Study of chemical composition of <Emphasis Type="Italic">Asparagus racemosus</Emphasis> roots

The chemical composition of Asparagus racemosus roots is studied by the methods of gas chromatography and high-performance liquid chromatography. Marker substances characteristic of this type of raw materials are revealed. The dioscin content in the roots of A. racemosus is quantitatively determined.     

Study of the stability of solid polyoxometalate Mo72Fe30 with a buckyball structure

Samples of polyoxometalate Mo₇₂Fe₃₀: [Mo₇₂Fe₃₀O₂₅₂(CH₃COO)₁₂{Mo₂O₇(H₂O)}₂ {H₂Mo₂O₈(H₂O)}(H₂O)₉₁] · ??150H₂O with a buckyball structure, which can be both crystalline and amorphous, were synthesized. It was shown that such samples can be studied by neutron diffraction. The stability of Mo₇₂Fe₃₀ to heating and UV light exposure (in poly(vinyl alcohol) and polyvinylpyrrolidone films) was studied by IR, EPR, and electronic absorption spectroscopy; thermal analysis; and mass spectrometry. Mo₇₂Fe₃₀ was found to be less stable to heating and irradiation in a poly(vinyl alcohol) film as compared with the related polyoxometallate Mo₁₃₂ free of iron. The sorption properties of Mo₇₂Fe₃₀ to organic vapors and its stability under sorption conditions were studied. It was demonstrated that, in addition to sorption, organic substances cause the destruction of buckyballs.     

Unimodular metagravity vs. general relativity with a scalar field

The unimodular metagravity, with the graviscalar as a dark matter, is compared with General Relativity (GR) in the presence of a scalar field. The effect of the graviscalar on the static spherically symmetric metric is studied. An exact limit solution representing a new cosmic object, the (harmonic) graviscalar black hole, is given. The relation with the black hole in the environment of a scalar field in GR is discussed.     

Penetration depth and pinning effects in high-Tc superconductors La-Sr-Cu-O and (Er,Ho)-Ba-Cu-O studies by μSR

We report the results of μSR investigations of the ceramic samples La_2-xSr_xCuO_4-σ (x=0.1, 0.15, 0.25) and ReBa₂Cu₃O_7-σ (Re=Er, Ho, Y_0.5Ho_0.5) in the external magnetic field 0–800 Oe. The measurements were performed by the ZFC and FC methods. The irreversibility effects were studied at several temperatures by measuring the mean value and the width of the magnetic field distribution on the muon in the step by step procedure of increasing and subsequent decreasing of the external field. The temperature dependences of the magnetic penetration depth perpendicular to the basal plane λ_⊥ were obtained. For the lanthanum sample with 0.15 of Sr its value at the zero temperature is λ_⊥ (0)=2400 Å, for Er-Ba-Cu-O λ_⊥ (0)=1600 Å.     

Development of principles of controlled synthesis of monolithic polymeric sorbents for ion chromatography

A series of monolithic macroporous sorbents based on glycidyl methacrylate and ethylene glycol dimethacrylate were prepared by free radical copolymerization. The effect of polymerization conditions and composition of reaction mixture on the pore structure of the monolithic material was studied by IR spectroscopy, intrusion mercury porosimetry, and scanning electron microscopy.     

A study of the influence of physico-chemical processes in a metal base/nonmetallic coating system on the operational properties of coatings in a chemically active medium

We propose a method for the analytic computation and prediction of the lifetime of electrically nonconducting coatings in chemically active media. We study the role that the quantity of passivating additives in the coating and other parameters of the medium-coating-base system play in the destruction of the coating. We investigate the influence of passivating components on the process of corrosive destruction of the metal under the coating.Translated fromMatematicheskie Metody i Fiziko-Mekhanicheskie Polya, Issue 31, 1990, pp. 30–36.     

Studying lepton family violation in lepton-lepton collisions

In the context of the future high energy – high luminosity electron and muon colliders, all the relevant four-lepton processes with the lepton family violation (LFV) are systematically classified. The most general LFV effective lagrangians are found, and the helicity differential cross sections for the LFV processes are calculated. The six- and eight-lepton Standard Model (SM) backgrounds are discussed, and the LFV processes clean of the six-lepton background are picked out. The possibility to suppress the six-lepton SM background, when present, by the unnatural initial beam polarizations is investigated. It is shown that the four-lepton LFV processes are amenable to experimental study in the lepton-lepton collisions in the most favourable cases up to the underlying scale of order TeV. Studying these processes should provide an essential part of the physics program for the next generation lepton colliders to unravel the outstanding flavour/family problem. Received: 20 October 1997 / Published online: 23 February 1998     

The concentration metamagnetic transition in Tm1−x TbxCo2 compounds

The Tm_1?x Tb_xCo₂ (0 ≤ x ≤ 1) system was studied by measuring the magnetic susceptibility, electrical resistance, and neutron diffraction. In the compounds with 0 < x ≤ 0.15, an inhomogeneous magnetic state characterized by the existence of large regions (up to 100 Å in size) with short-range ferrimagnetic order was found to occur. The maximum of the residual electrical resistance observed in the compound with x = 0.1 at the magnetic ordering temperature was established to be due to the scattering of conduction electrons by localized spin fluctuations associated with f-d exchange fluctuations caused by the substitution of terbium for thulium. The increase in the terbium concentration to x ≥ 0.15 leads to a sharp increase in the Co sublattice magnetization and the establishment of a long-range ferromagnetic order, which indicates a concentration metamagnetic transition in the band subsystem.     

Metamagnetic phase transition in Nd1−x TbxCo2 compounds

The electric resistivity and neutron diffraction measurements of the intermetallic compounds Nd_1?x Tb_xCo₂ (x = 0, 0.2, 0.3, 0.5, 0.7, or 1) have been performed. All compounds have a cubic structure at room temperature and a rhombohedral structure at 4.2 K. The magnetic structure of these compounds is described by the wave vector k = 0. The magnetizations of the rare earth and cobalt sublattices increase with increasing x. The concentration dependence of the cobalt sublattice magnetization is explained on the basis of the model of metamagnetic band subsystem in compounds of the RCo₂ type.