Synthesis and chiroptical properties of two new planar-chiral macrocycles

Could simple intraannular-arm macrocyclic systems exist in enantiopure stable forms? The effective synthesis of two representative compounds of such a class, their resolution into enantiomers, and experiments justifying their stability toward racemization are presented.     

On Non-Continuous Dirichlet Processes

We introduce here some Itô calculus for non-continuous Dirichlet processes. Such calculus extends what was known for continuous Dirichlet processes or for semimartingales. In particular we prove that non-continuous Dirichlet processes are stable under C ¹ transformation.     

Development and Application of new C30-Modified TLC Plates

JPC – Journal of Planar Chromatography – Modern TLC - This paper reports the efficiency of the C30 phase for HPLC and TLC separation of a mixture of tocopherol homologs and...     

Analysis of Glycosides and Aglycones of Flavonoid Compounds by Double-Development Thin-Layer Chromatography

JPC – Journal of Planar Chromatography – Modern TLC - Flavonoid glycosides are much more polar than their aglycones and the two groups of compounds are difficult to separate by planar...     

Algebraic representation of the linear problem as a method to construct the Darboux-Bäcklund transformation

An effective algorithm to construct the Darboux matrix based on the dressing method is proposed. Our approach consists in representing the linear problem as a system of algebraic constraints on two matrices. The Darboux matrix is determined from the requirement that the Darboux-Bäcklund transformation preserves these constraints. A non-isospectral deformation of the derivative nonlinear Schrödinger equation is discussed as an example.     

Tablet disintegration monitored by magnetic resonance imaging

The disintegration of bromhexin tablets was monitored by magnetic resonance imaging. The fast imaging method FLASH with spoiling gradients was used to obtain images of the tablets in short time intervals. The rate of the disintegration depends on the preparation method, kind and percentage of the carrier (polyethylene glycol, lactose). Solid dispersion with slow evaporation of solvent yields materials with decreased dissolution rate. Increasing molecular mass of polyethylene glycol and its percentage content also hampers disintegration.     

The capacity of parabolic julia sets

Supported by SFB 170 “Geometrie und Analysis” at the University of G?ttingen     

The complete grapht-packings andt-coverings

The aim of this paper is to introduce the notions of floor and ceiling functions related to graph edge-decompositions intot mutually isomorphic parts. It is shown that, given any natural numbert, uniform and extremal t-packing andt-covering exist for each complete graph and each complete bipartite graph. Extremal in this context means that both a remainder and a surplus are absolutely minimum. In proofs, decompositions of multigraphs into matchings are involved. Open problems and conjectures are stated.     

Semigroups of matrices of intermediate growth

Finitely generated linear semigroups over a field K that have intermediate growth are considered. New classes of such semigroups are found and a conjecture on the equivalence of the subexponential growth of a finitely generated linear semigroup S and the nonexistence of free noncommutative subsemigroups in S, or equivalently the existence of a nontrivial identity satisfied in S, is stated. This ‘growth alternative’ conjecture is proved for linear semigroups of degree 2, 3 or 4. Certain results supporting the general conjecture are obtained. As the main tool, a new combinatorial property of groups is introduced and studied.     

On the Modified Crystalline Stefan Problem with Singular Data

We study the behavior of solutions of the modified Stefan problem in the plane for polygonal interfaces. We are particularly interested in a solution near a singularity of either the loss of a facet or the breaking of a facet. We establish precise regularity results if a facet disappears. We use them to establish the existence of a weak solution with singular data, i.e., when some of the zero-crystalline-curvature facets have zero length.