H2O在SrTiO3-(001)TiO2表面上吸附和解离的密度泛函理论研究

利用密度泛函理论研究了0.25单层(ML),0.5ML,0.75ML和1ML吸附率下H2O在SrTiO3-(001)TiO2表面上的吸附行为.比较了不同吸附率下分子吸附和解离吸附的稳定性,利用微动弹性带(nudged elastic band)方法计算了H2O的解离势垒.结果表明:在低吸附率(0.25ML和0.5ML)时,H2O表现为解离吸附;在0.75ML吸附率下,分子吸附和解离吸附同时存在;而在全吸附(吸附率为1ML)时,分子吸附更稳定.基于对H2O分子与表面之间以及H2O分子之间的电荷转移和相互作用的分析,讨论了吸附率对H2O吸附和解离的影响.     

溶剂折射率对β-胡萝卜素拉曼散射截面的影响

以环己烷的1444 cm^-1拉曼线为内标,采用5145 nm激发光分别测量了β-胡萝卜素的C=C双键（1520 cm^-1）和C—C单键（1155 cm^-1）振动模式下在不同折射率溶剂中的拉曼散射截面,结果表明随溶剂的折射率增加β-胡萝卜素在两种振动模式下拉曼散射截面都增加.利用色散力和共振拉曼理论解释了在不同折射率溶剂中β-胡萝卜素散射截面的差异. 关键词： 拉曼散射截面 β-胡萝卜素 色散力 共振拉曼     

双回路紧凑型干式蒸发器的设计

对一种双回路紧凑型干式蒸发器进行了设计,给出了合理、新型的结构布置;对传热性能进行了计算,分析了污垢热阻对传热总热阻的影响。认为双回路紧凑型干式蒸发器实现了结构紧凑、节约空间的目的,随着并联机组应用的增加,该类型的干式蒸发器的应用也将日趋广泛。计算表明,采用高效强化换热管后,污垢热阻的数值将对传热强度构成重要影响,除垢防垢将成为提高传热效果的重要内容。双回路紧凑型干式蒸发器的设计和制造,对加工工艺提出了更高的要求。     

一种新型回转式制冷压缩机的设计

介绍一种新型回转式制冷压缩机,其是结合滚动转子式制冷压缩机和涡旋式制冷压缩机的特点,组合部分制冷压缩机的优点而设计的。所设计的新型制冷压缩机具有零部件少、制造简单、效率高、噪音小、运行平稳、适用功率范围广的特点。目前该制冷压缩机的开发还处于初级阶段,但对于开发有自主知识产权的新型压缩机产品,对于我国压缩机制造水平的提高、压缩机制造企业及制冷空调行业的发展有着重要的意义。     

Emergency response to disaster-struck scale-free network with redundant systems

Disasters cause tremendous damage every year. In this paper, we have specifically studied emergency response to disaster-struck scale-free networks when some nodes in the network have redundant systems. If one node collapses, its redundant system will substitute it to work for a period of time. In the first part, according to the network structure, several redundant strategies have been formulated, and then our studies focused on their effectiveness by means of simulation. Results show that the strategy based on total degrees is the most effective one. However, many nodes still collapse in the end if redundant systems do not have sufficient capability, so emergency responses are necessary. Several emergent strategies controlling the distribution of external resources have been proposed in the second part. The effectiveness of those emergent strategies are then studied from three aspects, such as the effect of strategies on spreading processes, minimum sufficient quantities of external resources and determination of the most appropriate emergent strategy. In addition, the effects of redundant intensity on these aspects have been discussed as well.     

可见/近红外光谱法无损检测赣南脐橙可溶性固形物

应用可见/近红外光谱法对赣南脐橙可溶性固形物进行了无损检测研究。通过主成分分析,获取光谱的有效信息,将其作为人工神经网络的输入变量进行非线性建模。90个建模样品训练结果是,样品参考值与预测值之间的相关系数为0.9147,训练均方差为0.5203;38个未知样品预测结果是:样品参考值与预测值之间的相关系数为0.9033,预测均方差为0.6964,相对预测偏差4.5709%。实验结果表明基于人工神经网络的可见/近红外光谱法无损检测赣南脐橙可溶性固形物是可行的。     

低温阀门冷态试验的稳态传热模拟与分析

利用有限元分析软件ANSYS对为控制20 K温度的氦气而设计的低温阀门在正常运行和冷态试验状态下的温度场进行模拟与分析。针对冷态试验状态下拉杆处出现冻结的问题,提出在上阀体处添加绝热层的方案,通过进一步的模拟计算预测其改进的效果。     

复色光伏孤子的稳定性

给出求解复色孤子半高宽的近似方法，该方法对分析复色光束的演化提供一个定性的基础 .进一步的数值模拟结果表明，当入射双曲正割光束满足复色光伏孤子半高宽与中心光强的 关系时，双曲正割光束在晶体中的传播就非常接近孤子，表明复色光伏孤子对于小的微扰是 稳定的.此外，复色光伏孤子对于小的轴偏离具有较好的稳定性；复色光伏孤子对因温度微 扰引起折射率变化的情况也具有较好的稳定性.一般情况下，初始光强分布接近复色光伏孤 子光强分布的两束光的光强在传播过程中不断地起伏，形成呼吸状结构，但如果入射面处的 光强明显偏离孤子的光 关键词： 复色光伏空间孤子 稳定性     

800℃下在氩气中分解甲烷合成单壁碳纳米管反应中水的作用(英文)

pacc:8220,7125X TheeffectsofH2OtosynthesizingSWCNTs bydecomposingCH4inArat800℃werestudied byTEMandRamanscattering.Itisshownthat thewaterinducedintothereactinggas(therela tivehumidityisabout5%atroomtemperature)increasedthepercentagecompositionoftheSWC NTs…     

Relaxation and dephasing of multiexcitons in semiconductor quantum dots

We measure the dephasing time of ground-state excitonic transitions in InGaAs quantum dots under electrical injection in the temperature range from 10 to 70 K. Electrical injection into the barrier region results in a pure dephasing of the excitonic transitions. Once the injected carriers fill the electronic ground state, the biexciton to exciton transition is probed and a correlation of the exciton and biexciton phonon scattering mechanisms is found. Additional filling of the excited states creates multiexcitons that show a fast dephasing due to population relaxation.