排序方式: 共有29条查询结果,搜索用时 15 毫秒
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Srood O. Rashid Sultan S. Almadhhi David J. Berrisford James Raftery Inigo Vitorica-Yrezabal George Whitehead Peter Quayle 《Tetrahedron》2019,75(16):2413-2430
The use of TiCl3-HCl as promotor in the radical Truce-Smiles reactions of 2-(((3,5-dimethylisoxazol-4-yl)sulfonyl)oxy)benzenediazonium salts has been investigated in detail. During these reactions the desired Truce-Smiles rearrangement (via an ipso-substitution reaction) is accompanied by the formation of a number of by-products including dihydrobenzo[5,6][1,2]oxathiino[3,4-d]isoxazole 4,4-dioxides, dioxidobenzo[e][1,2]oxathiin-3-yl)ethan-1-ones, anilines and chloroaromatics. Replacing TiCl3-HCl by Cu(NO3)2-Cu2O as reductant in these reactions was found to afford broadly comparable product distributions. Competition and radical clock experiments also provide an indication of the relative susceptibility of the isoxazole nucleus towards attack by aryl radicals. 相似文献
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Nicholas C. Norman A. Guy Orpen Michael J. Quayle Edward G. Robins 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(1):50-52
The structure of trans‐(bromo/chloro)hydridotetrakis(tri‐methylphosphine)rhodium(III) bis(tetrabromopyrocatechol‐ato‐O,O′)borate dichloromethane solvate, [RhCl0·74Br0·26H‐(C3H9P)4](C12BBr8O4)·CH2Cl2, is reported. The RhIII complex shows bromine/chlorine compositional disorder with a trans arrangement of the hydride and halide ligands. The anion has approximate D2d symmetry, with a central spiro‐B atom distorted from regular tetrahedral geometry by the small chelating O—B—O angles. 相似文献
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Madeleine Helliwell Christopher K. Knight Peter Quayle James Raftery 《Tetrahedron letters》2005,46(42):7129-7134
Bifurcate, tandem ATRC reactions provide rapid access to 2-oxabicyclo[4.3.0]nonane ring system present in terpenes such as eunicellin. 相似文献
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Non‐linear,cata‐Condensed,Polycyclic Aromatic Hydrocarbon Materials: A Generic Approach and Physical Properties 下载免费PDF全文
Barnaby T. Haire Kane W. J. Heard Dr. Mark S. Little Dr. Adam V. S. Parry Dr. James Raftery Dr. Peter Quayle Prof. Dr. Stephen G. Yeates 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(28):9970-9974
A generic approach to the regiospecific synthesis of halogenated polycyclic aromatics is made possible by the one‐ or two‐directional benzannulation reactions of readily available (ortho‐allylaryl)trichloroacetates (the “BHQ” reaction). Palladium‐catalysed cross‐coupling reactions of the so‐formed haloaromatics enable the synthesis of functionalised polycyclic aromatic hydrocarbons (PAHs) with surgical precision. Overall, this new methodology enables the facile mining of chemical space in search of new electronic functional materials. 相似文献
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Nicholas C. Norman A. Guy Orpen Michael J. Quayle George R. Whittell 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(3):m160-m161
Crystals of the title compound, [NiCl(C18H15P)2], contain one molecule per asymmetric unit with no short intermolecular interactions. This is noteworthy since previous studies have reported that the formally 15‐electron species oligomerizes in the solid state. The nickel(I) centre has a distorted trigonal–planar coordination geometry, the origin of which is suggested to be electronic in nature. 相似文献
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Nicholas C. Norman A. Guy Orpen Michael J. Quayle Craig R. Rice 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):440-444
The preparation and structures of three diborane(4) compounds are described. The compound B2(3,4‐S2C4H2‐1‐S)2 [2,2′‐bi(1,3,5,2‐trithiaborapentalene), C8H4B2S6] is planar and lies at a crystallographic inversion centre. The amine adducts [B2(C3S5)2(NHMe2)2] [2,2′‐bis(dimethylamino)‐2,2′‐bi(1,3,4,6,2‐tetrathiaborapentalene‐5‐thione), C10H14B2N2S10] and [B2(1,2‐S2C2H4)2(NHMe2)2]·0.33CH2Cl2 [1,2‐bis(di‐methylamino)‐1,1:2,2‐bis(dimethylenedithioxy)diborane(4) dichloromethane solvate, C8H22B2N2S4·0.33CH2Cl2] contain dimethylamine ligands bound to each boron in an anti conformation about the B—B bond, with tetrahedral geometry at the B atoms. The crystal structures display a number of S?S interactions, which appear to dictate the packing arrangements. 相似文献
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Stephen A. Eastham Michael R. Hallett Peter Quayle James Raftery 《Tetrahedron letters》2006,47(14):2299-2304
A Dötz benzannulation reaction has been utilized in the synthesis of the furo[2,3-b]furan core of aflatoxin B2. 相似文献
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A tandem Dotz-Mitsunobu sequence has been used to prepare the oxasteroid skeleton 相似文献