-like, delocalised character due to the relatively low redox potential of the squaraine bridge and are therefore compounds of Robin-Day class III. Thus we extended previous studies on organic mixed-valence systems by using the indolenine squaraine moiety as very electron-rich bridge between two electron-donating amine redox centres to provoke a strong coupling between the additional redox centres. We synthesised TA3, which has an N-N distance of 26 bonds between the triarylamine redox centres and is to our knowledge the longest bis(triarylamine) radical cation that is completely delocalised. We furthermore show that altering the symmetry of a squaraine dye by substitution of a squaric ring oxygen atom by a dicyanomethylene group has a direct impact on the optical properties of the monocations. In case of the dications, it turned out that the energetically most stable state of dianisylamine-substituted squaraines is an anti-ferromagnetically coupled open-shell singlet state.  相似文献   
68.
甘氨酸在SiO2表面的吸附及热缩合反应   总被引:2,自引:0,他引:2  
孟明 《催化学报》2005,26(5):393-398
 考察了甘氨酸水溶液平衡浓度和pH值对其在SiO2表面吸附行为的影响,采用DTG,XRD和FT-IR等手段对甘氨酸在SiO2表面的吸附量及晶相结构等进行了表征. 结果表明,甘氨酸在SiO2上的吸附不符合Langmuir吸附模型,当甘氨酸水溶液平衡浓度小于0.073 mol/L时,主要为特定位置吸附,此时SiO2对甘氨酸的吸附源于其表面≡Si-O-基团与甘氨酸离子的-NH+3 端的相互作用; 当平衡浓度大于0.073 mol/L时,呈多层吸附,形成α和β两种晶型的甘氨酸. 用TPD-MS对甘氨酸的热缩合行为进行了考察,结合FT-IR结果表明,产物为环状二聚体哌嗪二酮(DKP),没有检测到线式二聚体以及表面硅酯类物种形成. SiO2对表面吸附的甘氨酸分子产生了诱导活化,使其热缩合温度与体相α甘氨酸相比降低了50 ℃左右.  相似文献   
69.
70.
Tropylium ion mediated α-cyanation of amines is described. Even in the presence of KCN, tropylium ion is capable of oxidizing various amine substrates, and the resulting iminium ions undergo salt metathesis with cyanide ion to produce aminonitriles. The byproducts of this transformation are simply cycloheptatriene, a volatile hydrocarbon, and water-soluble potassium tetrafluoroborate. Thirteen total substrates are shown for the α-cyanation procedure, including a gram scale synthesis of 17β-cyanosparteine. In addition, a tropylium ion mediated oxidative aza-Cope rearrangement is demonstrated.  相似文献   
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