Adsorption of thorium(IV) on magnetic multi-walled carbon nanotubes

The influences of pH, contact time, solid-liquid ratio, temperature and C60(C(COOH)2)n on Th(IV) adsorption onto the magnetic multi-walled carbon nanotubes(MMWCNTs) were studied by batch technique. The dynamic process showed that the adsorption of Th(IV) onto MMWCNTs could reach equilibrium in 40 h and matched the pseudo-second-order kinetics model. The adsorption of Th(IV) onto MMWCNTs was significantly dependent on pH values, the adsorption ratio increased markedly at pH 3.0–5.0, and then maintained a steady state as pH values increased. At low pH, different C60(C(COOH)2)n content could enhance the adsorption content of Th(IV) onto MMWCNTs, but restrained it at higher pH. Through simulating the adsorption isotherms by Langmuir, Freundlich and Dubini-Radushkevich models, it could be seen respectively that the adsorption pattern of Th(IV) onto MMWCNTs was mainly surface complexation, and that the adsorption process was endothermic and irreversible.     

基于多重子域代理模型的结构可靠性分析

基于合理子域概念，构建多重代理模型。多重代理模型在合理子域内采用经典响应面模型，在合理子域外采用经典Kriging模型，能够充分利用两种经典模型各自的优势。多重代理模型能够合理规避经典响应面模型中响应函数采取事先假定形式带来的可靠度评估风险，同时能够有效避免经典Kriging模型中试验点组合爆炸的问题。相比经典响应面模型，多重代理模型所需试验点数量并未增加，计算效率与经典响应面模型大体相同。算例表明，本文方法的计算结果与MCS的计算结果几乎一致，具有较好的计算精度。     

Novel One-Pot Synthesis of Functionalized (Z)-2-Arylvinyl Bromides

A novel and versatile one-pot synthesis of functionalized (Z)-2-arylvinyl bromides was developed. The new procedure involved microwave-induced debrominative decarboxylation of cinnamic acid dibromide with Et₃N and subsequent esterification in the presence of dicyclohexyl carbodiimide (DCC) and dimethyl-aminopyridine (DMAP).     

基于LIBS技术的水泥粉末在线成分分析

在工业现场生产水泥的过程中，各种成分的含量直接影响着水泥的质量，因此如何快速准确地监测水泥中各个成分的含量意义重大。采用的实验方式为，将不经过任何预处理的水泥粉末直接放入位于二维移动平台上的物料盒中，通过激光诱导击穿光谱(LIBS)直接对水泥粉末表面的不同位置进行激发检测，对得到的光谱数据首先进行归一化和主成分分析等预处理操作，然后针对水泥中Ca, Si, Al, Fe, Mg五种元素，分别建立偏最小二乘(PLS)和支持向量回归(SVR)两种定量分析模型进行方法比较。此外，对比了粉末状水泥与压片式水泥两种测量方式的结果。实验结果表明，采用粉末状水泥直接测量的方式下，针对水泥样品元素浓度与所得到的光谱中特征线强度的关系，SVR方法比PLS方法更具优势，粉末状水泥直接测量的精度接近压片式测量的精度，说明LIBS技术对水泥粉末状样品直接在线测量具有可行性。     

PVDF-H1.6 Mn1.6 O4锂离子筛膜的制备及其提锂性能

锂元素是现代社会中重要的能源元素和战略资源,锂离子筛吸附法被认为是从盐湖卤水和海水中提锂最有前景的方法.然而,锂离子粉末具有流动性和渗透性较差的特点,制膜是一种典型的将之用于工业化的手段.本研究首先制备了多孔球型尖晶石型Li1.6 Mn1.6 O4,然后利用相转化法成功制得了PVDF-Li1.6 Mn1.6 O4多孔交联膜,酸浸后得到了PVDF-H1.6 Mn1.6 O4锂离子筛膜.吸附实验表明,当Li1.6 Mn1.6 O4负载量为11.9;时,其对应锂离子筛膜的Li+吸附容量最高,可以达到404 mg/m2,循环实验和选择性实验表明锂离子膜具有较好的循环利用性和Li+选择性.     

石英砂粒径对水合物沉积物力学性质的影响

利用自主研发的水合物沉积物原位合成与力学性质测试的高压低温三轴仪,通过多级加荷的试验方法,以不同粒径的砂粒作为沉积物骨架进行三轴压缩试验,得到了剪切过程的应力-应变关系曲线,以及不同粒径尺寸沉积物的强度,还有剪切过程中的体积变化关系。结果表明:含水合物沉积物强度随着沉积物粒径尺寸的增大而增强;在降压剪切过程中,所有粒径的水合物沉积物式样均有明显的剪缩现象。     

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In this paper, a nonparametric method for reliability of the stress-strength model is proposed when the dependent stress variable and strength variable are subject to right censoring. The dependence between variables is measured by the common Farlie-Gumbel-Morgenstern copula function and Clayton copula function. Using the empirical process theory, consistency and asymptotic normality of the proposed estimator is established in this paper. The results of numerical simulation show that the proposed method performs well in the case of finite sample. The method proposed in this paper has a wide application prospect in practice.     

Characteristics of the magnetic analysis system for a compact MPR-type spectrometer

The magnetic proton recoil(MPR)spectrometer is a novel diagnostic instrument with high perfor-mance for measurements of neutron spectra in inertial confinement fusion(ICF)experiments and high power fusion devices.A compact MPR-type spectrometer dedicated to the research of pulsed deuterium-tritium(DT)neutron spectroscopy of special experimental conditions is currently under design.Analyses of the main parameters and performance of the magnetic analysis system through 3-D particle transport calculations and MonteCarlo simulations and calibration of the system performance as a test using CR-39 solid track detector and α particle from 239pu and 226Ra radioactive sources are presented in this paper.The results indicate that the magnetic analysis system will achieve a detection efficiency level of 10-5-10-4 at an energy resolution of 1.5%-2.1%,and fulfills the design goals of the spectrometer.     

Alkylation mechanism of benzene with 1-dodecene catalyzed by Et_3NHCl-AlCl_3

The isotope exchange method was employed to investigate the catalytic mechanism of ionic liquid in alkylation of benzenes with olefins.It is proposed that alkylation was induced by the Lewis acid AlCl3 which attracted π electrons of 1-dodecene to shift toward 1-carbon,thus forming a carbonium ion.The carbonium ion further reacted with benzenes to form a complex.Due to unstabilit of the complex,a deuterated ring proton was transferred into an electronegative 1-carbon of the side chain to substitute for the A...